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The present work is a continuation of the earlier published results by authors on the investigation of Hydrogenated Vegetable Oil (HVO) on a High Efficiency Diesel Combustion System (SAE Int. J. Fuels Lubr. Paper No. 2013-01-1677 and JSAE Paper No. 283-20145128). In order to further validate and interpret the previously published results of soot microstructure and its consequences on oxidation behavior, the test program was extended to analyze the impact of soot composition, optical properties, and physical properties such as size, concentration etc. on the oxidation behavior. The experiments were performed with pure HVO as well as with petroleum based diesel and today's biofuel (i.e. FAME) as baseline fuels. The soot samples for the different analyses were collected under constant engine operating conditions at indicated raw NOx emissions of Euro 6 level using closed loop combustion control methodology.

The limited availability of fossil fuels and the increasing environmental pollution will lead to an increased demand for sustainable biofuels. The production of bio-based diesel fuels from vegetable oils is commonly accomplished using a process known as Trans-esterification. The product of Transesterification is Fatty Acid Methyl Ester (FAME), commonly known as Biodiesel. An alternative process is Hydro-treatment of seed oils or animal waste fats to produce highly paraffinic renewable diesel fuel called Hydrogenated Vegetable Oil (HVO). Detailed investigations were carried out by the “Department of Advanced Diesel Engine Development” at FEV GmbH Aachen (Germany), to explore the potential of this biofuel compound as a candidate for future compression ignition engines.