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Butanol is an attractive alternative fuel by virtue of its renewable source and low sooting tendency. In this paper, three butanol isomers (n-butanol, isobutanol, and tert-butanol) were induced via port injection respectively and n-heptane was directly injected into the cylinder to investigate reactivity controlled compression ignition in a heavy-duty diesel engine. This work evaluates the potential of applying butanol as low reactivity fuel and the effects of reactivity gradient on combustion and emission characteristics. The experiments were performed from low load to medium-high load. Due to the different reactivities among the butanol isomers, the exhaust gas recirculation rate and the direct injection strategy were varied for a specific butanol isomer and testing load. Particularly, isobutanol/n-heptane can be operated with single direct injection and no exhaust gas recirculation up to medium load due to the high octane rating.

N-butanol, as a biomass-based renewable fuel, has many superior fuel properties. It has a higher energy content and cetane number than its alcohol competitors, methanol and ethanol. Previous studies have proved that n-butanol has the capability to achieve lower emissions without sacrifice on thermal efficiency when blended with diesel. However, most studies on n-butanol are limited to low blending ratios, which restricts the improvement of emissions. In this paper, 80% by volume of n-butanol was blended with 20% by volume of n-heptane (namely BH80). The influences of various engine parameters (combustion phasing, EGR ratio, injection timing and intake pressure, respectively) on its combustion and emission characteristics are tested at different loads. The results showed that when BH80 uses more than 40% EGR, the emitted soot and nitrogen oxides (NOx) emissions are below the EURO VI legislation.

The accepted model of conventional diesel combustion [1] assumes a rich premixed flame slightly downstream of the maximum liquid penetration. The soot generated by this rich premixed flame is burnt out by a subsequent diffusion flame at the head of the jet. Even in situations in which the centre of combustion (CA50) is phased optimally to maximize efficiency, slow late stage combustion can still have a significant detrimental impact on thermal efficiency. Data is presented on potential late-stage combustion improvers in a EURO VI compliant HD engine at a range of speed and load points. The operating conditions (e.g. injection timings, EGR levels) were based on a EURO VI calibration which targets 3 g/kWh of engine-out NOx. Rates of heat release were determined from the pressure sensor data. To investigate late stage combustion, focus was made on the position in the cycle at which 90% of the fuel had combusted (CA90). An EN590 compliant fuel was tested.

Premixed Charge Compression Ignition concepts are promising to reduce NOx and soot simultaneously and keeping a high thermal efficiency. Partially premixed combustion is a single fuel variant of this new combustion concepts applying a fuel with a low cetane number to achieve the necessary long ignition delay. In this study, multiple injection strategies are studied in the partially premixed combustion approach to reach stable combustion and ultra-low NOx and soot emission at 15.5 bar gross indicated mean effective pressure. Three different injection strategies (single injection, pilot-main injection, main-post injection) are experimentally investigated on a heavy duty compression ignition engine. A fuel blend (70 vol% n-butanol and 30 vol% n-heptane) was tested. The effects of different pilot and post-injection timing, as well as Exhaust-gas Recirculation rate on different injection strategies investigated.

Post-injection strategies prove to be a valuable option for reducing soot emission, but experimental results often differ from publication to publication. These discrepancies are likely caused by the selected operating conditions and engine hardware in separate studies. Efforts to optimize not only engine-out soot, but simultaneously fuel economy and emissions of nitrogen oxides (NOx) complicate the understanding of post-injection effects even more. Still, the large amount of published work on the topic is gradually forming a consensus. In the current work, a Design-of-Experiments (DoE) procedure and regression analysis are used to investigate the influence of various operating conditions on post-injection scheduling and efficacy. The study targets emission reductions of soot and NOx, as well as fuel economy improvements. Experiments are conducted on a heavy-duty compression ignition engine at three load-speed combinations.

Second generation biomass is an attractive renewable feedstock for transport fuels. Its sulfur content is generally negligible and the carbon cycle is reduced from millions to tens of years. One hitherto non-valorized feedstock are so-called humins, a residual product formed in the conversion of sugars to platform chemicals, such as hydroxymethylfurfural and methoxymethylfurfural, intermediates in the production of FDCA, a building block used to produce the polyethylene furanoate (PEF) bottle by Avantium. The focus of this study is to investigate the spray combustion behavior of humins as a renewable alternative for heavy fuel oil (HFO) under large two-stroke engine-like conditions in an optically accessible constant volume chamber.

