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Technical Paper

Effect of Properties and Additives of Gasoline on Low-Speed Pre-Ignition in Turbocharged Engines

2022-08-30
2022-01-1077
Gasoline-related factors that affect low-speed pre-ignition (LSPI) include the distillation properties of gasoline, manganese (Mn), ethanol, diesel fuel, detergent for aftermarket, and iron (Fe). The combined effect of Mn with ethanol or high calcium engine oil (high-Ca oil) has not been sufficiently clarified. Therefore, appropriate countermeasures for LSPI have not yet been implemented. To clarify the effect of the gasoline properties and additives on LSPI, engine tests were conducted using gasoline with different “PM Index” values, an indicator of distillation properties, different concentrations of Mn, ethanol, diesel fuel, detergent, Fe, and high-Ca oil. The results showed that the LSPI frequency tended to increase with the PM Index, Mn up to 60 ppm, diesel fuel up to 2 vol.%, and detergent up to three times the standard amount.
Technical Paper

Study on Haptic Maneuver Guidance by Periodic Knocks on Accelerator Pedal

2015-03-10
2015-01-0039
This study proposes a method for presenting maneuver request information of accelerator pedal to a driver via the accelerator pedal itself. By applying periodic force like vibration on an accelerator pedal, information is transferred to the driver without displacing the accelerator pedal. In this study, the authors focus on a saw-tooth wave as the periodic force. When the saw-tooth-waved force is applied on the accelerator pedal, a human driver feels as if the accelerator pedal is knocked by someone periodically. In addition, information about the quantity of requested maneuver can be transferred by the amplitude of the saw-tooth wave. Based on these facts, the saw-tooth wave is modified and optimized empirically with ten human drivers so that the information of direction is transferred most reliably. In addition, the relationship between the amplitude of the saw-tooth wave and requested quantity of the pedal maneuver that the drivers feel is formulated.
Journal Article

Comparison of Fires in Lithium-Ion Battery Vehicles and Gasoline Vehicles

2014-04-01
2014-01-0428
Electric vehicles have become more popular and may be involved in fires due to accidents. However, characteristics of fires in electric vehicles are not yet fully understood. The electrolytic solution of lithium-battery vehicles is inflammable, so combustion characteristics and gases generated may differ from those of gasoline cars. Therefore, we conducted fire tests on lithium-ion battery vehicles and gasoline vehicles and investigated the differences in combustion characteristics and gases generated. The fire tests revealed some differences in combustion characteristics. For example, in lithium-ion battery vehicles, the battery temperature remained high after combustion of the body. However, there was almost no difference in the maximum CO concentration measured 0.5 to 1 m above the roof and 1 m from the side of the body. Furthermore, HF was not detected in either type of vehicle when measured at the same positions as for CO.
Journal Article

HC Traps for Gasoline and Ethanol Applications

2013-04-08
2013-01-1297
In-line hydrocarbon (HC) traps are not widely used to reduce HC emissions due to their limited durability, high platinum group metal (PGM) concentrations, complicated processing, and insufficient hydrocarbon (HC) retention temperatures required for efficient conversion by the three-way catalyst component. New trapping materials and system architectures were developed utilizing an engine dynamometer test equipped with dual Fourier Transform Infrared (FTIR) spectrometers for tracking the adsorption and desorption of various HC species during the light-off period. Parallel laboratory reactor studies were conducted which show that the new HC trap formulations extend the traditional adsorption processes (i.e., based on physic-sorption and/or adsorption at acid sites) to chemical reaction mechanisms resulting in oligomerized, dehydro-cyclization, and partial coke formation.
Technical Paper

Investigations of the impact of 10% ethanol blended fuels on performances of sold gasoline vehicles in the Japanese market already on the road in Japan

2011-08-30
2011-01-1987
The study of 10% ethanol blended gasoline (E10 gasoline) utilization has been conducted in the Japan Auto-Oil Program (JATOP). In order to clarify the impact of E10 gasoline on vehicle performances, exhaust emissions, evaporative emissions, driveability and material compatibility have been investigated by using domestic gasoline vehicles including mini motor vehicles which are particular to Japan. The test results reveal that E10 gasoline has no impact on exhaust emissions, engine startup time and acceleration period under the hot start condition, but a slight deterioration is observed in some test cases under the cold start condition using E10 gasolines with 50% distillation temperature (T50) level set to the upper limit of Japanese Industrial Standards (JIS) K 2202. Regarding evaporative emissions, the tested vehicles shows no remarkable increase in the hot soak loss (HSL), diurnal breathing loss (DBL) and running loss (RL) testing with E10 gasolines.
Technical Paper

