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Catalytic oxidation is an effective means of controlling the build up of ammonia and other trace gas contaminants within closed spaces. However, it sometimes leads to the formation of noxious gases that need to be removed in post-treatment systems. In addition, ammonia removal is an issue when regeneration of water from wastewater is considered since ammonia is a byproduct of urea decomposition. For example, the VPCAR (Vapor Phase Catalytic Ammonia Reduction) advanced water processor system includes an oxidation reactor for the destruction of ammonia and of other volatile organics that are not separated out in the evaporator due to their volatility. The oxidation of ammonia may produce nitrogen, nitrogen oxides (NO and NO2), nitrous oxide (N2O) and water vapor. The Spacecraft Maximum Allowable Concentration (SMAC) for NO and NO2 are respectively 4.5 and 0.5 ppm whereas the Threshold Limit Value (TLV) for N2O is 25 ppm.

The purification of waste water is a critical element of any long-duration space mission. The Vapor Phase Catalytic Ammonia Removal (VPCAR) system offers the promise of a technology requiring low quantities of expendable material that is suitable for exploration missions. NASA has funded an effort to produce an engineering development unit specifically targeted for integration into the NASA Johnson Space Center's Integrated Human Exploration Mission Simulation Facility (INTEGRITY) formally known in part as the Bioregenerative Planetary Life Support Test Complex (Bio-Plex) and the Advanced Water Recovery System Development Facility. The system includes a Wiped-Film Rotating-Disk (WFRD) evaporator redesigned with micro-gravity operation enhancements, which evaporates wastewater and produces water vapor with only volatile components as contaminants. Volatile contaminants, including organics and ammonia, are oxidized in a catalytic reactor while they are in the vapor phase.

The Conductivity Sensor designed for use in the Node 3 Water Processor Assembly (WPA) was based on the existing Space Shuttle application for the fuel cell water system. However, engineering analysis has determined that this sensor design is potentially sensitive to two- phase fluid flow (gas/liquid) in microgravity. The source for this sensitivity is the fact that free gas will become lodged between the sensor probe and the wall of the housing without the aid of buoyancy in 1-g. Once gas becomes lodged in the housing, the measured conductivity will be offset based on the volume of occluded gas. A development conductivity sensor was flown on the NASA Microgravity Plane (KC-135) to measure the offset, which was determined to range between 0 and 50%. This range approximates the offset experienced in 1-g gas sensitivity testing.

Hamilton Sundstrand Space Systems International, Inc. (HSSSI) is under contract to NASA Marshall Space Flight Center (MSFC) to develop a Water Processor Assembly (WPA) and Oxygen Generation Assembly (OGA) for the international Space Station (ISS). The WPA produces potable quality water from humidity condensate, carbon dioxide reduction water, water obtained from fuel cells, reclaimed urine distillate, hand wash and oral hygiene waste waters. The Oxygen Generation Assembly (OGA) electrolyzes potable water from the Water Recovery System (WRS) to provide gaseous oxygen to the Space Station module atmosphere. The OGA produces oxygen for metabolic consumption by crew and biological specimens. The OGA also replenishes oxygen lost by experiment ingestion, airlock depressurization, CO2 venting, and leakage. As a byproduct, gaseous hydrogen is generated. The hydrogen will be supplied at a specified pressure range to support future utilization.

Enhancements to the Regenerable Carbon Dioxide Removal System (RCRS) have undergone full-scale, pre-prototype development and testing to demonstrate a redundant system within the volume allotted for the RCRS on the Space Shuttle Orbiter. The concept for a Redundant Regenerable Carbon Dioxide Removal System (RRCRS) utilizes the existing canister of the RCRS, but partitions it into two, independent, two-bed systems. This partitioning allows for two, fully capable RCRS units to be packaged within the original volume, thus reducing stowage volume and launch weight when compared to the flight RCRS plus the backup LiOH system. This paper presents the results of development and testing of a full-scale, pre-prototype RRCRS and includes an overview of the design concept for a redundant system that can be packaged within the existing envelope.

The TIMES system was evaluated to determine its ability to process reverse osmosis (RO) brine as one of the Advanced Water Processor steps. Since preliminary testing performed in 1998 showed that the membrane typically used in the process (Nafion 117) offered a very poor ammonia rejection, a search for an alternate membrane exhibiting high ammonia rejection capability was initiated under NASA-JSC funding. This investigation has resulted in the selection of a PolyVinylAlcohol (PVA) composite membrane as a replacement. When processing RO brine and untreated human urine as feeds, the Pervap 2201 membrane showed a 96% ammonia rejection over a large range of ammonia concentration. The water permeation rates in both laboratory-scale and pilot scale testings were also similar to the Nafion. The water permeance of the Pervap 2201 was approximately 7.5 kg/h/m2/atm (1.1 lb/h/m2/psi).

Carbon dioxide reduction in a closed loop life support system recovers water from otherwise waste carbon dioxide and hydrogen. Incorporation of a carbon dioxide reduction assembly (CRA) into the International Space Station life support system frees up thousands of pounds of payload capacity in the supporting Space Shuttle that would otherwise be required to transport water. Achievement of this water recovery goal requires coordination of the CRA design to work within the existing framework of the interface systems that are either already on orbit or well advanced in their development; namely, the Oxygen Generator Assembly (OGA), Carbon Dioxide Removal Assembly (CDRA) and Water Processor Assembly (WPA). The Oxygen Generation System (OGS) rack is in its final design phase and is scarred to accept later installation of the CRA.

