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Battery packs for plug-in hybrid electrical vehicle (PHEV) applications can be characterized as high-capacity and high-power packs. For PHEV battery packs, their power and electrical-energy capacities are determined by the range of the electrical-energy-driven operation and the required vehicle drive power. PHEV packs often employ high-power lithium-ion (Li-ion) pouch cells with large cell capacity in order to achieve high packing efficiency. Lithium-ion battery packs for PHEV applications generally have a 96SnP configuration, where S is for cells in series, P is for cells in parallel, and n = 1, 2 or 3. Two PHEV battery packs with 355V nominal voltage and 25-kWh nominal energy capacity are studied. The first pack is assembled with 96 70Ah high-power Li-ion pouch cells in 96S1P configuration. The second pack is assembled with 192 35Ah high-power Li-ion pouch cells in 96S2P configuration.