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Methanol has been regarded as a potential transportation fuel due to its advanced combustion characteristics and flexible source. However, it is suffering from misfire and high HC emissions problems under cold start and low load conditions either on methanol SI engine or on methanol/diesel dual fuel engine. Hydrogen is a potential addition that can enhance the combustion of methanol due to its high flammability and combustion stability. In the current work, the effect of hydrogen fraction on the laminar flame characteristics of methanol- hydrogen-air mixture under varied equivalence ratio was investigated on a constant volume combustion chamber system coupled with a schlieren setup. Experiments were performed over a wide range of equivalence ratio of the premixed charge, varied from 0.8 to 1.4, as well as different hydrogen fraction, 0%, 5%, 10%, 15% and 20% (n/n). All tests were carried out at fixed temperature and pressure of 400K and 0.1MPa.

CNG-diesel dual fuel combustion mode has been regarded as a practical operation strategy because it not only can remain high thermal efficiency but also make full use of an alternative fuel, natural gas. However, it is suffering from misfire and high HC emissions under cold start and low load conditions. As known, hydrogen has high flammability. Thus, a certain proportion of hydrogen can be added in the natural gas (named HCNG) to improve combustion performance. In this work, the effect of hydrogen volume ratio on combustion characteristics was investigated on an optically accessible single-cylinder CNG-diesel engine using a Phantom v7.3 color camera. HCNG was compressed into the tank under different hydrogen volume ratios varied from 0% to 30%, while the energy substitution rate of` HCNG remained at 70%.

Hydrogen is a promising energy carrier because it is characterized by a fast combustion velocity, a wide range of sources, and clean combustion products. A hydrogen internal combustion engine (H2ICE) with a turbocharger has been used to solve the contradiction of power density and control NOx. However, the selection of a H2ICE compressor with a turbocharger is very different from traditional engines because of gas fuel. Hydrogen as a gas fuel has the same volume as its cylinder and thus increases pressure and reduces the mass flow rate of air in cylinder for a port fuel injection-H2ICE (PFI-H2ICE). In this study, a general method involving a H2ICE with a turbocharger is proposed by considering the effect of hydrogen on cylinders. Using this method, we can calculate the turbocharged pressure ratio and mass flow rate of air based on the target power and general parameters. This method also provides a series of intake temperatures of air before calculation to improve accuracy.

The combustion characteristics of hydrogen-air mixtures have significance significant impact on the performance and control of hydrogen-fueled internal combustion engines and the combustion velocity is an important parameter in characterizing the combustion characteristics of the mixture. A four-cylinder hydrogen internal combustion engine was used to study hydrogen combustion; the combustion characteristics of a hydrogen mixture were experimentally studied in a constant-volume incendiary bomb, and the turbulent premixed combustion characteristics of hydrogen were calculated and analyzed. Turbulent hydrogen combustion comes under the folded laminar flame model. The turbulent combustion velocity in lean hydrogen combustion is related not only to the turbulent velocity and the laminar burning velocity, but also to the additional turbulence term caused by the instability of the flame.

NOx are the only harmful emissions of hydrogen internal combustion engine. EGR is one of the effective methods to reduce NOx. The traditional EGR is not suitable for hydrogen internal combustion engine. Therefore, the study of influence of hot EGR on hydrogen internal combustion engine is important. A 2.0L hydrogen internal combustion engine with hot EGR system model is employed to optimize the diameter and position of hot EGR based on a simulation analysis. The result shows that both of the combustion temperature and NOx increase as EGR increases due to the rise of intake temperature for low load condition, for heavy load, with the increase of EGR rate, NOx emissions decreases slightly before the mixture equivalence ratio comes to 1and then dropped significantly after the mixture equivalence ratio greater than 1. Unburned hydrogen in TWC has the effect of reducing NOx after catalysts decrease largely.

Nowadays, the world is facing severe energy crisis and environment problems. Development of hydrogen fuel vehicles is one of the best ways to solve these problems. Due to the difficulties of infrastructures, such as the hydrogen transport and storage, hydrogen fuel vehicles have not been widely used yet. As a result, Hydrogen-gasoline dual-fuel vehicle is a solution as a compromise. In this paper, three way catalytic converter (TWC) was used to reduce emissions of hydrogen-gasoline dual-fuel vehicles. On wide open throttle and load characteristics, the conversion efficiency of TWC in gasoline engine was measured. Then the TWC was connected to a hydrogen internal combustion engine. After switching the hydrogen and gasoline working mode, emission data was measured. Experiment results show that the efficiency of a traditional TWC can be maintained above 85%., while it works in a hydrogen-gasoline dual-fuel alternative working mode.

