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Compared with diesel fuel, FAME is relatively unstable and readily generates acids such as acetic acid and propionic acid. When FAME-blended diesel fuel is used in existing diesel vehicles, it is important to maintain the concentration of FAME-origin acid in the fuel at an appropriately low level to assure vehicle safety. In the present study, the oxidation of diesel fuel containing 5% FAME is investigated. Several kinds of FAMEs were examined, including reagents such as methyl linoleate and methyl linolenate, as well as commercially available products. The level of acid, peroxide, water, and methanol and the pressure of the testing vessel were measured. The result shows that unsaturated FAMEs that have two or more double bonds are unstable. Also, water is generated by oxidation of FAME blended diesel fuel, accelerating corrosion of the terne sheet.

The Agency of Natural Resources and Energy, Ministry of Economy, Trade and Industry has conducted conformity tests of diesel fuel containing Fatty Acid Methyl Ester (FAME) to amend diesel fuel standards in Japan. The objective of the tests is to examine appropriate specifications of diesel fuel containing FAME for automotive use for existing vehicles in the Japanese market. The conformity testing includes verification of fuel system component compatibility, tail pipe emissions, and characterization of the reliability and durability of the engine system, including the fuel injection system. In designing the conformity tests, the maximum FAME concentration was 5%. Most of the new standards are essentially equivalent to EN14214, but the total acid number (TAN) of specific acids, and oxidation stability of the new standards for diesel fuel containing FAME, are different from EN14214.

Fuels of wide range of density and viscosity were tested by using a DI diesel engine that conforms to present Japanese regulations. A total of 9 fuels was tested. Six test fuels were commercial automotive diesel fuel available in Japan. In order to expand the density range, test fuels of kerosene, high-density diesel fuel and automotive diesel fuel in Singapore were also included. The density range was 0.796 to 0.856 (g/cm3), and the viscosity range was 1.52 to 5.44 (mm2/s). The test mode was Japanese D13. Also, some fuels were tested by the Japanese transient test mode. Moreover, fuel spray was observed by an optical method to clarify the relationship between viscosity and Sauter mean diameter.