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Technical Paper

Understanding Catalyst Overheating Protection (COP) as a Source of Post-TWC Ammonia Emissions from Petrol Vehicle

2022-08-30
2022-01-1032
TWC exposure to extreme temperature could result in irreversible damage or thermal failure. Thus, a strategy embedded in the engine control unit (ECU) called catalyst overheating protection (COP) will be activated to prevent TWC overheating. When COP is activated, the command air-fuel ratio will be enriched to cool the catalyst monolith down. Fuel enrichment has been proven a main prerequisite for ammonia formation in hot TWCs as a by-product of NOx reduction. Hence, COP events could theoretically be a source of post-catalyst ammonia from petrol vehicles, but this theory is yet to be confirmed in published literature. This paper validated this hypothesis using a self-programmed chassis-level test. The speed of the test vehicle was set to constant while the TWC temperature was raised stepwise until a COP event was activated.
Technical Paper

Experimental Study of B20 Combustion and Emission Characteristics under Several EGR Conditions

2015-04-14
2015-01-1078
It is found that biodiesel has a great potential to reduce the nitrogen oxides (NOx) and soot emissions simultaneously in low temperature combustion (LTC) mode. The objective of this study is to investigate the combustion and emission characteristics of 20% biodiesel blend diesel fuel (B20) under several exhaust gas recirculation (EGR) conditions for LTC application. An experimental investigation of B20 was conducted on a four-stroke common rail direct injection diesel engine at 2000rpm and 25% load condition. The EGR ratio was adjusted from 10% to 66%, and the injection pressure was tuned from 100MPa to 140MPa. The result showed that B20 generated less soot emission than conventional diesel with increasing EGR ratio, especially when the EGR ratio was beyond 30%. Soot emission increased with increasing EGR ratio up to 50% EGR, after which there is a steep decrease in particular matter (PM).
Technical Paper

A Study of Hydrogen Internal Combustion Engine EGR System

2014-04-01
2014-01-1071
NOx are the only harmful emissions of hydrogen internal combustion engine. EGR is one of the effective methods to reduce NOx. The traditional EGR is not suitable for hydrogen internal combustion engine. Therefore, the study of influence of hot EGR on hydrogen internal combustion engine is important. A 2.0L hydrogen internal combustion engine with hot EGR system model is employed to optimize the diameter and position of hot EGR based on a simulation analysis. The result shows that both of the combustion temperature and NOx increase as EGR increases due to the rise of intake temperature for low load condition, for heavy load, with the increase of EGR rate, NOx emissions decreases slightly before the mixture equivalence ratio comes to 1and then dropped significantly after the mixture equivalence ratio greater than 1. Unburned hydrogen in TWC has the effect of reducing NOx after catalysts decrease largely.
Technical Paper

Effects of Electrically Heated Catalyst on the Low Temperature Performance of Vanadium-Based SCR Catalyst on Diesel Engine

2014-04-01
2014-01-1527
The NOx conversion efficiency of vanadium-based SCR catalyst is lower under low temperature. Utilizing an exhaust analyzer, the effects of electrically heated catalyst on the performance of vanadium-based SCR catalyst under low temperature was studied on the engine test bench. The inlet temperature of SCR catalyst without the electrically heated catalyst were in the range of 150°C∼270°C under various steady engine modes, and the NSR (Normalized Stoichiometric Ratio) was set as 0.4,0.6,0.8,1.0. The results showed that under the space velocity of 20000h−1, with the application of the electrically heated catalyst, the inlet temperature of SCR increased about 19.9°C on average and the NOx conversion efficiency improved about 8.0%. The NOx conversion efficiency increased 1.7%∼8.6% at the temperatures of 150°C∼174°C, and 1.0%∼15.9% at the temperatures of 186°C∼270°C.
Technical Paper

A Study of the Adaptability of Three Way Catalytic Converter under Hydrogen-Gasoline Dual-Fuel Alternate Working Mode

