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PlugIn Hybrid Electric Vehicles (PHEV) offer the opportunity to experience electric driving without the risk of vehicle break-down due to a low battery charge state. Thus, PHEV's represent an attractive means of meeting future CO2-legislation. PHEV batteries must fulfill a divergent list of requirements: on the one hand, the battery must supply sufficient energy to ensure it can be driven an appropriate distance in EV-mode. On the other hand, even with a low state-of-charge (SOC), the battery must supply sufficient power to assist the engine in vehicle acceleration or to recuperate on deceleration. This leads to a compromise in terms of cell selection. Fundamentally, high energy cells cannot provide high charge and discharge rates and high power cells cannot provide sufficient energy.