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Advanced Computational Fluid Dynamics (CFD) modeling of reacting sprays provides access to information not available even applying the most advanced experimental techniques. This is particularly evident if the combustion model handles detailed chemical kinetic models efficiently to describe the fuel auto-ignition and oxidation processes. Complex chemistry also provides the temporal evolution of key species closely related to emissions formation, such as polycyclic aromatic hydrocarbons (PAHs) that are well-known as soot precursors. In this framework, present investigation focuses on the analysis of the so-called Spray-A combustion characteristics using two different flamelet-based combustion models. Both Reynolds-Averaged Navier-Stokes (RANS) and Large-Eddy Simulation (LES) predictions are combined to study not only the averaged spray characteristics, but also the relevance of different realizations in this particular problem.