Appropriate emergency response information is required for first responder before hydrogen fuel cell vehicles will become widespread. This paper investigates experimentally the hydrogen dispersion in the vicinity of a vehicle which accidentally releases hydrogen horizontally with a single volumetric flow of 2000 NL/min in the under-floor section while varying cross and frontal wind effects. This hydrogen flow rate represents normally a full throttle power condition. Forced wind was about maximum 2 m/s. The results indicated that the windward side of the vehicle was safe but that there were chiefly two areas posing risks of fire by hydrogen ignition. One was the leeward side of the vehicle's underbody where a larger region of flammable hydrogen dispersion existed in light wind than in windless conditions. The other was the area around the hydrogen leakage point where most of the leaked hydrogen remained undiffused in an environment with a wind of no stronger than 2 m/s.

Hydrogen concentration during combustion in a confined space with a ceiling was investigated. The results indicated that steady-state hydrogen concentration was highest at the ceiling surface for all hydrogen flow rates. When hydrogen concentration was 10-20%, weak flame propagation occurred at the ceiling surface, with the most easily burnable spots being dented areas such as seams, pores and creases on the ceiling surface. The unstable and limited nature of flame propagation at the ceiling surface was attributed to the relationship between temperature and hydrogen concentration in a confined space.

To investigate the events that could arise when fighting fires in vehicles with carbon fiber reinforced plastic (CFRP) hydrogen storage cylinders, we conducted experiments to examine whether a hydrogen jet diffusion flame caused by activation of the pressure relief device (PRD) can be extinguished and how spraying water influences the cylinder and PRD. The experiments clarified that the hydrogen jet flame cannot be extinguished easily with water or dry powder extinguishers and that spraying water during activation of the PRD may result in closure of the PRD, but is useful for maintaining the strength of CFRP composite cylinders for vehicles.

A single-cylinder Gasoline Direct Injection Engine (GDI) engine with a centrally mounted spray-guided injection system (150 bar fuel pressure) has been operated with stoichiometric and rich mixtures. The base fuel was 65% iso-octane and 35% toluene; hydrogen was aspirated into a plenum in the induction system, and its equivalence ratios were set to 0, 0.02, 0.05 and 0.1. Ignition timing sweeps were conducted for each operating point. Combustion was speeded up by adding hydrogen as expected. In consequence the MBT ignition advance was reduced, as were cycle-by-cycle variations in combustion. Adding hydrogen led to the expected reduction in IMEP as the engine was operated at a fixed manifold absolute pressure (MAP). An engine model has also been set up using WAVE. Particulate Matter (PM) emissions were measured with a Cambustion DMS500 particle sizer.

The SAE Fuel Cell Vehicle (FCV) Safety Working Group has been addressing FCV safety for over 9 years. The initial document, SAE J2578, was published in 2002. SAE J2578 has been valuable as a Recommended Practice for FCV development with regard to the identification of hazards and the definition of countermeasures to mitigate these hazards such that FCVs can be operated in the same manner as conventional gasoline internal combustion engine (ICE)-powered vehicles. SAE J2578 is currently being revised so that it will continue to be relevant as FCV development moves forward. For example, test methods were refined to verify the acceptability of hydrogen discharges when parking in residential garages and commercial structures and after crash tests prescribed by government regulation, and electrical requirements were updated to reflect the complexities of modern electrical circuits which interconnect both AC and DC circuits to improve efficiency and reduce cost.

The SAE FCV Safety Working Group has been addressing fuel cell vehicle (FCV) safety for over 8 years. The initial document, SAE J2578, was published in 2002. SAE J2578 has been valuable to FCV development with regard to the identification of hazards and the definition of countermeasures to mitigate these hazards such that FCVs can be operated in the same manner as conventional gasoline internal combustion engine (ICE)-powered vehicles. J2578 is currently being updated to clarify and update requirements so that it will continue to be relevant and useful in the future. An update to SAE J1766 for post-crash electrical safety was also published to reflect unique aspects of FCVs and to harmonize electrical requirements with international standards. In addition to revising SAE J2578 and J1766, the Working Group is also developing a new Technical Information Report (TIR) for vehicular hydrogen systems (SAE J2579).

The hydrogen consumption of fuel cell vehicles (FCV) can be measured by the gravimetric, pressure and flow methods within a ±1% error. These are the methods acknowledged by ISO and SAE [1, 2], but require the test vehicles to be modified in order to supply hydrogen from an external, rather than the onboard tank. Consequently, technical assistance of the vehicle manufacturer is necessary for this modification, while various components in the test vehicle must be readjusted. For these reasons, a measurement method free of vehicle modification is in great demand. The present study therefore developed an “oxygen balance method” which determines the amount of hydrogen that has reacted with oxygen in the fuel cell stack by measuring the oxygen concentration in exhaust gas.