2014-04-01
2014-01-1342
Nowadays, the world is facing severe energy crisis and environment problems. Development of hydrogen fuel vehicles is one of the best ways to solve these problems. Due to the difficulties of infrastructures, such as the hydrogen transport and storage, hydrogen fuel vehicles have not been widely used yet. As a result, Hydrogen-gasoline dual-fuel vehicle is a solution as a compromise. In this paper, three way catalytic converter (TWC) was used to reduce emissions of hydrogen-gasoline dual-fuel vehicles. On wide open throttle and load characteristics, the conversion efficiency of TWC in gasoline engine was measured. Then the TWC was connected to a hydrogen internal combustion engine. After switching the hydrogen and gasoline working mode, emission data was measured. Experiment results show that the efficiency of a traditional TWC can be maintained above 85%., while it works in a hydrogen-gasoline dual-fuel alternative working mode.
Journal Article

Effects of 7, 9, and 10 psi Vapor Pressure Fuels on Multi-Day Diurnal Evaporative Emissions of Tier 2 and LEV II Vehicles

2013-04-08
2013-01-1057
In order to meet more stringent evaporative emissions requirements, multiple advancements in vehicle fuel system and carbon canister technologies have been made. Regardless of technological advancements, the vapor pressure of the fuel remains a vital property in controlling evaporative emissions. A series of tests were performed to explore the effects of vapor pressure on multiday diurnal evaporative emissions for 9 and 10 psi Reid Vapor Pressure (RVP) 10% ethanol (E10) gasoline-blend fuels, followed by tests with 7 psi RVP E10 gasoline on a subset of the same vehicles. A test procedure was developed to monitor evaporative emissions, canister loading profiles and breakthrough emissions for each of the fuels. A total of five vehicles were tested on all 3 fuels, blended to represent 7, 9, and 10 psi at sea level. Tests were run over 14 days using the United States (U.S.)
Technical Paper

Impact of Ignition Energy Phasing and Spark Gap on Combustion in a Homogenous Direct Injection Gasoline SI Engine Near the EGR Limit

2013-04-08
2013-01-1630
For spark-ignition gasoline engines operating under the wide speed and load conditions required for light duty vehicles, ignition quality limits the ability to minimize fuel consumption and NOx emissions via dilution under light and part load conditions. In addition, during transients including tip-outs, high levels of dilution can occur for multiple combustion events before either the external exhaust gas can be adjusted and cleared from the intake or cam phasing can be adjusted for correct internal dilution. Further improvement and a thorough understanding of the impact of the ignition system on combustion near the dilution limit will enable reduced fuel consumption and robust transient operation. To determine and isolate the effects of multiple parameters, a variable output ignition system (VOIS) was developed and tested on a 3.5L turbocharged V6 homogeneous charge direct-injection gasoline engine with two spark plug gaps and three ignition settings.
Technical Paper

Renewable Ethanol Use for Enabling High Load Clean Combustion in a Diesel Engine

2013-04-08
2013-01-0904
As a renewable energy source, the ethanol fuel was employed with a diesel fuel in this study to improve the cylinder charge homogeneity for high load operations, targeting on ultra-low nitrogen oxides (NOx) and smoke emissions. A light-duty diesel engine is configured to adapt intake port fuelling of the ethanol fuel while keeping all other original engine components intact. High load experiments are performed to investigate the combustion control and low emission enabling without sacrificing the high compression ratio (18.2:1). The intake boost, exhaust gas recirculation (EGR) and injection pressure are independently controlled, and thus their effects on combustion and emission characteristics of the high load operation are investigated individually. The low temperature combustion is accomplished at high engine load (16~17 bar IMEP) with regulation compatible NOx and soot emissions.
Technical Paper

Impact of Fuel Metal Impurities on the Durability of a Light-Duty Diesel Aftertreatment System

