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Additive manufacturing was used to fabricate a head for an automotive-scale single-cylinder engine operating on natural gas. The head was consisted of a bimetallic composition of stainless steel and bronze. The engine performance using the bimetallic head was compared against the stock cast iron head. The heads were tested at two speeds (1200 and 1800 rpm), two brake mean effective pressures (6 and 10 bar), and two equivalence ratios (0.7 and 1.0). The bimetallic head showed good durability over the test and produced equivalent efficiencies, exhaust temperatures, and heat rejection to the coolant to the stock head. Higher combustion temperatures and advanced combustion phasing resulted from use with the bimetallic head. The implication is that with optimization of the valve timing, an efficiency benefit may be realized with the bimetallic head.

The Society of Automotive Engineers Fatigue Design & Evaluation Committee [SAE FD&E] is actively working on a total life project for weldments, in which the welding residual stress is a key contributor to an accurate assessment of fatigue life. Physics-based welding process simulation and various types of residual stress measurements were pursued to provide a representation of the residual stress field at the failure location in the fatigue samples. A well-controlled and documented robotic welding process was used for all sample fabrications to provide accurate inputs for the welding simulations. One destructive (contour method) residual stress measurement and several non-destructive residual stress measurements-surface X-ray diffraction (XRD), energy dispersive X-ray diffraction (EDXRD), and neutron diffraction (ND)-were performed on the same or similarly welded samples.

This study is a continuation of previous work assessing the robustness of a Cummins XPI common rail injection system operating with gasoline-like fuel. All the hardware from the original study was retained except for the high pressure pump head and check valves which were replaced due to cavitation damage. An additional 400 hour NATO cycle was run on the refurbished fuel system to achieve a total exposure time of 800 hours and detect any other significant failure modes. As in the initial investigation, fuel system parameters including pressures, temperatures and flow rates were logged on a test bench to monitor performance over time. Fuel and lubricant samples were taken every 50 hours to assess fuel consistency, metallic wear, and interaction between fuel and oil. High fidelity driving torque and flow measurements were made to compare overall system performance when operating with both diesel and light distillate fuel.

The application of polyalkylene glycol (PAG) as a base stock for engine oil formulation has been explored for substantial fuel economy gain over traditional formulations with mineral oils. Various PAG chemistries were explored depending on feed stock material used for manufacturing. All formulations except one have the same additive package. The friction performance of these oils was evaluated in a motored single cylinder engine with current production engine hardware in the temperature range 40°C-120°C and in the speed range of 500 RPM-2500 RPM. PAG formulations showed up to 50% friction reduction over GF-5 SAE 5W-20 oil depending on temperature, speed, and oil chemistry. Friction evaluation in a motored I-4 engine showed up to 11% friction reduction in the temperature range 40°C-100°C over GF-5 oil. The paper will share results on ASTM Sequence VID fuel economy, Sequence IVA wear, and Sequence VG sludge and varnish tests. Chassis roll fuel economy data will also be shared.

The effect of charge rate was determined using constant-current (CC) and the USABC Fast-Charge (FC) tests on commercial lithium-ion cells. Charging at high rates caused performance decline in the cells. Representing the resistance data as ΔR vs. Rn-1 plots was shown to be a viable method to remove the ambiguity inherent in the time-based analyses of the data. Comparing the ΔR vs. Rn-1 results, the change in resistance was proportional to charge rate in both the CC and FC cell data, with the FC cells displaying a greater rate of change. Changes, such as delamination, at the anode were seen in both CC and FC cells. The amount of delamination was proportional to charge rate in the CC cells. No analogous trend was seen in the FC cells; extensive delamination was seen in all cases. These changes may be due to the interaction of processes, such as lithium plating and i2R heating.

In order to ensure the safety of a structure, adequate strength for structural elements must be provided. Moreover, catastrophic deformations such as buckling must be prevented. Using the linear finite element method, deterministic buckling analysis is completed in two main steps. First, a static analysis is performed using an arbitrary ordinate applied loading pattern. Using the obtained element axial forces, the geometric stiffness of the structure is assembled. Second, an eigenvalue problem is performed between structure's elastic and geometric stiffness matrices, yielding the structure's critical buckling loads. However, these deterministic approaches do not consider uncertainty the structure's material and geometric properties. In this work, a new method for finite element based buckling analysis of a structure with uncertainty is developed. An imprecise probability formulation is used to quantify the uncertainty present in the mechanical characteristics of the structure.

