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Technical Paper

Structure and properties of a nano-carbon composite surface coating for roll-to-roll manufacturing of titanium fuel cell bipolar plates

2023-09-29
2023-32-0138
In the 1st generation Toyota "MIRAI" fuel cell stack, carbon protective surface coating is deposited after individual Ti bipolar plate being press-formed into the desired shape. Such a process has relatively low production speed, not ideal for large scale manufacturing. A new coating concept, consisting of a nanostructured composite layer of titanium oxide and carbon particles, was devised to enable the incorporation of both the surface treatment and the press processes into the roll-to-roll production line. The initial coating showed higher than expected contact resistance, of which the root cause was identified as nitrogen contamination during the annealing step that inhibited the formation of the composite film structure. Upon the implementation of a vacuum furnace chamber as the countermeasure, the issue was resolved, and the improved coating could meet all the requirements of productivity, conductivity, and durability for use in the newer generation of fuel cell stacks.
Journal Article

Development of a Ceramic EHC

2022-03-29
2022-01-0536
In recent years, electrically heated catalysts (EHCs) have been developed to achieve lower emissions. In several EHC heating methods, the direct heating method, which an electric current is applied directly to the catalyst substrate, can easily activate the catalyst before engine start-up. The research results reported on the use of the direct heating EHC to achieve significant exhaust gas purification during cold start-up [1]. From the perspective of catalyst loading, ceramics is considered to be a better material for the substrate than metal due to the difference in coefficient of thermal expansion between the catalyst and the substrate, but the EHC made of ceramics has difficulties such as controllability of the current distribution, durability and reliability of the connection between the substrate and the electrodes.
Technical Paper

Development of Ultra Low Viscosity 0W-8 Engine Oil

2020-04-14
2020-01-1425
Further fuel economy improvement of the internal combustion engine is indispensable for CO2 reduction in order to cope with serious global environmental problems. Although lowering the viscosity of engine oil is an effective way to improve fuel economy, it may reduce the wear resistance. Therefore, it is important to achieve both improved fuel economy and reliability. We have developed new 0W- 8 engine oil of ultra-low viscosity and achieved an improvement in fuel economy by 0.8% compared to the commercial 0W-16 engine oil. For this new oil, we reduced the friction coefficient under boundary lubrication regime by applying an oil film former and calcium borate detergent. The film former increased the oil film thickness without increasing the oil viscosity. The calcium borate detergent enhanced the friction reduction effect of molybdenum dithiocarbamate (MoDTC).
Technical Paper

Vibrational Analysis Method on High-frequency Electric-drive Motor Noise

2020-04-14
2020-01-0463
When a vehicle is cruising, unpleasant noise in the 4 to 5 KHz high-frequency band can be heard at the center of all seats in the vehicle cabin. In order to specify the source of this noise, the correlation between the noise and airborne noise from the outer surface of the transmission was determined, and transfer path analysis was conducted for the interior of the transmission. The results indicated that the source of the noise was the 0th-order breathing mode specific to the drive motor. To make it possible to predict this at the desk, a vibrational analysis method was proposed for drive motors made up of laminated electrical steel sheets and segment-type coils. Material properties data for the electrical steel sheets and coils was employed in the drive motor vibrational analysis model without change. The shapes of the laminated electrical steel sheets and coils were also accurately modeled.
Technical Paper

Analysis of CVT Element Vibration by In-Situ Measurement

2020-04-14
2020-01-0906
When the belt contacts a pulley in a pushing belt-type CVT, vibration is generated by frictional force due to rubbing between the individual elements that are components of the belt, which is said to increase wear and noise. The authors speculated that the source of that vibration is misalignment of the secondary pulley and primary pulley V-surfaces. To verify that phenomenon, a newly developed micro data logger was attached to an element of a mass-produced metal pushing V-belt CVT and the acceleration was measured at rotations equal to those at drive (1000 to 2500 r/m). In addition, the results of calculations using a behavior analysis model showed that changes in pulley misalignment influence element vibration, and that the magnitude of the vibration is correlated to the change in the metal pushing V-belt alignment immediately before the element contacts the pulley.
Technical Paper