Recently introduced sulfur caps on marine fuels in so-called sulfur emission control areas (SECAs) are forcing shipping companies to sail on more or less automotive grade diesel in lieu of the considerably less expensive, but sulfur-laden heavy fuel oil (HFO) to which they were accustomed. This development is an opportunity for a bio-based substitute, given that most biomass is sulfur free by default. Moreover, given that biomass is typically solid to start with, cracking it to an HFO grade, which is highly viscous in nature, will involve fewer and/or less harsh process steps than would be the case if an automotive grade fuel were to be targeted. In this study, a renewable low sulfur heavy fuel oil (LSHFO) has been produced by means of subcritical water assisted lignin depolymerization in the presence of a short length surfactant, ethylene glycol monobutyl ether (EGBE).

Gasoline-ethanol-methanol (GEM) blends, with constant stoichiometric air-to-fuel ratio (iso-stoichiometric blending rule) and equivalent to binary gasoline-ethanol blends (E2, E5, E10 and E15 in % vol.), were defined to investigate the effect of methanol and combined mixtures of ethanol and methanol when blended with three FACE (Fuels for Advanced Combustion Engines) Gasolines, I, J and A corresponding to RON 70.2, 73.8 and 83.9, respectively, and their corresponding Primary Reference Fuels (PRFs). A Cooperative Fuel Research (CFR) engine was used under Spark Ignition and Homogeneous Charge Compression Ignited modes. An ignition quality tester was utilized in the Compression Ignition mode. One of the promising properties of GEM blends, which are derived using the iso-stoichiometric blending rule, is that they maintain a constant octane number, which has led to the introduction of methanol as a drop-in fuel to supplement bio-derived ethanol.

In this work, the influences of aromatics on combustion and emission characteristics from a heavy-duty diesel engine under various loads and exhaust gas recirculation (EGR) conditions are investigated. Tests were performed on a modified single-cylinder, constant-speed and direct-injection diesel engine. An engine exhaust particle sizer (EEPS) was used in the experiments to measure the size distribution of engine-exhaust particle emissions in the range from 5.6 to 560 nm. Two ternary blends of n-heptane, iso-octane with either toluene or benzaldehyde denoted as TRF and CRF, were tested, diesel was also tested as a reference. Test results showed that TRF has the longest ignition delay, thus providing the largest premixed fraction which is beneficial to reduce soot. However, as the load increases, higher incylinder pressure and temperature make all test fuels burn easily, leading to shorter ignition delays and more diffusion combustion.

Owing to environmental and health concerns, tetraethyl lead was gradually phased out from the early 1970's to mid-1990's in most developed countries. Advances in refining, leading to more aromatics (via reformate) and iso-paraffins such as iso-octane, along with the introduction of (bio) oxygenates such as MTBE, ETBE and ethanol, facilitated the removal of lead without sacrificing RON and MON. In recent years, however, legislation has been moving in the direction of curbing aromatic and olefin content in gasoline, owing to similar concerns as was the case for lead. Meanwhile, concerns over global warming and energy security have motivated research into renewable fuels. Amongst which are those derived from biomass. The feedstock of interest in this study is lignin, which, together with hemicellulose and cellulose, is amongst the most abundant organic compounds on the planet.

For natural gas (NG)-diesel RCCI, a multi-zonal, detailed chemistry modeling approach is presented. This dual fuel combustion process requires further understanding of the ignition and combustion processes to maximize thermal efficiency and minimize (partially) unburned fuel emissions. The introduction of two fuels with different physical and chemical properties makes the combustion process complicated and challenging to model. In this study, a multi-zone approach is applied to NG-diesel RCCI combustion in a heavy-duty engine. Auto-ignition chemistry is believed to be the key process in RCCI. Starting from a multi-zone model that can describe auto-ignition dominated processes, such as HCCI and PCCI, this model is adapted by including reaction mechanisms for natural gas and NOx and by improving the in-cylinder pressure prediction. The model is validated using NG-diesel RCCI measurements that are performed on a 6 cylinder heavy-duty engine.

The concept of Partially Premixed Combustion is known for reduced hazardous emissions and improved efficiency. Since a low-reactive fuel is required to extend the ignition delay at elevated loads, controllability and stability issues occur at the low-load end. In this investigation seven fuel blends are used, all having a Research Octane Number of around 70 and a distinct composition or boiling range. Four of them could be regarded as ‘viable refinery fuels’ since they are based on current refinery feedstocks. The latter three are based on primary reference fuels, being PRF70 and blends with ethanol and toluene respectively. Previous experiments revealed significant ignition differences, which asked for further understanding with an extended set of measurements. Experiments are conducted on a heavy duty diesel engine modified for single cylinder operation. In this investigation, emphasis is put on idling (600 rpm) and low load conditions.

Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.