Cavitation plays an important role in fuel injection systems. It alters the nozzle's internal flow structure and discharge coefficient, and also contributes to injector wear. Quantitatively measuring and mapping the cavitation vapor distribution in a fuel injector is difficult, as cavitation occurs on very short time and length scales. Optical measurements of transparent model nozzles can indicate the morphology of large-scale cavitation, but are generally limited by the substantial amount of scattering that occurs between vapor and liquid phases. These limitations can be overcome with x-ray diagnostics, as x-rays refract, scatter and absorb much more weakly from phase interfaces. Here, we present an overview of some recent developments in quantitative x-ray diagnostics for cavitating flows. Measurements were conducted at the Advanced Photon Source at Argonne National Laboratory, using a submerged plastic test nozzle.

Cavitation plays a significant role in high pressure diesel injectors. However, cavitation is difficult to measure under realistic conditions. X-ray phase contrast imaging has been used in the past to study the internal geometry of fuel injectors and the structure of diesel sprays. In this paper we extend the technique to make in-situ measurements of cavitation inside unmodified diesel injectors at pressures of up to 1200 bar through the steel nozzle wall. A cerium contrast agent was added to a diesel surrogate, and the changes in x-ray intensity caused by changes in the fluid density due to cavitation were measured. Without the need to modify the injector for optical access, realistic injection and ambient pressures can be obtained and the effects of realistic nozzle geometries can be investigated. A range of single and multi-hole injectors were studied, both sharp-edged and hydro-ground. Cavitation was observed to increase with higher rail pressures.

Lignin by-products from biorefineries has the potential to provide a low-cost alternative to petroleum-based precursors to manufacture carbon fiber, which can be combined with a binding matrix to produce a structural material with much greater specific strength and specific stiffness than conventional materials such as steel and aluminum. The market for carbon fiber is universally projected to grow exponentially to fill the needs of clean energy technologies such as wind turbines and to improve the fuel economies in vehicles through lightweighting. In addition to cellulosic biofuel production, lignin-based carbon fiber production coupled with biorefineries may provide $2,400 to $3,600 added value dry Mg−1 of biomass for vehicle applications. Compared to producing ethanol alone, the addition of lignin-derived carbon fiber could increase biorefinery gross revenue by 30% to 300%.

Over 250 million vehicles are operating on United States roads and highways and over 12 million of them reach the end of their useful lives annually. These end-of-life vehicles (ELVs) contain over 24 million tons (21.8 million metric tonnes) of materials including ferrous and non-ferrous metals, polymers, glass, and automotive fluids. They also contain many parts and components that are still useable and some that could be economically rebuilt or remanufactured. Dismantlers acquire the ELVs and recover from them parts for resale “as-is” or after remanufacturing. The dismantler then sells what remains of the vehicle, the “hulk”, to a shredder who shreds it to recover and sell the metals. Presently, the remaining non-metallic materials, commonly known as shredder residue, are mostly landfilled. The vehicle manufacturers, now more than ever, are working hard to build more energy efficient and safer, more affordable vehicles.

A sustainable activity is one that is economically attractive, environmentally friendly and provides a beneficial service to society in a safe and responsible manner. Having a sustainable operation is a target that today’s industries are striving to attain. The automotive industry and its products are major users of natural resources and a source of greenhouse emissions. In order to reduce its energy consumption and greenhouse emissions the industry is using more lightweighting materials in manufacturing its products. These materials include polymers, composites, aluminum and magnesium. The increased interest in hybrid vehicles will increase the need for new materials such as lithium, cobalt and nickel. At the same time, regulations are calling for recycling more of the obsolete vehicles. Replacing the steel, which is recyclable, with lighter materials will result in a reduction in the recycling rate of vehicles unless the lightweighting materials are recycled.

Microstructure level inhomogeneities between the harder martensite phase and the softer ferrite phase render the dual phase (DP) steels more complicated failure mechanisms and associated failure modes compared to the conventionally used low alloy homogenous steels. This paper examines the failure mode DP780 steel under different loading conditions using finite element analyses on the microstructure levels. Micro-mechanics analyses based on the actual microstructures of DP steel are performed. The two-dimensional microstructure of DP steel was recorded by scanning electron microscopy (SEM). The plastic work hardening properties of the ferrite phase was determined by the synchrotron-based high-energy X-ray diffraction technique. The work hardening properties of the martensite phase were calibrated and determined based on the uniaxial tensile test results. Under different loading conditions, different failure modes are predicted in the form of plastic strain localization.

The process of shredding end-of-life vehicles to recover metals results in a byproduct commonly referred to as shredder residue. The four and a half million metric tons of shredder residue produced annually in the United States is presently land filled. To meet the challenges of automotive materials recycling, the U.S. Department of Energy is supporting research at Argonne National Laboratory in cooperation with the Vehicle Recycling Partnership (VRP) of the United States Council for Automotive Research (USCAR) and the American Plastics Council. This paper presents the results of a study that was conducted by Argonne to determine variations in the composition of shredder residue from different shredders. Over 90 metric tons of shredder residues were processed through the Argonne pilot plant. The contents of the various separated streams were quantitatively analyzed to determine their composition and to identify materials that should be targeted for recovery.