2013-04-08
2013-01-0513
Alkali and alkaline earth metal impurities found in diesel fuels are potential poisons for diesel exhaust catalysts. Using an accelerated aging procedure, a set of production exhaust systems from a 2011 Ford F250 equipped with a 6.7L diesel engine have been aged to an equivalent of 150,000 miles of thermal aging and metal exposure. These exhaust systems included a diesel oxidation catalyst (DOC), selective catalytic reduction (SCR) catalyst, and diesel particulate filter (DPF). Four separate exhaust systems were aged, each with a different fuel: ULSD containing no measureable metals, B20 containing sodium, B20 containing potassium and B20 containing calcium. Metals levels were selected to simulate the maximum allowable levels in B100 according to the ASTM D6751 standard. Analysis of the aged catalysts included Federal Test Procedure emissions testing with the systems installed on a Ford F250 pickup, bench flow reactor testing of catalyst cores, and electron probe microanalysis (EPMA).
Journal Article

HC Traps for Gasoline and Ethanol Applications

2013-04-08
2013-01-1297
In-line hydrocarbon (HC) traps are not widely used to reduce HC emissions due to their limited durability, high platinum group metal (PGM) concentrations, complicated processing, and insufficient hydrocarbon (HC) retention temperatures required for efficient conversion by the three-way catalyst component. New trapping materials and system architectures were developed utilizing an engine dynamometer test equipped with dual Fourier Transform Infrared (FTIR) spectrometers for tracking the adsorption and desorption of various HC species during the light-off period. Parallel laboratory reactor studies were conducted which show that the new HC trap formulations extend the traditional adsorption processes (i.e., based on physic-sorption and/or adsorption at acid sites) to chemical reaction mechanisms resulting in oligomerized, dehydro-cyclization, and partial coke formation.
Technical Paper

Advanced Urea SCR System Study with a Light Duty Diesel Vehicle

2012-04-16
2012-01-0371
U.S. federal vehicle emission standards effective in 2007 require tight control of NOx and hydrocarbon emissions. For light-duty vehicles, the current standard of Tier 2 Bin 5 is about 0.07 g/mi NOx and 0.09 g/mi NMOG (non-methane organic gases) at 120,000 mi. However, the proposed future standard is 0.03 g/mi for NMOG + NOx (~SULEV30) at 150,000 mi. There is a significant improvement needed in catalyst system efficiencies for diesel vehicles to achieve the future standard, mainly during cold start. In this study, a less than 6000 lbs diesel truck equipped with an advanced urea Selective Catalytic Reduction (SCR) system was used to pursue lower tailpipe emissions with an emphasis on vehicle calibration and catalyst package. The calibration was tuned by optimizing exhaust gas recirculation (EGR) fuel injection and cold start strategy to generate desirable engine-out emissions balanced with reasonable temperatures.
Technical Paper

A Visualization Test Setup for Investigation of Water-Deposit Interaction in a Surrogate Rectangular Cooler Exposed to Diesel Exhaust Flow

2012-04-16
2012-01-0364
Exhaust gas recirculation (EGR) coolers are commonly used in diesel engines to reduce the temperature of recirculated exhaust gases in order to reduce NOx emissions. The presence of a cool surface in the hot exhaust causes particulate soot deposition as well as hydrocarbon and water condensation. Fouling experienced through deposition of particulate matter and hydrocarbons results in degraded cooler effectiveness and increased pressure drop. In this study, a visualization test setup is designed and constructed so that the effect of water condensation on the deposit formation and growth at various coolant temperatures can be studied. A water-cooled surrogate rectangular channel is employed to represent the EGR cooler. One side of the channel is made of glass for visualization purposes. A medium duty diesel engine is used to generate the exhaust stream.
Technical Paper

EGR and Swirl Distribution Analysis Using Coupled 1D-3D CFD Simulation for a Turbocharged Heavy Duty Diesel Engine

