Search Results

In this study, engine-out gaseous emissions are reviewed using the Fourier Transform Infrared (FTIR) spectroscopy measurement of methanol diesel dual fuel combustion experiments performed in a heavy-duty diesel engine. Comparison to the baseline diesel-only condition shows that methanol-diesel dual fuel combustion leads to higher regulated carbon monoxide (CO) emissions and unburned hydrocarbons (UHC). However, NOX emissions were reduced effectively with increasing methanol substitution rate (MSR). Under dual-fuel operation with methanol, emissions of nitrogen oxides (NOX), including nitric oxide (NO), nitrogen dioxide (NO2), and nitrous oxide (N2O), indicate the potential to reduce the burden of NOX on diesel after-treatment devices such as selective catalytic reduction (SCR).

Pouch cells are increasingly popular form factors for the construction of energy storage systems in electric vehicles of all classes. Knowledge of the stress generated by these higher capacity pouch cells is critical to properly design battery modules and packs for both normal and abnormal operation. Existing literature predominantly offers data on smaller pouch cells with capacities of less than 10 Ah, leaving a gap in our understanding of the behavior of these larger cells. This experimental study aimed to bridge this knowledge gap by measuring loads and stresses in constrained 65 Ah pouch cells under both cycling and abuse conditions. To capture the desired responses, a load cell was located within a robust fixture to measure cell stress in real time after the application of a preload of approximately 30 kilograms or 294 N, equivalent to a pressure of 0.063 bar, with a fixed displacement.

As GHG and fuel economy regulations of light-duty vehicles have become more stringent, advanced emissions reduction technology has extensively penetrated the US light-duty vehicle fleet. This new technology includes not only advanced conventional engines and transmissions, but also greater adoption of electrified powertrains. In 2022, electrified vehicles – including mild hybrids, strong hybrids, plug-ins, and battery electric vehicles – made up nearly 17% of the US fleet and are on track to further increase their proportion in subsequent years. The Environmental Protection Agency (EPA) has previously used its Advanced Light-Duty Powertrain and Hybrid Analysis (ALPHA) full vehicle simulation tool to evaluate the greenhouse gas (GHG) emissions of light-duty vehicles. ALPHA contains a library of benchmarked powertrain components that can be matched to specific vehicles to explore GHG emissions performance.

Multiple areas in the U.S. continue to struggle with achieving National Ambient Air Quality Standards for ozone. These continued issues highlight the need for further reductions in NOX emission standards in multiple industry sectors, with heavy-duty on-highway engines being one of the most important areas to be addressed. Starting in 2014, CARB initiated a series of technical demonstration programs aimed at examining the feasibility of achieving up to a 90% reduction in tailpipe NOX, while at the same time maintaining a path towards GHG reductions that will be required as part of the Heavy-Duty Phase 2 GHG program. These programs culminated in the Stage 3 Low NOX program, which demonstrated low NOX emissions while maintaining GHG emissions at levels comparable to the baseline engine.

Upcoming regulations from CARB and EPA will require diesel engine manufacturers to validate aftertreatment durability with full useful life aged components. To this end, the Diesel Aftertreatment Accelerated Aging Cycle (DAAAC) protocol was developed to accelerate aftertreatment aging by accounting for hydrothermal aging, sulfur, and oil poisoning deterioration mechanisms. Two aftertreatment systems aged with the DAAAC protocol, one on an engine and the other on a burner system, were directly compared to a reference system that was aged to full useful life using conventional service accumulation. After on-engine emission testing of the fully aged components, DOC and SCR catalyst samples were extracted from the aftertreatment systems to compare the elemental distribution of contaminants between systems. In addition, benchtop reactor testing was conducted to measure differences in catalyst performance.

Eco-driving algorithms enabled by Vehicle to Everything (V2X) communications in Connected and Automated Vehicles (CAVs) can improve fuel economy by generating an energy-efficient velocity trajectory for vehicles to follow in real time. Southwest Research Institute (SwRI) demonstrated a 7% reduction in energy consumption for fully loaded class 8 trucks using SwRI’s eco-driving algorithms. However, the impact of these schemes on vehicle emissions is not well understood. This paper details the effort of using data from SwRI’s on-road vehicle tests to measure and evaluate how eco-driving could impact emissions. Two engine and aftertreatment configurations were evaluated: a production system that meets current NOX standards and a system with advanced aftertreatment and engine technologies designed to meet low NOX 2031+ emissions standards.

In 2020, CARB adopted the low NOX omnibus ruling, which provided revisions to on-road heavy duty engine compliance standards and certification practices. As part of the updates to the regulation, CARB has introduced a new in-use vehicle testing process that broadens the operation modes tested and considers the manufacturer’s intended vehicle application. Compared to the previous method, or the Not-to-Exceed approach, cold start and low ambient temperature provisions were included as part of the updates. The inclusion of low temperature operation requires the OEMs to design a robust engine and aftertreatment package that extends NOX conversion performance. The following work discusses the NOX emissions performance impact in a low temperature ambient environment. The engine and aftertreatment system evaluated was designed to comply with CARB’s low NOX regulations. The cycles tested included the CARB Southern NTE cycle and an FTP-LLC protocol.

