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To meet TierII/LEVII emissions standards, light duty diesel (LDD) vehicles require high conversion efficiencies from the Aftertreatment Systems (ATS) for the removal of both Hydrocarbon (HC) and Nitrogen Oxide (NOx) species. The most populous configuration for LDD ATS have the Selective Catalytic Reduction (SCR) catalyst positioned on the vehicle behind the close coupled Diesel Oxidation Catalyst (DOC) and Catalyzed Diesel Particulate Filter (CDPF). This SCR position may require active heating measures which rely on the DOC/CDPF to provide heat through the combustion of HC and CO in the exhaust. Although DOCs are always impacted by their aging conditions, some aging conditions are shown to be both reversible and irreversible.

Meeting regulated tailpipe emission standards requires a full system approach by automotive engineers encompassing: engine design, combustion system metrics, exhaust heat management, aftertreatment design and exhaust system packaging. Engine and combustion system design targets define desired engine out exhaust constituents, exhaust gas temperatures and oil consumption rates. Protecting required catalytic converter volume in the engine bay for stricter tailpipe emission standards is becoming more difficult. Future fuel economy mandates are leading to vehicle downsizing which is affecting all aspects of vehicle component packaging. In this study, we set out to determine the potential palladium (Pd) cost penalty as a result of increased light-off time required as a catalyst is positioned further away from the engine. Two aged converter systems with different Pd loadings were considered, and EPA FTP-75 emission tested at six different catalyst positions.

Proposed LEV-III emission level will require improvements in NMOG, CO and NOx emissions as measured over FTP and US06 emission cycles. Incremental improvements in washcoat technologies, cold start calibration and catalyst system design are required to develop a cost effective solution set. New catalyst technologies demonstrated both lower HC and NOx emissions with 25% less platinum group metals (PGM). FTP and US06 emissions were measured on a 4-cylinder 2.4L application which compares a close-coupled converter and close-coupled + underfloor converter systems. A PGM placement study was performed with the close-coupled converter system employing these new catalyst technologies. Emissions results suggest that the placement of PGM is critical in minimizing emissions and PGM costs.