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Our earlier experimental study has shown that exhaust unburnt hydrocarbon emissions from spark-ignition engines can be reduced effectively by using in-cylinder catalysts on the surface of the piston top-land crevice. In order to improve the understanding of the process and mechanism by means of which unburnt hydrocarbon emissions are reduced, a phenomenological mathematical model was developed for catalytic oxidation processes in the piston-ring-pack crevice. This paper describes in details the modelling of the processes of the gas flow, mass diffusion and reaction kinetics in the crevices. The flow in the crevices is assumed to be isothermal and at the temperature of the piston crown surface. The overall rate of reaction is calculated using expressions for mass diffusion for laminar flows in channels and a first-order Arrhenius-type expression for catalytic reaction kinetics of hydrocarbon oxidation over platinum.

A novel approach was proposed and investigated to reduce unburned hydrocarbon emissions from spark-ignition engines using in-cylinder catalysts. The unburned hydrocarbons in spark-ignition engines arise primarily from sources near the combustion chamber walls, such as flame quenching at the entrance of crevice volumes and at the combustion chamber wall, and the absorption and desorption of fuel vapour into oil layers on the cylinder wall. The proximity of these sources of unburned hydrocarbons to the wall means that they can be reduced significantly by simply using in-cylinder catalysts on the combustion chamber walls, in particular on the surfaces of the crevice volumes. A platinum-rhodium coating was deposited on the top and side surfaces of the piston crown, and its effects on the engine combustion and emission characteristics were examined in this experimental investigation.