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TWC exposure to extreme temperature could result in irreversible damage or thermal failure. Thus, a strategy embedded in the engine control unit (ECU) called catalyst overheating protection (COP) will be activated to prevent TWC overheating. When COP is activated, the command air-fuel ratio will be enriched to cool the catalyst monolith down. Fuel enrichment has been proven a main prerequisite for ammonia formation in hot TWCs as a by-product of NOx reduction. Hence, COP events could theoretically be a source of post-catalyst ammonia from petrol vehicles, but this theory is yet to be confirmed in published literature. This paper validated this hypothesis using a self-programmed chassis-level test. The speed of the test vehicle was set to constant while the TWC temperature was raised stepwise until a COP event was activated.

As a new type of energy, free-piston linear generator (FPLG) attracts more research on its stable operation and power performance, while less on its combustion and emission performance. So, in this paper, the emission characteristics of FPLG in two different modes are studied through a port fuel injection (PFI) mode which was verified by the experiment and a gasoline direct injection (GDI) mode. The results showed that: both the GDI mode and the PFI mode produced large amounts of nitrogen oxide (NOx) during the working process. But the GDI mode produced before the PFI mode and it produced nearly 2 times than the PFI mode. However, the formation rate of NOx in GDI mode is much lower than that in PFI mode. Meanwhile, in both modes, 90% of NOX was generated in the cylinder at the temperature higher than 1750K, and only about 10% of NOX was generated at a temperature lower than 1750K.

Hydrogen fuel is a future energy to solve the problems of energy crisis and environmental pollution. Hydrogen internal combustion engines can combine the advantage of hydrogen without carbon pollution and the main basic structure of the traditional engines. However, the power of the port fuel injection hydrogen engines is smaller than the same volume gasoline engine because the hydrogen occupies the volume of the cylinder and reduces the air mass flow. The turbocharger can increase the power of hydrogen engines but also increase the NOx emission. Hence, a comprehensive controlling strategy to solve the contradiction of the power, BTE and NOx emission is important to improve the performance of hydrogen engines. This paper shows the controlling strategy for a four-stroke, 2.3L hydrogen engine with a turbocharger. The controlling strategy divides the operating conditions of the hydrogen engine into six parts according to the engine speeds and loads.

HTL is a kind of biodiesel converted from wet biowaste via hydrothermal liquefaction (HTL), which has drawn increasing attention in recent years due to its wide range of raw materials (algae, swine manure, and food processing waste). However, from the previous experiments done in a constant volume chamber, it was observed that the presence of 20% of HTL in the blend produced as much soot as pure diesel at in chamber environment oxygen ratio of 21%, and even more soot at low oxygen ratios. It was also observed that n-butanol addition could reduce the soot emission of diesel significantly under all tested conditions. In this work, the spray and combustion characteristics of HTL and diesel blends with n-butanol added were investigated in a constant volume chamber. The in-chamber temperature and oxygen ranged from 800 to 1200 K and 21% to 13%, respectively, covering both conventional and low-temperature combustion (LTC) regimes.

This study employed a diesel particulate generator (DPG), with an installed engine oil injector for soot and ash accumulation in a diesel particulate filter (DPF). Ash was generated by engine oil injection into the diesel burner flame. The amount of soot accumulation per loading varied from 0.5 g/L to 8 g/L while ash accumulation amount per loading was maintained at 0.5 g/L. Initially, ash accumulation distribution in the DPF was visualized using X-ray computed tomography (CT). It was revealed that the form of ash accumulation changed depending on the amount of soot accumulation before active regeneration, i.e., a large amount of soot accumulation resulted in plug ash, whereas a small amount of soot accumulation resulted in wall ash. To clarify ash accumulation mechanisms, soot and ash transport behavior in DPF during active regeneration process was directly observed using a high-speed camera through an optically accessible D-shaped cut DPF covered with a quartz glass plate.

This work investigated the mechanism of oil dilution by post injection to remove accumulated particulate matter on the diesel particulate filter of diesel engines. We developed a model to simulate post injection spray under low ambient gas pressure conditions. The model can predict the quantity of fuel mass adhered on the cylinder wall. The adhered fuel enters oil sump through the piston ring and cause oil dilution. The fuel in diluted oil evaporates during normal engine operations. We focus on the mechanism of fuel evaporation from diluted oil. The effects of engine speed and oil temperature on the evaporation were investigated. The results showed that the fuel evaporation rate increases with increasing engine speed and oil temperature. Furthermore, we developed an empirical model to predict the fuel evaporation rate of diluted oil through regression analysis with measured data.

Flash boiling has drawn much attention recently for its ability to enhance spray atomization and vaporization, while providing better fuel/air mixing for gasoline direct injection engines. However, the behaviors of flash boiling spray with multi-component fuels have not been fully discovered. In this study, isooctane, ethanol and the mixtures of the two with three blend ratios were chosen as the fuels. Measurements were performed with constant fuel temperature while ambient pressures were varied to adjust the superheated degree. Macroscopic and microscopic characteristics of flash boiling spray were investigated using Diffused Back-Illumination (DBI) imaging and Phase Doppler Anemometry (PDA). Comparisons between flash boiling sprays with single component and binary fuel mixtures were performed to study the effect of fuel properties on spray structure as well as atomization and vaporization processes.