Elucidation of the Sulfide Corrosion Mechanism in Piston Pin Bushings

2020-04-14
2020-01-1079
Recent trends to downsize engines have resulted in lighter weight and greater compactness. At the same time, however, power density has increased due to the addition of turbocharger and other such means to supplement engine power and torque, and this has increased the thermal and mechanical load. In this kind of environment, corrosion of the copper alloy bushing (piston pin bushing) that is press-fitted in the small end of the connecting rod becomes an issue. The material used in automobile bearings, of which the bushing is a typical example, is known to undergo sulfidation corrosion through reaction with an extreme-pressure additive Zinc Dialkyldithiophosphate (ZnDTP) in the lubricating oil. However, that reaction path has not been clarified. The purpose of the present research, therefore, is to clarify the reaction path of ZnDTP and copper in an actual engine environment.
Technical Paper

Development of Simplified Finite Element Model for Ultra-High-Strength Steel Resistance Spot Weld Fractures

2020-04-14
2020-01-0220
This paper describes the development of a simplified fracture finite element (FE) model for resistance spot welds (RSW) of ultra-high-strength steel (UHSS) that can be incorporated into large-scale vehicle FE model. It is known that the RSW of UHSS generates two types of fracture modes: heat-affected zone (HAZ) and nugget zone fractures. Lap shear and peeling coupon tests using UHSS sheets found that the different RSW fracture modes occurred at different nugget diameters. To analyze this phenomenon, detailed simulated coupon tests were carried out using solid hexahedral elements. The analytical results revealed that RSW fractures are defined by both the application of plastic strain on the elements and the stress triaxiality state of the elements. A detailed model incorporating a new fracture criteria model recreated the different UHSS RSW fracture modes and achieved a close correlation with the coupon test results.
Technical Paper

Residual Stress Analysis for Additive Manufactured Large Automobile Parts by Using Neutron and Simulation

2020-04-14
2020-01-1071
Metal additive manufacturing has high potential to produce automobile parts, due to its shape flexibility and unique material properties. On the other hand, residual stress which is generated by rapid solidification causes deformation, cracks and failure under building process. To avoid these problems, understanding of internal residual stress distribution is necessary. However, from the view point of measureable area, conventional residual stress measurement methods such as strain gages and X-ray diffractometers, is limited to only the surface layer of the parts. Therefore, neutron which has a high penetration capability was chosen as a probe to measure internal residual stress in this research. By using time of flight neutron diffraction facility VULCAN at Oak Ridge National Laboratory, residual stress for mono-cylinder head, which were made of aluminum alloy, was measured non-distractively. From the result of precise measurement, interior stress distribution was visualized.
Technical Paper

Development of a New High Orientation Paint System to Achieve Outstanding Real Metallic Designs

2020-04-14
2020-01-0899
Silver metallic colors with thin and smooth aluminum flake pigments have been introduced for luxury brand OEMs. Regarding the paint formulation for these types of colors, low non-volatile(NV) and high aluminum flake pigment contents are known as technology for high metallic appearance designs. However, there are two technical concerns. First is mottling which is caused by uneven distribution of the aluminum flake pigments in paint film and second is poor film property due to high aluminum pigment concentration in paint film. Therefore, current paint systems have limitation of paint design. As a countermeasure for those two concerns, we had investigated cellulose nanofiber (CNF) dispersion liquid as both the coating binder and rheology control agent in a new type of waterborne paint system. CNF is an effective rheology control agent because it has strong hydrogen bonds with other fiber surfaces in waterborne paint.
Technical Paper

Prediction of Ductile Fracture Propagation of High Strength Steels in Automotive Structures

2019-04-02
2019-01-1097
Initiation and propagation of ductile fractures in crashed automotive components made from high strength steels are investigated in order to understand the mechanism of fracture propagation. Fracture of these components is often prone to occur at the sheet edge in a strain concentration zone under crash deformation. The fracture then extends intricately to the inside of the structure under the influence of the local stress and strain field. In this study, a simple tensile test and a 3-point bending test of high strength steels with tensile strengths of 590 MPa and 1180 MPa are carried out. In the tensile test, a coupon having a hole and a notch is deformed in a uniaxial condition. The effect of the notch type on the strain concentration and fracture behavior are investigated by using a digital imaging strain measurement system.
Technical Paper

