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Journal Article

Characterization of the Ultrafine and Black Carbon Emissions from Different Aviation Alternative Fuels

2015-09-15
2015-01-2562
This study reports gaseous and particle (ultrafine and black carbon (BC)) emissions from a turbofan engine core on standard Jet A-1 and three alternative fuels, including 100% hydrothermolysis synthetic kerosene with aromatics (CH-SKA), 50% Hydro-processed Esters and Fatty Acid paraffinic kerosene (HEFA-SPK), and 100% Fischer Tropsch (FT-SPK). Gaseous emissions from this engine for various fuels were similar but significant differences in particle emissions were observed. During the idle condition, it was observed that the non-refractory mass fraction in the emitted particles were higher than during higher engine load condition. This observation is consistent for all test fuels. The 100% CH-SKA fuel was found to have noticeable reductions in BC emissions when compared to Jet A-1 by 28-38% by different BC instruments (and 7% in refractory particle number (PN) emissions) at take-off condition.
Technical Paper

Impact of Ethanol and Isobutanol Gasoline Blends on Emissions from a Closed-Loop Small Spark-Ignited Engine

2015-04-14
2015-01-1732
The focus of this study was the characterization and comparison of power-specific exhaust emission rates from a closed-loop small spark-ignited engine fuelled with ethanol and isobutanol gasoline blends. A 4-cycle Kohler ECH-630 engine certified to the Phase 3 emissions standards was operated over the G2 test cycle, a six-mode steady-state test cycle, in its original configuration. This engine was equipped with electronic ignition, electronic fuel injection and an oxygen sensor. Certification gasoline fuel was splash-blended by percent volume with ethanol and isobutanol to result in the test blend levels of E10, E15, iB16 and iB8-E10. Reductions in emission rates of carbon monoxide (up to 12.0% with the ethanol blends and up to 11.4% with the isobutanol blends) were achieved along with a reduction in total hydrocarbons (up to 10.9% with the ethanol blends and up to 8.2% with the isobutanol blends). Nitrogen oxide emissions were decreased by up to 9.8% with the ethanol blends.
Technical Paper

The Impact of Isobutanol and Ethanol on Gasoline Fuel Properties and Black Carbon Emissions from Two Light-Duty Gasoline Vehicles

2015-04-14
2015-01-1076
This study reported black carbon (BC) mass and solid particle number emissions from a gasoline direct injection (GDI) vehicle and a port fuel injection (PFI) vehicle on splash blended E10 and iB16 fuels over the FTP-75 and US06 drive cycles at standard and cold ambient temperatures. For the FTP-75 drive cycle, the GDI vehicle had lower solid particle number and BC mass emissions from E10 (5.1×1012 particles/mile; 4.2 mg/mile) and iB16 (5.2×1012 particles/mile; 3.9 mg/mile) compared to E0 (7.2×1012 particles/mile; 7.0 mg/mi). Most of the reductions were attributed to the statistically significant reductions during the phases 1 and 2 of the FTP-75 drive cycle. iB16 was also observed to have statistically significant reduction on BC emissions when compared to E0 at cold ambient temperature but E10 did not show such BC reduction. For the PFI vehicle, most of the solid particle number and BC mass emissions were emitted primarily during phase 1 of the FTP-75 drive cycle.
Technical Paper

Immediate Impacts on Particulate and Gaseous Emissions from a T56 Turbo-Prop Engine Using a Biofuel Blend

2013-09-17
2013-01-2131
Adoption of hydro-processed esters and fatty acid biojet fuels is a critical component for the sustainability of the aviation industry. Aviation biofuels reduce pollution and provide alternatives to conventional fossil fuels. A study of the impacts of biofuels on emissions from a T56 turbo-prop engine was undertaken as a joint effort among several departments of the Government of Canada. In this study, particulate (including particle number and black carbon (BC) mass) and regulated gaseous emissions (CO2, CO, NO, NO2, THC) were characterized with the engine operating on conventional F-34 jet fuel and jet fuel blended with camelina-based hydro-processed biojet fuel (C-HEFA) by 50% in volume. Emissions characterization, conducted after 20-hour ground engine durability tests, showed immediate significant reductions in particle number and BC mass when the engine was operated on the C-HEFA blend.
Journal Article

Impact of Ambient Temperature on Gaseous and Particle Emissions from a Direct Injection Gasoline Vehicle and its Implications on Particle Filtration