The spray structure and vaporization processes of flash-boiling sprays in a constant volume chamber under a wide range of superheated conditions were experimentally investigated by a high speed imaging technique. The Engine Combustion Network’s Spray G injector was used. Four fuels including gasoline, ethanol, and gasoline-ethanol blends E30 and E50 were investigated. Spray penetration length and spray width were correlated to the degree of the superheated degree, which is the ratio of the ambient pressure to saturated vapor pressure (pa/ps). It is found that parameter pa/ps is critical in describing the spray transformation under flash-boiling conditions. Three distinct stages namely the slight flash-boiling, the transition flash-boiling, and the flare flash-boiling are identified to describe the transformation of spray structures.

There are a few different ways in which biofuels can be sourced, with the most popular coming from agricultural sources. An alternative approach is to utilize biowaste. An estimated 20 million dry tons of volatile organic compounds, or biowaste, is annually deposited in US municipal wastewaters. Most of this biowaste energy content is not recovered and, as a result, the biowaste could be a massive potential source of renewable energy. Biocrude diesel is converted from wet biowaste via hydrothermal liquefaction (HTL). Three types of feedstocks (algae, swine manure, and food processing waste) were converted into biocrude oil via HTL. From the previous experiments done in an AVL 5402 single-cylinder diesel engine, it was observed that the presence of 20% of HTL in the blend performed similarly during combustion to pure diesel. By studying these mixtures in a constant volume chamber, these observations could be compared to the results in the diesel engine.

To meet the strict emission regulations for diesel engines, an advanced processing device such as a Urea-SCR (selective catalytic reduction) system is used to reduce NOx emissions. The Real Driving Emissions (RDE) test, which is implemented in the European Union, will expand the range of conditions under which the engine has to operate [1], which will lead to the construction of a Urea-SCR system capable of reducing NOx emissions at lower and higher temperature conditions, and at higher space velocity conditions than existing systems. Simulations are useful in improving the performance of the urea-SCR system. However, it is necessary to construct a reliable NOx reduction model to use for system design, which covers the expanded engine operation conditions. In the urea-SCR system, the mechanism of ammonia (NH3) formation from injected aqueous urea solution is not clear. Thus, it is important to clarify this mechanism to improve the NOx reduction model.

Ignition location is one of the important factors that affect the thermal efficiency, exhaust emissions and knock sensitivity in premixed-charge ignition engines. However, the ignition initiation locations of pre-chamber generated turbulent jet ignition, which is a promising ignition enhancement method, are not clearly understood due to the complex physics behind it. Motivated by this, the ignition initiation location of a transient turbulent jet in a constant volume combustor is analyzed by the use of computational fluid dynamics (CFD) simulations. In the CFD simulations of this work, commercial codes KIVA-3 V release 2 and an in-house-developed chemical solver with a detailed mechanism for H2/air mixtures are used. Comparisons are performed between simulated and experimental ignition initiation locations, and they agree well with one another. A detailed parametric study of the influence of in-cylinder temperature on the ignition initiation location is also performed.

Light-duty China-6, which is among the most stringent vehicle exhaust emission standards globally, mandates the monitoring and reporting of real driving emissions (RDE) from July, 2023. In the process of regulation promulgation and verification, more than 300 RDE tests have been performed on over 50 China-5 and China-6 certified models. This technical paper endeavors to summarize the experience of RDE practice in China, and discuss the impacts of some boundary conditions (including vehicle dynamic parameters, data processing methods, hybrid propulsion and testing altitude) on the result of RDE measurement. In general, gasoline passenger cars confront few challenges to meet the upcoming RDE NOx requirement, but some China-5 certified samples, even powered by naturally-aspirated engines may have PN issues. PN emissions from some GDI-hybrid powertrain systems also need further reduction to meet China-6 RDE requirements.

Particulate matter emissions are becoming a big issue for GDI engines as the emission regulations being more stringent. Methanol has been considered to be an important alternative fuel to reduce soot emissions. To understand the effect of methanol addition on soot and polycyclic aromatic hydrocarbons (PAHs) formation, the 2-D distributions of soot volume fraction and different size PAHs relative concentrations in methanol/gasoline laminar diffusion flames were measured by TC-LII and PLIF techniques. The effect of methanol was investigated under the conditions of the same carbon flow and the same flame height. The methanol volume fraction was set as M0/20/40/60/80. The results showed that the natural luminescent flame lift-off height and soot lift-off height increases consistently with the increasing methanol content due to the increase of outlet velocity of fuel vapor.