Development of TLP-AI Technology to Realize High Temperature Operation of Power Module

2019-04-02
2019-01-0607
Application of SiC power devices is regarded as a promising means of reducing the power loss of power modules mounted in power control units. Due to those high thermostable characteristics, the power module with SiC power devices are required to have higher operating temperature than the conventional power module with Si power devices. However, the limitations of current packaging technology prevent the utilization of the full potential of SiC power devices. To resolve these issues, the development of device bonding technology is very important. Although transient liquid phase (TLP) bonding is a promising technology for enabling high temperature operation because its bonding layer has a high melting point, the characteristics of the TLP bonding layer tend to damage the power devices. This paper describes the development of a bonding technology to achieve high temperature operation using a stress reduction effect.
Technical Paper

Development of Traction Motor for New Fuel Cell Vehicle and New Electric Vehicle

2018-04-03
2018-01-0450
Honda’s purpose is to realize the joy and freedom of mobility and a sustainable society in which people can enjoy life. As such, three series of environmental vehicles-FCVs, BEVs, and PHEVs-have been developed so that users in communities around the world can select the ones best suited to their local energy circumstances and individual lifestyles. This paper discusses a structure that enhances both the motive power performance and quietness of a newly developed FCV/BEV traction motor. To enhance motive power performance, the research focused on the stator lamination technique. As for methods of affixing the stator’s layers, the practice with previous models has been adhesion lamination, using electric steel sheets that come pre-made with adhesive layers. Having adhesive layers, however, lowers the ratio (space factor) of steel sheet layers. The new motor uses electric steel sheets without an adhesive layer in order to enhance motive power performance.
Technical Paper

Atomization in High-Pressure Die Casting - Step 2 Simulation of Atomized Flow of Molten Aluminum by LES-VOF Method

2018-04-03
2018-01-1393
The atomization of molten aluminum when injected during high-pressure die casting is analyzed to determine its effect in enhancing the strength of the product being cast. In the previously reported first step of this study, molten aluminum was injected into open space and its atomization was observed photographically. Now in the second step of the study, a simulation is conducted to determine how the molten aluminum becomes atomized at the injection nozzle (gate) and how this atomized material flows and fills the cavity. A new simulation method is developed based on large-eddy simulation coupled with the volume-of-fluid method. The simulation system is verified by comparing its output with photographs taken in the first step of the study. Simulations are then conducted using an approximation of a real cavity to visualize how it is filled by the atomized molten aluminum.
Technical Paper

Research of Atomization Phenomena in HPDC-Step 1 Feature of Gas Porosity Dispersion and Photography of Atomized Flow

2018-04-03
2018-01-1392
In recent years, studies have been conducted on the relationship between the J factor, which indicates flow of molten aluminum at the time of injection, and the quality of HPDC products. The flow of molten metal at a high J factor is referred to as “Atomized Flow.” The authors and others conducted studies on the relationship between the J factor and the strength of HPDC products. An area exceeding 300MPa was found in the product produced at a high J factor corresponding to the “Atomized Flow.” The defect was less in the above-mentioned position because the gas porosity was finely dispersed. Considering that the fine dispersion of gas porosity is related to the “Atomized Flow”, pictures were taken to analyze “Atomized Flow.” The molten aluminum was ejected into an open space at a high speed and the splashed conditions were photographed. From the images taken by the pulse laser permeation, the conditions of microscopic atomized flow were observed precisely.
Technical Paper

Development of Three-Way Catalysts Enhanced NOx Purifying Activity

2018-04-03
2018-01-0942
Growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. One of the key technologies is a new OSC material that has low surface area (SA) and high OSC performance. We enhanced the pyrochlore- ceria/zirconia (CZ) which has a very small SA. In order to enhance the heat resistance and promote the OSC reaction, we selected and optimized the additive element. This material showed high OSC performance especially in the temperature range of 400 degrees or less. Another key technology is washcoat structure that has high gas diffusivity by making connected pore in the washcoat (New pore forming technology).
Technical Paper

