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Technical Paper

The Role of Lubricating Oil in Diesel Particulate and Particulate PAH Emissions

1987-11-01
872084
The role of lubricating oil in total particulate emmissions and in terms of polycyclic aromatic compounds (PAC) associated with the solvent organic fraction (SOF) of the particulate are investigated. Analysis of unused lubricating oil shows negligible concentrations of PAC. Used lubricating oil from a modified Perkins 4.236 Diesel engine, showed significant concentrations of PAC had accumulated in the oil in the form of PAC from unburnt fuel. Analysis of the oil was by gas chromatography using simultaneous parallel triple detection, allowing analysis of polycyclic aromatic hydrocarbons (PAH), nitrogen containing PAH (PANH) and sulphur containing PAH (PASH). Motoring the engine in the absence of fuel enabled the contribution of lubricating oil to the exhaust particulate and particulate PAC emission to be determined.
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