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A comprehensive experimental and numerical analysis of two state-of-the-art diesel AfterTreatment Systems (ATS) for automotive applications is presented in this work. Both systems, designed to fulfill Euro 6 emissions regulations standards, consist of a closed-coupled Diesel Oxidation Catalyst (DOC) followed by a Selective Catalytic Reduction (SCR) catalyst coated on a Diesel Particulate Filter (DPF), also known as SCR on Filter (SCRoF or SCRF). While the two systems feature the same Urea Water Solution (UWS) injector, major differences could be observed in the UWS mixing device, which is placed upstream of the SCRoF, whose design represents a crucial challenge due to the severe flow uniformity and compact packaging requirements.

Nowadays, injection rate shaping and multi-pilot events can help to improve fuel efficiency, combustion noise and pollutant emissions in diesel engine, providing high flexibility in the shape of the injection that allows combustion process control. Different strategies can be used in order to obtain the required flexibility in the rate, such as very close pilot injections with almost zero Dwell Time or boot shaped injections with optional pilot injections. Modern Common-Rail Fuel Injection Systems (FIS) should be able to provide these innovative patterns to control the combustion phases intensity for optimal tradeoff between fuel consumption and emission levels.

In this work, several nanostructured ceria-based catalysts were prepared by the hydrothermal technique varying two synthesis parameters (namely, temperature and pH). Then, cerias with different shapes (i.e., cubes, rods, combination of them, other polyhedra) and structural properties were obtained. The prepared materials were tested for the CO oxidation and soot oxidation efficiency. The results have shown that, for the CO oxidation, activities depend on the surface properties of the catalysts. Conversely, for the soot oxidation, the most effective catalysts exhibit better soot-catalyst contact conditions.

The selection and tuning of the Fuel Injection System (FIS) are among the most critical tasks for the automotive diesel engine design engineers. In fact, the injection strongly affects the combustion phenomena through which controlling a wide range of related issues such as pollutant emissions, combustion noise and fuel efficiency becomes feasible. In the scope of the engine design optimization, the simulation is an efficient tool in order to both predict the key performance parameters of the FIS, and to reduce the amount of experiments needed to reach the final product configuration. In this work a complete characterization of a solenoid ballistic injector for a Light-Duty Common Rail system was therefore implemented in a commercially available one-dimensional computational software called GT-SUITE. The main phenomena governing the injector operation were simulated by means of three sub-models (electro-magnetic, hydraulic and mechanical).

The effects of using blended renewable diesel fuel (30% vol.), obtained from Rapeseed Methyl Ester (RME) and Hydrotreated Vegetable Oil (HVO), in a Euro 5 small displacement passenger car diesel engine have been evaluated in this paper. The hydraulic behavior of the common rail injection system was verified in terms of injected volume and injection rate with both RME and HVO blends fuelling in comparison with commercial diesel. Further, the spray obtained with RME B30 was analyzed and compared with diesel in terms of global shape and penetration, to investigate the potential differences in the air-fuel mixing process. Then, the impact of a biofuel blend usage on engine performance at full load was first analyzed, adopting the same reference calibration for all the tested fuels.

Particulate Matter (PM) particles number and size distribution emitted from a small displacement automotive Common-Rail Diesel engine were analyzed in order to evaluate the impact of different engine operating parameters, such as engine load, EGR rate and injection pattern during DPF regeneration. The engine was equipped with a close coupled aftertreatment system, featuring a Diesel Oxidation Catalyst (DOC) and a Diesel Particulate Filter (DPF) integrated in a single canning. The pollutant emissions were sampled at two locations along the exhaust system: at the engine outlet and downstream of the diesel oxidation catalyst, in order to characterize particles entering the DOC and the DPF respectively. Particle size distributions were measured by means of a two stage dilution system coupled with a downstream Scanning Mobility Particle Sizer (SMPS).

Molybdenum sulfide nanoparticles have been successfully obtained, for lubricant applications, by means of a wet chemical synthesis in an aqueous solution employing ammonium molybdate, citric acid and ammonium sulfide as the reactants. Some molybdenum-citrate complexes were formed and they reacted with the ammonium sulfide to form MoS₂ nanoparticles. Mo:citrate molar ratio was identified as being the most relevant of the synthesis parameters that affected the phase and morphology of the final products. The optimized nanopowders were softly agglomerated and amorphous, with a mean size of the primary particles of about 30 nm. The compatibility between the thus obtained MoS₂ nanopowders and some commercial after-treatment catalysts for diesel vehicle engines was tested. Diesel oxidation, soot combustion and ammonia-SCR de-NOx catalysts were considered as were the possible effects on the catalytic activity and their possible reaction to the MoS₂ additive.

Experimental work was carried out on a small displacement Euro 5 automotive diesel engine alternatively fuelled with ultra low sulphur diesel (ULSD) and with two blends (30% vol.) of ULSD and of two different fatty acid methyl esters (FAME) obtained from both rapeseed methyl ester (RME) and jatropha methyl ester (JME) in order to evaluate the effects of different fuel compositions on particle number (PN) emissions. Particulate matter (PM) emissions for each fuel were characterized in terms of number and mass size distributions by means of two stage dilutions system coupled with a scanning mobility particle sizer (SMPS). Measurements were performed at three different sampling points along the exhaust system: at engine-out, downstream of the diesel oxidation catalyst (DOC) and downstream of the diesel particulate filter (DPF). Thus, it was possible to evaluate both the effects of combustion and after-treatment efficiencies on each of the tested fuels.

The aim of this work is to analyze particle number and size distribution from a small displacement Euro 5 common rail automotive diesel engine, equipped with a close coupled aftertreatment system, featuring a DOC and a DPF integrated in a single canning. In particular the effects of different combustion processes on PM characteristics were investigated, by comparing measurements made both under normal operating condition and under DPF regeneration mode. Exhaust gas was sampled at engine outlet, at DOC outlet and at DPF outlet, in order to fully characterize PM emissions through the whole exhaust line. After a two stage dilution system, sampled gas was analyzed by means of a TSI 3080 SMPS, in the range from 6 to 240 nm. Particle number and size distribution were evaluated at part load operating conditions, representative of urban driving.