Hamilton Sundstrand Space Systems International (HSSSI) is currently under contract with NASA MSFC to design, fabricate and deliver the Water Processor Assembly (WPA) for the International Space Station (ISS). As part of this effort HSSSI has developed an oxidation catalyst for the catalytic reactor assembly in the WPA. This paper discusses full-scale development reactor testing and the status of the life testing of the oxidation catalyst used in the reactor.

Hamilton Sundstrand Space Systems International, Inc. (HSSSI) is under contract to NASA Marshall Space Flight Center (MSFC) to develop a Water Processor Assembly (WPA) for the International Space Station (ISS). The WPA produces potable quality water from humidity condensate, carbon dioxide reduction water, water obtained from fuel cells, reclaimed urine distillate, shower, handwash and oral hygiene wastewaters. All planned development testing has been completed and this paper provides the status of the development activities and results for the WPA.

This project is a Phase III SBIR contract between NASA and Water Reuse Technology (WRT). It covers the redesign, modification, and construction of the Wiped-Film Rotating-Disk (WFRD) evaporator for use in microgravity and its integration into a Vapor Phase Catalytic Ammonia Removal (VPCAR) system. VPCAR is a water processor technology for long duration space exploration applications. The system is designed as an engineering development unit specifically aimed at being integrated into NASA Johnson Space Center's Bioregenerative Planetary Life Support Test Complex (BIO-Plex). The WFRD evaporator and the compressor are being designed and built by WRT. The balance of the VPCAR system and the integrated package are being designed and built by Hamilton Sundstrand Space Systems International, Inc. (HSSSI) under a subcontract with WRT. This paper provides a description of the VPCAR technology and the advances that are being incorporated into the unit.

The International Space Station Waste Collector Subsystem Risk Mitigation Experiment (ISS WCS RME) was flown as the primary (Shuttle) WCS on Space Shuttle flight STS-104 (ISS-7A) in July 2001, to validate new design enhancements. In general, the WCS is utilized for collecting, storing, and compacting fecal & associated personal hygiene waste, in a zero gravity environment. In addition, the WCS collects and transfers urine to the Shuttle waste storage tank. All functions are executed while controlling odors and providing crew comfort. The ISS WCS previously flew on three Shuttle flights as the Extended Duration Orbiter (EDO) WCS, as it was originally designed to support extended duration Space Shuttle flights up to 30 days in length. Soon after its third flight, the Space Shuttle Program decided to no longer require 30 day extended mission duration capability and provided the EDO WCS to the ISS Program.

Hamilton Sundstrand Space Systems International, Inc. (HSSSI) is under contract to NASA Marshall Space Flight Center (MSFC) to develop a Water Processor Assembly (WPA) and Oxygen Generation Assembly (OGA) for the International Space Station (ISS). The WPA produces potable quality water from humidity condensate, carbon dioxide reduction water, water obtained from fuel cells, reclaimed urine distillate, shower, handwash and oral hygiene waste waters. The Oxygen Generation Assembly (OGA) electrolyzes potable water from the Water Recovery System (WRS) to provide gaseous oxygen to the Space Station module atmosphere. The OGA produces oxygen for metabolic consumption by crew and biological specimens. The OGA also replenishes oxygen lost by experiment ingestion, airlock depressurization, CO2 venting, and leakage. As a byproduct, gaseous hydrogen is generated. The hydrogen will be supplied at a specified pressure range to support future utilization.

The Water Processor developed for the International Space Station includes a high temperature catalytic reactor that utilizes oxygen gas to oxidize dissolved chemicals. The effluent from the reactor is a mixture of gases (O2, CO2, N2) and hot water. Since the crew has requested that drinking water does not contain any free gas at body temperature (37.8 °C or 100 °F), a phase separator operating at elevated temperatures is required downstream of the catalytic reactor. For this application, Hamilton Sundstrand Space Systems International (HSSSI) has developed a passive Gas Liquid Separator (GLS) that relies on a positive barrier - a membrane - to extract the free gas from the inlet two-phase mixture. The membrane selected is a hollow fiber hydrophobic asymmetric membrane with pore size in the ultra-filtration range. This paper outlines the challenges in both design and operation that were overcome during the development of this device.

Hamilton Sundstrand Space Systems International, Inc. HSSSI) is under contract to NASA Marshall Space Flight Center (MSFC) to develop a Water Processor Assembly (WPA) and Oxygen Generation Assembly (OGA) for the International Space Station (ISS). The WPA produces potable quality water from humidity condensate, carbon dioxide reduction water, water obtained from fuel cells, reclaimed urine distillate, shower, handwash and oral hygiene waste waters. The Oxygen Generation Assembly (OGA) electrolyzes potable water from the Water Recover System (WRS) to provide gaseous oxygen to the Space Station module atmosphere. The OGA produces oxygen for metabolic consumption by crew and biological specimens. The OGA also replenishes oxygen lost by experiment ingestion, airlock depressurization, CO2 venting, and leakage. As a byproduct, gaseous hydrogen is generated. The hydrogen will be supplied at a specified pressure range to support future utilization.