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Technical Paper

Highly Predictive Accelerated Weathering of Engineering Thermoplastics

2003-03-03
2003-01-1192
Current accelerated weathering protocols such as SAE J1960 or ASTM G26 do not provide reliable, predictive results for engineering thermoplastics. Correlation factors among resin types and even different colors of a single resin have variations that are 60-100% of the mean at the 95% confidence level, making these tests useless for lifetime prediction or even reliable ranking of materials. We have developed improved conditions using CIRA/sodalime-filtered xenon arc, a more rain-like water spray, and occasional sponge-wiping of the samples. The data for gloss loss and color shift agree very well with Florida data giving a correlation factor of 3100±680 kJ/m2 (at 340 nm) per Florida year at the 95% confidence level. The acceleration factor is 7.6x.
Technical Paper

Conductive Thermoplastic Resin for Electrostatically Painted Applications

1998-02-23
980983
The formulation of injection moldable thermoplastics with small loadings of graphite nanotubes provides sufficient conductivity in molded parts to allow for use in electrostatic painting applications. Normally, plastic parts need to be painted with a conductive primer prior to the electrostatic painting of base and clear coats. The use of conductive plastics eliminates the need for the priming step, and improves paint transfer efficiency and first pass yield. These elements provide obvious savings in materials and labor. What is less obvious, however, is the dramatic positive environmental impact that can occur through the reduction in emissions of volatile organic compounds (VOCs). Graphite nanotube technology provides advantages over other technologies such as conductive carbon black. In order to reach the percolation threshold for conductivity in carbon-black-containing resins, the loading of carbon black required tends to embrittle the polymer.
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