Aftertreatment durability demonstration is a required validation exercise for on-road medium and heavy-duty diesel engine certification. The demonstration is meant to validate emissions compliance for the engine and aftertreatment system at full useful life or FUL. Current certification practices allow engine manufacturers to complete partial aging and then extrapolate emissions performance results to FUL. While this process reduces the amount of service accumulation time, it does not consider changes in the aftertreatment deterioration rate. Rather, deterioration is assumed to occur at a linear rate, which may lead to false conclusions relating to emissions compliance. With CARB and EPA’s commitment to the reduction of criteria emissions, emphasis has also been placed on revising the existing certification practices. The updated practices would require engine manufacturers to certify with an aftertreatment system aged to FUL.

As governmental agencies focus on low levels of the oxides of nitrogen (NOx) emissions compliance, new off-road applications are being reviewed for both regulated and unregulated emissions to understand the technological challenges and requirements for improved emissions performance. The California Air Resources Board (CARB) has declared its intention to pursue more stringent NOX standards for the off-road market. As part of this effort, CARB initiated a program to provide a detailed characterization of emissions meeting the current Tier 4 off-road standards [1]. This work focused on understanding the off-road market, establishing a current technology emissions baseline, and performing initial modeling on potential low NOx solutions. This paper discusses a part of this effort, focuses on the emissions characterization from two non-road engine platforms, and compares the emissions species from different approaches designed to meet Tier 4 emissions regulations.

As agencies continue to focus on emissions compliance, low NOX discussions have started to propagate beyond the on-highway market. Nonroad applications, which contribute to 29% of the PM emissions and 11% of the NOX emissions in California, are being reviewed to understand the technological challenges and requirements for improved emissions performance. To help facilitate a nonroad low NOX technology demonstration, information from current engine and aftertreatment technologies required a detailed assessment. The following work will discuss the emissions characterization results from two non-road engine platforms. The intention of this study was to compare the emissions species from different approaches designed to meet Tier 4 emissions regulations. The platforms reflect available technology for DPF and non-DPF aftertreatment architectures.

Southwest Research Institute (SwRI) utilizes the burner-based Exhaust Composition Transient Operation LaboratoryTM (ECTO-Lab) to accurately simulate transient engines and replicate real exhaust that is produced by light and heavy-duty engines for aftertreatment aging and evaluations. This system can generate and dose NOX over transient cycles from a range of 20 ppm to 1200 ppm where the NOX is generated by the in-situ decomposition and combustion of a fuel-bound, nitrogen containing compound. During the combustion and decomposition of the nitrogen containing compound over 95 % of the NOX generated is in the form of NO. To authentically simulate exhaust gases, it is necessary to account for the distribution of the NO to the NO2. Since previous work has established that the decomposition of nitric acid can be utilized as a method to generate NO2, the objective of this project was to develop control of NO and NO2 within SwRI’s ECTO-Lab through the decomposition of nitric acid.

A push for more stringent emissions regulations has resulted in larger, increasingly complex aftertreatment solutions. In particular, oxides of nitrogen (NOX) and particulate matter (PM) have been controlled using two separate systems, selective catalytic reduction (SCR) and the catalyze diesel particulate filter (CDPF), or the functionality has been combined into a single device producing the SCR on filter (SCRoF). The SCRoF forgoes beneficial NO2 production present in the CDPF to avoid NH3 oxidation which occurs when using platinum group metals (PGM) for oxidation. In this study, mixed-metal oxides are shown to oxidize NO to NO2 without appreciable NH3 oxidation. This selectivity leads to enhanced performance when combined with a typical Cu-zeolite catalyst.

Detailed characterization of particle emissions from three different engine technologies were performed, two of which were advanced technology engines. One of the engines was a nonroad Tier 4 Final emission regulation compliant 6.8L John Deere PSS 6068 diesel engine operated with its production calibration strategy. The other two engine platforms were advanced engine technologies whose controllers were developed by Southwest Research Institute (SwRI). These included a dual fuel Navistar MaxxForce 13L natural gas-diesel engine and a Cummins ISX 15L diesel engine. The dual fuel engine was operated in two distinct modes, conventional dual fuel (CDF) mode and low temperature reactivity controlled compression ignition (RCCI) mode. The Cummins ISX engine was operated using a “hot” or low EGR combustion strategy. For each engine technology, the test campaign involved steady-state test modes ranging from low speed low load to high speed high load conditions.