Recovering metals from obsolete automobiles, home appliances, and other metal-containing obsolete durables and other scrap involves shredding these objects and separating the reusable metals from the shredded material by using magnets, eddy current separators, and metal detectors. Over 12 million automobiles are shredded annually in the United States alone, and almost all of the 4.5 million metric tonnes (5 million short tons) of the shredder residue produced in the United States annually is disposed of in landfills. Over 13.6 million tonnes (15 million tons) of shredder residue is generated worldwide every year. The rise in disposal costs is further exacerbated in that the percentage of shredder residue that must be disposed of, in comparison with the percentage of marketable recovered metals, is increasing because of the increasing content of polymers in automobiles and in home appliances.

The addition of metal nanoparticles to standard coolant fluids dramatically increases the thermal conductivity of the liquid. The properties of the prepared nanofluids will allow for lighter, smaller, and higher efficiency spacecraft thermal control systems to be developed. Nanofluids with spherical or rod-shaped metal nanoparticles were investigated. At a volume concentration of 0.5%, the room temperature thermal conductivity of a 2 nm spherical gold nanoparticle-water solution was increased by more than 10% over water alone. Silver nanorods increased the thermal conductivity of ethylene glycol by 53% and water by 26%.

Propagation-based and phase-enhanced x-ray imaging was developed as a unique metrology technique to visualize the internal structure of high-pressure fuel injection nozzles. We have visualized the microstructures inside 200-μm fuel injection nozzles in a 3-mm-thick steel housing using this novel technique. Furthermore, this new x-ray-based metrology technique has been used to directly study the highly transient needle motion in the nozzles in situ and in real-time, which is virtually impossible by any other means. The needle motion has been shown to have the most direct effect on the fuel jet structure and spray formation immediately outside of the nozzle. In addition, the spray cone-angle has been perfectly correlated with the numerically simulated fuel flow inside the nozzle due to the transient nature of the needle during the injection.

Preliminary work was conducted in the casting of magnesium using the lost foam casting process. The lost foam or expendable pattern casting (EPC) process is capable of making extremely complicated part shapes at acceptable soundness levels and with low manufacturing costs. Standard test shapes were used to determine the ability of the magnesium to fill the mold and to assess the types of defects encountered. This paper will briefly explain how this project evolved including the developmental strategies formed, the products selected, the casting trials performed, and the casting results.

When compared with new oil, used diesel engine oils exhibited thermal conductivity that increases as the concentration of soot increases. The magnitude of the effect depends on the oil composition, and on the size and dispersion of the soot particles. Although soot in engine oil is generally deleterious to engine performance from the standpoint of wear and deposits, no negative effects were observed on the thermal performance of the oil itself; indeed, even slight positive effects are expected for oils that maintain soot in stable dispersion. Therefore, the thermal challenge for engine oils in diesel engines that use exhaust gas recirculation will be to prevent soot deposition on engine surfaces.

Applying nanotechnology to thermal engineering, ANL has addressed the interesting and timely topic of nanofluids. We have developed methods for producing both oxide and metal nanofluids, studied their thermal conductivity, and obtained promising results: (1) Stable suspensions of nanoparticles can be achieved. (2) Nanofluids have significantly higher thermal conductivities than their base liquids. (3) Measured thermal conductivities of nanofluids are much greater than predicted. For these reasons, nanofluids show promise for improving the design and performance of vehicle thermal management systems. However, critical barriers to further development and application of nanofluid technology are agglomeration of nanoparticles and oxidation of metallic nanoparticles. Therefore, methods to prevent particle agglomeration and degradation are required.

In an effort to reduce fuel consumption and emissions, hybrid vehicles incorporating fuel cell systems are being developed by automotive manufacturers, their suppliers, federal agencies (specifically, the U.S. Department of Energy) and national laboratories. The fuel cell system will require an air management subsystem that includes a compressor/expander. Certain components in the compressor will require innovative lubrication technology in order to reduce parasitic energy losses and improve their reliability and durability. One such component is the air bearing for air turbocompressors designed and fabricated by Meruit, Inc. Argonne National Laboratory recently developed a carbon-based coating with low friction and wear attributes; this near-frictionless-carbon (NFC) coating is a potential candidate for use in turbocompressor air bearings. We presents here an evaluation of the Argonne coating for air compressor thrust bearings.