2013-04-08
2013-01-0527
Gaseous and particle emissions from a gasoline direct injection (GDI) and a port fuel injection (PFI) vehicle were measured at various ambient temperatures (22°C, -7°C, -18°C). These vehicles were driven over the U.S. Federal Test Procedure 75 (FTP-75) and US06 Supplemental Federal Test Procedure (US06) on Tier 2 certification gasoline (E0) and 10% by volume ethanol (E10). Emissions were analyzed to determine the impact of ambient temperature on exhaust emissions over different driving conditions. Measurements on the GDI vehicle with a gasoline particulate filter (GPF) installed were also made to evaluate the GPF particle filtration efficiency at cold ambient temperatures. The GDI vehicle was found to have better fuel economy than the PFI vehicle at all test conditions. Reduction in ambient temperature increased the fuel consumption for both vehicles, with a much larger impact on the cold-start FTP-75 drive cycle observed than for the hot-start US06 drive cycle.
Technical Paper

Impact of Varying Biodiesel Blends on Direct-Injection Light-Duty Diesel Engine Emissions

2012-04-16
2012-01-1313
A 1.9L turbocharged direct-injection engine representing a model year 1998-2003 Volkswagen vehicle, equipped with the OEM diesel oxidation catalyst (DOC) and exhaust gas recirculation (EGR), was tested on an eddy-current engine dynamometer with a critical flow venturi-constant volume sampling system (CFV-CVS). The engine was operated over three steady-state modes: 1600 rev/min at 54 Nm; 1800 rev/min at 81 Nm; and 2000 rev/min at 98 Nm. Commercially available ultra-low sulfur diesel fuel (≺15 ppm S) was splash-blended with fatty acid methyl ester biodiesels derived from three different feedstocks: canola, soy, and tallow/waste fry oil. Test blend levels included: 0%, 2%, 5%, 20%, 50%, and 100% biodiesel for each feedstock.
Technical Paper

Performance and Emissions Evaluation of Compressed Natural Gas and Clean Diesel Buses at New York City's Metropolitan Transit Authority

2003-03-03
2003-01-0300
The New York City Metropolitan Transit Authority (MTA) has initiated a program to utilize various diesel emission control, alternative fuel, and hybrid electric drive technologies as part of its ongoing effort to provide environmentally friendly bus service. The New York State Department of Environmental Conservation (DEC) has joined with the MTA and Environment Canada in evaluating this program, and has established a protocol for measuring both regulated and unregulated emissions, as well as other operational parameters. This paper compares and contrasts the emissions of buses powered by Detroit Diesel Series 50 diesel engines and Series 50G Compressed Natural Gas (CNG) engines. All buses have been tested for regulated emissions at the Emissions Research and Measurement Division of Environment Canada, in Ottawa, Ontario. Unregulated emissions measurements, including particle size distributions and chemical analysis, have been supported by DEC staff.
Technical Paper

The Contribution of Methanol (VOC) Emissions from Windshield Washer Fluid Use to the Formation of Ground-Level Ozone

2000-03-06
2000-01-0663
The potential for methanol emissions from the use of windshield washer fluid to contribute significantly to the formation of ground-level ozone in Canada is assessed. Reactivity and plausible chemical mechanisms for ozone formation are discussed. Assuming an environmental half-life of methanol of one month, a significant amount of these methanol emissions could participate in ozone formation. Options for reducing methanol emissions from this source were investigated in consultation with industry stakeholders. Recommendations included seasonal conversion to summer formulations, limiting methanol content, modifying OEM practices, and investigating more efficient fluid delivery systems.
Technical Paper

Evaluations of Current Natural Gas Vehicle Technology Exhaust Emissions at Various Operating Temperatures

1995-10-01
952437
As more stringent vehicle emission standards are introduced worldwide, there is an increased need to provide a thorough assessment of the environmental impact of alternative fuels. With the advent of CNG as a viable transportation fuel, the development of advanced computer controlled fuel delivery systems is imperative in order to ensure acceptable emission performance. At present, the majority of light and medium duty engines operating on natural gas are primarily gasoline automotive engines which have been retrofitted to allow for the use of CNG. The Mobile Sources Emissions Division of Environment Canada and the Canadian Gas Association have conducted a joint test program in order to develop a database of exhaust emissions from vehicles typically converted for operation on either gasoline or natural gas at various operating temperatures.
Technical Paper

Emissions from Methanol, Ethanol, and Diesel Powered Urban Transit Buses

1994-11-01
942261
The recent tightening of emission standards for new heavy duty engines has lead to the development and implementation of alternative fuel engines, particularly for urban transit bus applications. Alternative fuels are intended to offer a potential emissions benefit with regards to the regulated emissions, and especially the particulate matter, which has received the greatest degree of regulatory action. However, the entire composition of the engine emissions should be considered when evaluating the environmental benefits of these new fuels, and also the continued performance of these engines in actual fleet service. In this study the exhaust emissions from methanol, ethanol, and diesel - powered buses were determined during transient operation of the vehicles on a heavy duty chassis dynamometer. The tests of the alcohol fuelled buses, and a control diesel bus were conducted as the buses accumulated mileage in revenue generating service.
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