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With the advantages of flexible size and high energy density etc., pouch-type lithium ion battery cells with large capacity have been found more and more applications in electric vehicles. For these large-scale battery cells, thermal uniformity is vital for their safety and cycle life. To be specific, temperature gradients are expected to cause different degradation rates of active materials in different areas, which is possible to cause early failure or even fire and explosion of the battery cell. Thus, it is necessary to illustrate the batterie’s thermal uniformity in detail under different operating conditions. This work investigated the thermal uniformity of two 36 Ah pouch-type NCM/C battery cells with different sizes using both the thermal imaging method and thermoelectric effect method with K-type thermocouples. Experimental results show that there is an obvious temperature gradient on the surface of the pouch-type battery cell.