A Gasoline Compression Ignition combustion strategy was developed and showed its capabilities in the heavy duty single cylinder test-cell, resulting in indicated efficiencies up to 50% and low engine out emissions applying to EU VI and US 10 legislations while the soot remained at a controllable 1.5 FSN. For this concept a single-cylinder CI-engine was used running at a lambda of ∼1.6 and EGR levels of ∼50% and a modified injection strategy. Part of this strategy was also the use of a gasoline blended with an ignition improver, giving the blend a cetane number in the range of regular diesel; ∼50. In this paper a step is taken towards implementation of this combustion concept into a multi-cylinder light duty standalone CI-engine. A standard CI-engine was modified so that its gas-exchange system could deliver the requested amounts of EGR and lambda.

Controlling ignition delay is the key to successfully enable partially premixed combustion in diesel engines. This paper presents experimental results of partially premixed combustion in an optically accessible engine, using primary reference fuels in combination with artificial exhaust gas recirculation. By changing the fuel composition and oxygen concentration, the ignition delay is changed. To determine the position of the flame front, high-speed visualization of OH-chemiluminescence is used, enabling a cycle-resolved analysis of OH formation. A clear correlation is observed between ignition delay and flame location. The mixing of fuel and air during the ignition delay period defines the local equivalence ratio, which is estimated based on a spherical combustion volume for each spray. The corresponding emission measurements using fast-response analyzers of CO, HC and NOX confirm the decrease in local equivalence ratio as a function of ignition delay.

In recent years the automotive industry has been forced to reduce the harmful and pollutant emissions emitted by direct-injected diesel engines. To accomplish this difficult task various solutions have been proposed. One of these proposed solutions is the usage of gaseous fuels in addition to the use of liquid diesel. These gaseous fuels have more gasoline-like properties, such as high octane numbers, and thereby are resistant against auto-ignition. Diesel on the other hand, has a high cetane number which makes it prone to auto-ignition. In this case the gaseous fuel is injected in the inlet manifold, and the diesel is direct injected in the cylinder at the end of the compression stroke. Thereby the diesel fuel spontaneously ignites and acts as an ignition source. The main goals for the use of a dual-fuel operation with diesel and gaseous fuels are the reduction of particulate matter (PM) and nitrogen oxides (NOx) emission.

In earlier research, a new class of bio-fuels, so-called cyclic oxygenates, was reported to have a favorable impact on the soot-NOx trade-off experience in diesel engines. In this paper, the soot-NOx trade-off is compared for two types of cyclic oxygenates. 2-phenyl ethanol has an aromatic and cyclohexane ethanol a saturated or aliphatic ring structure. Accordingly, the research is focused on the effect of aromaticity on the aforementioned emissions trade-off. This research is relevant because, starting from lignin, a biomass component with a complex poly-aromatic structure, the production of 2-phenyl ethanol requires less hydrogen and can therefore be produced at lower cost than is the case for cyclohexane ethanol.

Recently, some studies have shown high efficiencies using controlled auto-ignition by blending gasoline and diesel to a desired reactivity. This concept has been shown to give high efficiency and, because of the largely premixed charge, low emission levels. The origin of this high efficiency, however, has only partly been explained. Part of it was attributed to a lower temperature combustion, originating in lower heat losses. Another part of the gain was attributed to a faster, more Otto-like (i.e. constant volume) combustion. Since the concept was mainly demonstrated on one single test setup so far, an experimental study has been performed to reproduce these results and gain more insight into their origin. Therefore one cylinder of a heavy duty test engine has been equipped with an intake port gasoline injection system, primarily to investigate the effects of the balance between the two fuels, and the timing of the diesel injection.

Increasing fuel prices keep bringing attention to alternative, cheaper fuels. Liquefied Petroleum Gas (LPG) has been well known for decades as an alternative fuel for spark ignition (SI) passenger cars. More recently, aftermarket LPG systems were also introduced to Heavy Duty transport vehicles. These (port fuel) systems either vaporize the liquid fuel and then mix it with intake air, or inject fuel into the engine's intake ports. While this concept offers significant fuel cost reductions, for aftermarket certification and large-scale OEM use some concerns are present. Unburned hydrocarbons (UHC) and carbon monoxide (CO) emissions are known to be high because of premixed charge getting trapped into crevices and possibly being blown through during valve-overlap. Apart from the higher emission levels, this also limits fuel efficiency and therefore cost savings.

Existing gasoline DI injection equipment has been modified to generate single hole pulsed gas jets. Injection experiments have been performed at combinations of 3 different pressure ratios (2 of which supercritical) respectively 3 different hole geometries (i.e. length to diameter ratios). Injection was into a pressure chamber with optical access. Injection pressures and injector hole geometry were selected to be representative of current and near-future DI natural gas engines. Each injector hole design has been characterized by measuring its discharge coefficient for different Re-levels. Transient jets produced by these injectors have been visualized using planar laser sheet Mie scattering (PLMS). For this the injected gas was seeded with small oil droplets. The corresponding flow field was measured using particle image velocimetry (PIV) laser diagnostics.