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In this work, several nanostructured ceria-based catalysts were prepared by the hydrothermal technique varying two synthesis parameters (namely, temperature and pH). Then, cerias with different shapes (i.e., cubes, rods, combination of them, other polyhedra) and structural properties were obtained. The prepared materials were tested for the CO oxidation and soot oxidation efficiency. The results have shown that, for the CO oxidation, activities depend on the surface properties of the catalysts. Conversely, for the soot oxidation, the most effective catalysts exhibit better soot-catalyst contact conditions.

Molybdenum sulfide nanoparticles have been successfully obtained, for lubricant applications, by means of a wet chemical synthesis in an aqueous solution employing ammonium molybdate, citric acid and ammonium sulfide as the reactants. Some molybdenum-citrate complexes were formed and they reacted with the ammonium sulfide to form MoS₂ nanoparticles. Mo:citrate molar ratio was identified as being the most relevant of the synthesis parameters that affected the phase and morphology of the final products. The optimized nanopowders were softly agglomerated and amorphous, with a mean size of the primary particles of about 30 nm. The compatibility between the thus obtained MoS₂ nanopowders and some commercial after-treatment catalysts for diesel vehicle engines was tested. Diesel oxidation, soot combustion and ammonia-SCR de-NOx catalysts were considered as were the possible effects on the catalytic activity and their possible reaction to the MoS₂ additive.

The aim of this work is to analyze particle number and size distribution from a small displacement Euro 5 common rail automotive diesel engine, equipped with a close coupled aftertreatment system, featuring a DOC and a DPF integrated in a single canning. In particular the effects of different combustion processes on PM characteristics were investigated, by comparing measurements made both under normal operating condition and under DPF regeneration mode. Exhaust gas was sampled at engine outlet, at DOC outlet and at DPF outlet, in order to fully characterize PM emissions through the whole exhaust line. After a two stage dilution system, sampled gas was analyzed by means of a TSI 3080 SMPS, in the range from 6 to 240 nm. Particle number and size distribution were evaluated at part load operating conditions, representative of urban driving.