Optimizing Transmission Loss for Lightweight Body Structures

2017-06-05
2017-01-1812
In an effort to reduce mass, future automotive bodies will feature lower gage steel or lighter weight materials such as aluminum. An unfortunate side effect of lighter weight bodies is a reduction in sound transmission loss (TL). For barrier based systems, as the total system mass (including the sheet metal, decoupler, and barrier) goes down the transmission loss is reduced. If the reduced surface density from the sheet metal is added to the barrier, however, performance can be restored (though, of course, this eliminates the mass savings). In fact, if all of the saved mass from the sheet metal is added to the barrier, the TL performance may be improved over the original system. This is because the optimum performance for a barrier based system is achieved when the sheet metal and the barrier have equal surface densities. That is not the case for standard steel constructions where the surface density of the sheet metal is higher than the barrier.
Journal Article

Development of GFRTP Crush Box with Consideration of Use Environment and Effect of Fiber Orientation

2017-03-28
2017-01-0498
Regulation of automotive CO2 emissions is becoming increasingly stringent throughout the world in response to global warming. For automakers, this means a focus not only on increasing the fuel economy of powertrains, but also on reducing automotive driving resistance. High expectations are held for thermoplastic fiber-reinforced plastics (FRP) for the realization of automotive weight savings while also offering high levels of productivity and recyclability. Thermoplastic FRP crush boxes display a higher level of energy absorption performance than metal (steel, aluminum, etc.) crush boxes. This will contribute to automotive weight savings and improved package design. In the case of automotive front bumper beam systems, it is necessary to realize stable load characteristics irrespective of the use environment. It is therefore necessary to consider the effects of temperature and thermoplastic resin degradation.
Journal Article

Development of a New Ceramic Substrate with Gas Flow Control Functionality

2017-03-28
2017-01-0919
Emission regulations in many countries and regions around the world are becoming stricter in reaction to the increasing awareness of environment protections, and it has now become necessary to improve the performance of catalytic converters to achieve these goals. A catalytic converter is composed of a catalytically active material coated onto a ceramic honeycomb-structured substrate. Honeycomb substrates play the role of ensuring intimate contact between the exhaust gas and the catalyst within the substrate’s flow channels. In recent years, high-load test cycles have been introduced which require increased robustness to maintain low emissions during the wide range of load changes. Therefore, it is extremely important to increase the probability of contact between the exhaust gas and catalyst. To achieve this contact, several measures were considered such as increasing active sites or geometrical surface areas by utilizing substrates with higher cell densities or larger volumes.
Journal Article

Development of Heat Resistant Titanium Alloy for Exhaust Valves Applicable for Motorcycles

2016-11-08
2016-32-0023
Amidst of the recent concerns on depletion of natural resources, a new heat resistant titanium alloy has been developed using the minimum amount of rare metals. Using Ti-811 as a basis and modifying the alloy composition to Ti-7Al-2Mo-0.2Si-0.15C-0.2Nb, the mechanical property, the creep resistance and the oxidation resistance at high temperatures are improved. At the same time, with the β transformation point shifted to a higher temperature, the hot formability is also improved. The newly developed alloy has made it possible to expand the application of titanium material to exhaust valves in reciprocating engines.
Journal Article

Development of Base Metal Catalyst and Its Compatibility Study for Motorcycle Applications

2016-11-08
2016-32-0071
We developed a copper catalyst using zero Platinum group metals (hereafter PGMs) to fit motorcycle specific emission gas environment. Though many research reports to develop catalyst without using PGMs that are precious and costly resources are available, no reports had proven Base Metal Catalyst development to meet actual emission regulation equivalent to PGM catalysts. Compared to conventional PGM catalysts, higher temperature is required to keep high catalytic conversion efficiency by utilizing properties of this Base Metal Catalyst. Thus, this Base Metal Catalyst is located in cross coupling position, though it is rare case in motorcycle. This catalyst location could cause negative impacts on engine knocking, engine performance and drivability. This time, to overcome such negative impacts we optimized whole exhaust system, including parts around catalyst.
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