If a compressed hydrogen tank for vehicles is filled with hydrogen gas more quickly, the gas temperature in the tank will increase. In this study, we conducted hydrogen gas filling tests using the TYPE 3 and TYPE 4 tanks. During the tests, we measured the temperature of the internal liner surface and investigated its relationship with the gas temperature in the tank. We found that the gas temperature in the upper portion of the TYPE 4 tank rose locally during filling and that the temperature of the internal liner surface near that area also rose, resulting in a temperature higher than the gas temperature at the center of the tank. To keep the maximum temperature in the tank below the designed temperature (85°C) during filling and examine the representative tank internal temperatures, it is important to examine filling methods that can suppress local rises of tank internal temperature.

Fuel cell vehicles represent a new system, and their safety has not yet been fully proved comparing with present automobile. Thorough safety evaluation is especially needed for the fuel system, which uses hydrogen as fuel, and the electric system, which uses a lot of electricity. The fuel cell stacks that are to be loaded on fuel cell vehicles generate electricity by reacting hydrogen and oxygen through electrolytic polymer membranes which is very thin. The safety of the fuel and electric systems should also be assessed for any abnormality that may be caused by electrolytic polymer membranes for any reasons. The purpose of our tests is to collect basic data to ultimately establish safety standards for fuel cell stacks. Methanol pool flame exposure tests were conducted on stationary use fuel cell stacks of two 200W to evaluate safety in the event of a fire.

hydrogen was leaked from the underfloor at a flow rate exceeding 131 NL/min (11.8 g/min), which is the allowable fuel leakage rate at the time of a collision of compressed hydrogen vehicles in Japan, and the resulting distribution of concentration in the engine compartment and the dispersion after stoppage of the leak were investigated. Furthermore, ignition tests were also conducted and the impact on the surroundings (mainly on human bodies) was investigated to verify the safety of the allowable leakage rate. The tests clarified that if hydrogen leaks from the underfloor at a flow rate of 1000 NL/min (89.9 g/min) and is ignited in the engine compartment, people around the vehicle will not be seriously injure. Therefore, it can be said that a flow rate of 131 NL/min (11.8 g/min), the allowable fuel leakage rate at the time of a collision of compressed hydrogen vehicles in Japan, assures a sufficient level of safety.

The distribution of concentrations of hydrogen leaking into the front compartment and the dispersion after the leak was stopped were investigated to obtain basic data for specifying the mounting positions of hydrogen leak detecting sensors and the threshold values of alarms for compressed hydrogen vehicles. Ignition tests were also conducted to investigate the flammability and the environmental impact (i.e. the impact on human bodies). These tests were also conducted with methane to evaluate the protection against hydrogen leaks in vehicles in comparison with natural gas (methane). We found that the concentration of hydrogen in the front compartment reached 23.7 vol% maximum when hydrogen gas was allowed to leak for 600 sec from the center of the bottom of the wheelbase at a rate of 131 NL/min, which is the allowable limit for a fuel leak at the time of collision of compressed hydrogen vehicles in Japan.

In this study, we evaluated the fire safety of vehicles that use compressed hydrogen as fuel. We conducted fire tests on vehicles that used compressed hydrogen and on vehicles that used compressed natural gas and gasoline and compared temperatures around the vehicle and cylinder, internal pressure of the cylinder, irradiant heat around the vehicle, sound pressure levels when the pressure relief device (PRD) was activated, and damage to the vehicle and surrounding flammable objects. The results revealed that vehicles equipped with compressed hydrogen gas cylinders are not more dangerous than CNC or gasoline vehicles, even in the event of a vehicle fire.

Japan Automobile Research Institute has devised and evaluated the various fuel consumption measurement methods for fuel cell vehicles (FCVs). The examination covers the methods based on measurement of electrical current, hydrogen pressure/temperature, weight and flow rate that are expected to be the same accuracy and convenience as conventional measurement methods such as carbon balance method or fuel flow measurement method. As a result of examining the measurement accuracy for each method with a sonic nozzle used as a standard, it is found that both the pressure method and the weight method fulfill the target accuracy of ±1% and that the flow method is able to improve the accuracy by means of calibration with hydrogen. Also, as a result of applying each method to the fuel consumption test of FCVs, the relative error between the pressure method and weight method is within ±1%.

A fuel cell (FC) powerplant is an electrochemical engine that converts fuel and an oxidant electrochemically into electric energy, water and other chemical byproducts. When hydrogen is used as the fuel, the only products of the electrochemical reactions are water and electric power. Other conventional and advanced powerplants for transportation, such as the internal combustion (IC) engine, the Diesel engine and others, are thermal combustion engines. The theoretical or thermodynamic efficiency of a fuel cell or electrochemical engine is much higher than the thermodynamic efficiency of a heat engine. The practical efficiency of a fuel cell is highest at partial load, whereas the practical efficiency of a heat engine is highest at maximum power. A survey is presented of the different fuel cell types and their characteristics. The proton-exchange-membrane (PEM) fuel cell is shown to be the best available fuel cell for transportation applications.