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The reduction of automotive emissions is instrumental in the fight against air pollution and its impact on global warming. This realization has empowered governments around the world to mandate lower levels of vehicle emissions requiring the Original Equipment Manufacturers (OEMs) to implement advanced aftertreatment technologies in their applications. Achieving emission levels as low as SULEV30 or SULEV20 would have been impossible only a couple of decades ago, however, these lower levels of emissions are now a possibility through advanced control strategies and aftertreatment systems. As a part of this mandate to lower emissions, OEMs are also continuously monitoring the health and performance of their aftertreatment and control components. The implementation of On Board Diagnostics (OBD) ensures that control systems are functioning robustly and the emission levels are achieved and maintained to high mileages for the life of the vehicle.

Advances in diesel engine and catalyst technologies have enabled light passenger vehicles in meeting the most stringent Tier 3/LEV III emission levels and durability requirements. The advancements in diesel aftertreatment catalyst technology have made catalysts more susceptible to low levels of impurities, typically referred to as poisons. Published studies over the last two decades, have shown a significant impact on the performance of catalysts, to the presence of sulfur and other inorganics in fuels and oils. The design of an aftertreatment system (ATS) typically sets limits for lubricant and fuel quality, specific to the geographical region and availability of certain level of regulated fuels. In this study, we investigate a real-world aged diesel vehicle which exhibited deterioration in tailpipe emissions, beyond levels targeted during engineering development.

Significant reduction in Nitrogen Oxide (NOx) emissions will be required to meet LEV III Emissions Standards for Light Duty Diesel passenger vehicles (LDD). As such, Original Equipment Manufacturers (OEMs) are exploring all possible aftertreatment options to find the best balance between performance, robustness and cost. The primary technology adopted by OEMs in North America to achieve low NOx levels is Selective Catalytic Reduction (SCR) catalyst. The critical parameters needed for SCR to work properly are: an appropriate reductant such as ammonia (NH3) typically provided as urea, adequate operating temperatures, and optimum Nitrogen Dioxide (NO2) to NOx ratios (NO2/NOx). The NO2/NOx ratio is mostly influenced by Precious Group Metals (PGM) containing catalysts located upstream of the SCR catalyst. Different versions of zeolite based SCR technologies are available on the market today and these vary in their active metal type (iron, copper, vanadium), and/or zeolite type.

Significant reduction in Nitrogen Oxide (NOx) emissions will be required to meet LEV III/Tier III Emissions Standards for Light Duty Diesel (LDD) passenger vehicles. As such, Original Equipment Manufacturers (OEMs) are exploring all possible aftertreatment options to find the best balance between performance, durability and cost. The primary technology adopted by OEMs in North America to achieve low NOx levels is Selective Catalytic Reduction (SCR). The critical parameters needed for SCR to work properly are: an appropriate reductant such as ammonia (NH3) provided as Diesel Exhaust Fluid (DEF), which is an aqueous urea solution 32.5% concentration in weight with water (CO(NH2)2 + H2O), optimum operating temperatures, and optimum nitrogen dioxide (NO2) to NOx ratios (NO2/NOx). The NO2/NOx ratio is most influenced by Precious Group Metals (PGM) containing catalysts upstream of the SCR catalyst.