Two methods of sampling exhaust emissions are typically used for characterizing emissions from diesel engines: total dilution which uses a constant volume sampling (CVS) system and partial flow dilution which relies on proportionally diluting a small part from the main exhaust stream. The CVS dilutes the entire exhaust flow to a constant volumetric flowrate which allows for proportional sampling of the exhaust species during transient engine operation. For partial dilution sampling during transient engine operation, obtaining a proportional sample is more rigorous and dilution of the extracted sample must be continuously changed throughout the cycle in order for the extracted sample flowrate to be proportional to the continuously changing exhaust flow. Typically, regulated emissions measured using both methods for an engine platform have shown good correlation. The focus for this work was on the experimental investigation of the two methods for the measurement of unregulated species.

The worldwide trend of tightening CO2 emissions standards and desire for near zero emissions is driving development of high efficiency natural gas engines for a low CO2 replacement of traditional diesel engines. A Cummins Westport ISX12 G was previously converted to a Dedicated EGR® (D-EGR®) configuration with two out of the six cylinders acting as the EGR producing cylinders. Using a systems approach, the combustion and turbocharging systems were optimized for improved efficiency while maintaining the potential for achieving 0.02 g/bhp-hr NOX standards. A prototype variable nozzle turbocharger was selected to maintain the stock torque curve. The EGR delivery method enabled a reduction in pre-turbine pressure as the turbine was not required to be undersized to drive EGR. A high energy Dual Coil Offset (DCO®) ignition system was utilized to maintain stable combustion with increased EGR rates.

Gasoline direct injection (GDI) has changed the exhaust composition in comparison with the older port fuel injection (PFI) systems. More recently, light-duty vehicle engine manufactures have combined these two technologies to take advantage of the knock benefits and fuel economy of GDI with the low particulate emission of PFI. These dual injection strategy engines have made a change in the combustion emission composition produced by these engines. Understanding the impact of these changes is essential for automotive companies and aftertreatment developers. A novel sampling system was designed to sample the exhaust generated by a dual injection strategy gasoline vehicle using the United States Federal Test Procedure (FTP). This sampling system was capable of measuring the regulated emissions as well as collecting the entire exhaust from the vehicle for measuring unregulated emissions.

Since the conception of the internal combustion engine, smoky and ill-smelling exhaust was prevalent. Over the last century, significant improvements have been made in improving combustion and in treating the exhaust to reduce these effects. One group of compounds typically found in exhaust, polycyclic aromatic hydrocarbons (PAH), usually occurs at very low concentrations in diesel engine exhaust. Some of these compounds are considered carcinogenic, and most are considered hazardous air pollutants (HAP). Many methods have been developed for sampling, handling, and analyzing PAH. For this study, an improved method for dilute exhaust sampling was selected for sampling the PAH in diesel engine exhaust. This sampling method was used during transient engine operation both with and without aftertreatment to show the effect of aftertreatment.

To meet increasingly stringent emissions and fuel economy regulations, many Original Equipment Manufacturers (OEMs) have recently developed and deployed small, high power density engines. Turbocharging, coupled with gasoline direct injection (GDI) has enabled a rapid engine downsizing trend. While these turbocharged GDI (TGDI) engines have indeed allowed for better fuel economy in many light duty vehicles, TGDI technology has also led to some unintended consequences. The most notable of these is an abnormal combustion phenomenon known as low speed pre-ignition (LSPI). LSPI is an uncontrolled combustion event that takes place prior to spark ignition, often resulting in knock, and has been known to cause catastrophic engine damage. LSPI propensity depends on a number of factors including engine design, calibration, fuel properties and engine oil formulation. Several engine tests have been developed within the industry to better understand the phenomenon of LSPI.

Gasoline direction injection (GDI) engines have been widely used by light-duty vehicle manufacturers in recent years to meet stringent fuel economy and emissions standards. Particulate Matter (PM) mass emissions from current GDI engines are primarily composed of soot particles or black carbon with a small fraction (15% to 20%) of semi-volatile hydrocarbons generated from unburned/partially burned fuel and lubricating oil. Between 2017 and 2025, PM mass emissions regulations in the USA are expected to become progressively more stringent going down from current level of 6 mg/mile to 1 mg/mile in 2025. As PM emissions are reduced through soot reduction, lubricating oil derived semi-volatile PM is expected to become a bigger fraction of total PM mass emissions.

Solid and metallic ash particle number (PN) and particulate matter (PM) mass emission measurements were performed on a heavy-duty (HD) on-highway diesel engine and a compressed natural gas (CNG) engine. Measurements were conducted under transient engine operation that included the FTP, WHTC and RMC. Both engines were calibrated to meet CARB ultra low NOX emission target of 0.02 g/hp-hr, a 90% reduction from current emissions limit. The HD diesel engine final exhaust configuration included a number of aftertreatement sub-systems in addition to a selective catalytic reduction filter (SCRF). The stoichiometric CNG engine final configuration included a closed coupled Three Way Catalyst (ccTWC) and an under floor TWC (ufTWC). The aftertreatment systems for both engines were aged for a full useful life (FUL) of 435,000 miles, prior to emissions testing. PM mass emissions from both engines were comparable and well below the US EPA emissions standard.