White smoke emission is observed at the tailpipe of diesel vehicles when unburned hydrocarbons (HCs) are adsorbed on a diesel oxidation catalyst (DOC) under low exhaust gas temperature. The purpose of this study is to gain a better understanding of white smoke emission derived from HCs, and to reduce emission levels. First, the components of HCs and the particle size distribution of white smoke emission were analyzed. It was clarified that semi-volatile organic compounds (SVOC) and water are condensed around soluble organic fraction and the order of particle size in white smoke is submicron scale. Additionally, the correlation between the behavior of white smoke emission and the amount/quality of HCs adsorbed on a DOC were investigated by examining the change of zeolite content in the DOC. It was found that the heavy HCs ratio in adsorbed HCs on DOC increases with a decrease in zeolite content when DOC inlet gas temperature is 120 °C.

In the urea SCR system, urea solution is injected by injector installed in the front stage of the SCR catalyst, and NOx can be purified on the SCR catalyst by using NH3 generated by the chemical reaction of urea. NH3 is produced by thermolysis of urea and hydrolysis of isocyanic acid after evaporation of water in the urea solution. But, biuret and cyanuric acid which may cause deposit are sometimes generated by the chemical reactions without generating NH3. Spray behavior and chemical reaction of urea solution injected into the tail-pipe are complicated. The purpose of this study is to reveal the spray behavior and NH3 generation process in the tail-pipe, and to construct the model capable of predicting those accurately. In this report, the impingement spray behavior is clarified by scattered light method in high temperature flow field. Liquid film adhering to the wall and deposit generated after evaporation of water from the liquid film are photographed by the digital camera.

Methanol has been regarded as a potential transportation fuel due to its advanced combustion characteristics and flexible source. However, it is suffering from misfire and high HC emissions problems under cold start and low load conditions either on methanol SI engine or on methanol/diesel dual fuel engine. Hydrogen is a potential addition that can enhance the combustion of methanol due to its high flammability and combustion stability. In the current work, the effect of hydrogen fraction on the laminar flame characteristics of methanol- hydrogen-air mixture under varied equivalence ratio was investigated on a constant volume combustion chamber system coupled with a schlieren setup. Experiments were performed over a wide range of equivalence ratio of the premixed charge, varied from 0.8 to 1.4, as well as different hydrogen fraction, 0%, 5%, 10%, 15% and 20% (n/n). All tests were carried out at fixed temperature and pressure of 400K and 0.1MPa.

CNG-diesel dual fuel combustion mode has been regarded as a practical operation strategy because it not only can remain high thermal efficiency but also make full use of an alternative fuel, natural gas. However, it is suffering from misfire and high HC emissions under cold start and low load conditions. As known, hydrogen has high flammability. Thus, a certain proportion of hydrogen can be added in the natural gas (named HCNG) to improve combustion performance. In this work, the effect of hydrogen volume ratio on combustion characteristics was investigated on an optically accessible single-cylinder CNG-diesel engine using a Phantom v7.3 color camera. HCNG was compressed into the tank under different hydrogen volume ratios varied from 0% to 30%, while the energy substitution rate of` HCNG remained at 70%.

The diesel low temperature combustion (LTC) can keep high efficiency and produce low emission. Which has been widely studied at home and abroad in recent years. The combustion control parameters, such as injection pressure, injection timing, intake oxygen concentration, intake pressure, intake temperature and so on, have an important influence on the combustion and emission of diesel LTC. Therefore, to realize different combustion modes and combustion mode switch of diesel engine, it is necessary to accurately control the injection parameters and intake parameters of diesel engine. In this work, experimental study has been carried out to analyze the effect of intake oxygen concentration, intake pressure and intake temperature in combustion and emission characteristics of diesel LTC, such as in-cylinder pressure, temperature, heat release rate, NOx and soot emission.

The electronic control of direct injection fuel system, which could improve engine fuel efficiency, dynamics and engine emission performance through good atomization, precise control of fuel injection time and improvement of fuel-gas mixture, is the key technology to achieve the stratified combustion and lean combustion. In this paper, a direct injection injector that based on voice coil motor was designed aiming at the technical characteristics of one 800cc two-stroke cam-less engine. Prior to a one - dimensional simulation model of injector was established by AMEsim and the maximal fuel injection demand was met via the optimization of the main parameters of the injector, the structure of the voice coil motor was optimized by magnetic equivalent circuit method. After that, the maximal flow rate of the injector was verified by the injector bench test while the atomization characteristic of the injector was verified by using a high-speed camera.

Bio-butanol has been widely investigated as a promising alternative fuel. However, the main issues preventing the industrial-scale production of butanol is its relatively low production efficiency and high cost of production. Acetone-butanol-ethanol (ABE), the intermediate product in the ABE fermentation process for producing bio-butanol, has attracted a lot of interest as an alternative fuel because it not only preserves the advantages of oxygenated fuels, but also lowers the cost of fuel recovery for individual component during fermentation. If ABE could be directly used for clean combustion, the separation costs would be eliminated which save an enormous amount of time and money in the production chain of bio-butanol.