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Hydrogen nowadays is considered one promising energy carrier for future mobility scenarios. Its application as a fuel in ICEs greatly benefits from Direct Injection (DI) strategies, which help to reduce the disadvantages of PFI systems such as air displacement effects, knocking, backfiring and low power density. In SI-engines one appropriate way to increase efficiency is the reduction of wall heat losses by jet- and/or wall-guided mixture formation systems. In theory, Compression Ignition (CI) systems employing a diffusion type of combustion allow for a significant raise in compression ratio and, thus, are likely to excel the SI concept in terms of efficiency. The following paper deals with results obtained from investigations on H2 Compression-Ignition (H2-CI) combustion systems by employing both thermodynamic research engines and 3D CFD simulation.