2011-09-13
2011-01-2222
A new diesel engine, called the 6.7L Power Stroke® V-8 Turbo Diesel and code named "Scorpion" was designed and developed by Ford Motor Company for the full-size pickup truck and light commercial vehicle markets. A high pressure Exhaust Gas Recirculation (EGR) layout in combination with a Variable Geometry Turbine (VGT) is used to deliver cooled EGR for in-cylinder NOx reduction. The cylinder-to-cylinder variation of EGR and swirl ratio is tightly controlled by the careful design of the EGR mixer and intake system flow path to reduce variability of cylinder-out PM and NOx emissions. 3D-CFD studies were used to quickly screen several EGR mixer designs based on mixing efficiency and pressure drop considerations. To optimize the intake system, 1D-3D co-simulation methodology with AVL-FIRE and AVL-BOOST has been used to assess the cylinder-to-cylinder EGR distribution and dynamic swirl.
Technical Paper

Benchmarking of an Open Source CFD Process for Aerodynamics Prediction of Multiple Vehicle Types

2011-04-12
2011-01-0163
A benchmark study was conducted to assess the capability of an open source CFD based process to accurately simulate the physics of the flow field around various vehicle types. The ICON FOAMpro process was used to simulate the flow field of four baseline geometries of a Truck, CD-Car, B-Car and an SUV. Further studies were carried out to assess the effects of geometry variations on the predicted aerodynamic lift and drag. A Detached-Eddy Simulation (DES) approach was chosen for the benchmarks. In addition to aerodynamic lift and drag values, the results for surface pressure data, surface and wake flow fields were calculated. These results were compared with values obtained using Ford's existing CFD processes.
Technical Paper

Numerical Study of Ultra Low Solidity Airfoil Diffuser in an Automotive Turbocharger Compressor

2009-04-20
2009-01-1470
For the application of advanced clean combustion technologies, such as diesel HCCI/LTC, a compressor with high efficiency over a broad operation range is required to supply a high amount of EGR with minimum pumping loss. A compressor with high pitch of vaneless diffuser would substantially improve the flow range of the compressor, but it is at the cost of compressor efficiency, especially at low mass flow area where most of the city driving cycles resides. In present study, an ultra low solidity compressor vane diffuser was numerically investigated. It is well known that the flow leaving the impeller is highly distorted, unsteady and turbulent, especially at relative low mass flow rate and near the shroud side of the compressor. A conventional vaned diffuser with high stagger angle could help to improve the performance of the compressor at low end. However, adding diffuser vane to a compressor typically restricts the flow range at high end.
Technical Paper

Accessory Drive Belt Pulley Entry Friction Study and Belt Chirp Noise

1999-05-17
1999-01-1709
Accessory belt “chirp” noise is a major quality issue in the automotive and truck industry. Chirp noise control is often achieved by very tight pulley alignment, a guideline being .33 degree maximum belt entry angle into each grooved pulley. Occasionally belts will chirp at pulleys where the system alignment is this good or better. This study offers an explanation for such occurrences. This is a study to see if fundament groove side sticking theory correlates with the belt entry angle, and how the coefficient of friction relates to this entry angle. The study combines theory with lab data. In summary, the study fundamentally links the coefficient of friction of the belt to the belt chirp noise phenomenon, and allows the projection of a belt's general tendency to chirp to be predicted by the measurement of belt coefficient of friction on a test stand.
Technical Paper

Stoichiometric Air-Fuel Ratio Control Analysis

1981-02-01
810274
A great deal of current automotive engineering effort involves the development of three-way catalyst-based emission control systems that seek to minimize fuel consumption while simultaneously meeting stringent exhaust emission standards. Mitigation of emissions is enhanced in a three-way catalyst system when the system air-fuel ratio (A/F) is in proximity to ideal burning or stoichiometry. This paper is concerned with extending methods used for determining engine calibrations to closed-loop systems with three-way catalysts. The paper presents a simulation model that employs experimentally obtained data to characterize the A/F control loop.
Technical Paper

Automotive Electronics in the 80’s

1980-08-01
800921
This paper discusses the growing use of electronics to provide improved fuel economy and control of engine emissions. The advantages of electronic engine controls are outlined, transducers utilized in a 1980 EEC III CFI application are described, and potential future expansion of electronic engine control is discussed.
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