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Homogeneous Charge Compression Ignition (HCCI) combustion has attracted considerable interest in recent years as a new combustion concept for internal combustion engines. On the other hand, two combustion concepts proposed for two-cycle spark-ignition (SI) engines are Active Thermo-Atmosphere Combustion (ATAC) and Activated Radical (AR) combustion. The authors undertook this study to examine the similarities and differences between HCCI combustion and ATAC (AR) combustion. Differences in the low-temperature oxidation reaction behavior between these two combustion processes were made clear using one test engine.