Unregulated Emissions Evaluation of Gasoline Combustion Systems (Lean Burn / Stoichiometric DISI and MPI), State of the Art Diesel Aftertreatment Technologies (DPF, urea-SCR and DOC), and Fuel Qualities Effects (EtOH, ETBE, Aromatics and FAME)

2007-10-29
2007-01-4082
In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.
Technical Paper

Study of Future Engine Oil (First Report): Future Engine Oil Scenario

2007-07-23
2007-01-1977
In recent years, problems such as global warming, the depletion of natural resources, and air pollution caused by emissions are emerging on a global scale. These problems call for efforts directed toward the development of fuel-efficient engines and exhaust gas reduction measures. As a solution to these issues, performance improvements should be achieved on the oil that lubricates the sliding sections of engines. This report points to features required of future engine oil-such as contribution to fuel consumption, minimized adverse effects on the exhaust gas aftertreatment system, and improved reliability achieved by sludge reduction-and discusses the significance of these features. For engine oil to contribution of engine oil to lower fuel consumption, we examined the effects of reduced oil viscosity on friction using gasoline and diesel engines.
Technical Paper

Investigations of Compatibility of ETBE Gasoline with Current Gasoline Vehicles II

2007-07-23
2007-01-2039
JCAPII gasoline workgroup reported vehicle emission study to comprehend the impact of ETBE blending. In previous study, we focused on the compatibility of ETBE blended gasoline with Japanese current gasoline vehicles in-use. Based on recent discussion with ETBE 8% blended gasoline into the market, more information becomes necessary. In this second report, we studied to comprehend the actual emission impact using realistic model fuels using several base stocks. Fuel properties of T50, T90 and aromatic compound content were selected through discussions. Specifications were changed within the range of the market. Both ETBE 0% and 8% were combined for these fuel matrixes. In total, eight fuels and two reference fuels were tested. Two J-ULEV vehicles (one MPI, and a stoichiometric-SIDI) were procured as representatives. We discussed quantitative and qualitative impact toward emissions. Data regarding CO2 and fuel economy change were also reported.
Technical Paper

Investigations of Compatibility of ETBE Gasoline with Current Gasoline Vehicles

2006-10-16
2006-01-3381
Clarifying the impact of ETBE 8% blended fuel on current Japanese gasoline vehicles, under the Japan Clean Air Program II (JCAPII) we conducted exhaust emission tests, evaporative emission tests, durability tests on the exhaust after-treatment system, cold starting tests, and material immersion tests. ETBE 17% blended fuel was also investigated as a reference. The regulated exhaust emissions (CO, HC, and NOx) didn't increase with any increase of ETBE content in the fuel. In durability tests, no noticeable increase of exhaust emission after 40,000km was observed. In evaporative emissions tests, HSL (Hot Soak Loss) and DBL (Diurnal Breathing Loss) didn't increase. In cold starting tests, duration of cranking using ETBE 8% fuel was similar to that of ETBE 0%. In the material immersion tests, no influence of ETBE on these material properties was observed.
Technical Paper

Influence of Ferrocene on Engine and Vehicle Performance

2006-10-16
2006-01-3448
Ferrocene is used as an antiknock additive to replace lead alkyls. To clarify the influence of one metal additive, ferrocene, on engine, following experiments were carried out. The insulation resistance of spark plugs was measured, deposits in the engine were analyzed, and an exhaust emission and fuel economy tests were conducted using gasoline containing ferrocene. The deposit, which contained iron oxides, adhered to the combustion chamber, spark plugs, and exhaust pipe when the engine operated with gasoline containing ferrocene. When vehicles operated with gasoline containing ferrocene, fuel consumption increased and the exhaust temperature rose. In addition, an abnormal electrical discharge pattern was observed in spark plugs operating at high temperatures. Iron-oxide of Fe3O4 is changed into Fe2O3 under high temperatures. Discharge current flows in iron oxides including Fe2O3 because the conductivity of Fe2O3 increases at high temperatures.
Technical Paper

Fire Safety Evaluation of a Vehicle Equipped with Hydrogen Fuel Cylinders: Comparison with Gasoline and CNG Vehicles

2006-04-03
2006-01-0129
In this study, we evaluated the fire safety of vehicles that use compressed hydrogen as fuel. We conducted fire tests on vehicles that used compressed hydrogen and on vehicles that used compressed natural gas and gasoline and compared temperatures around the vehicle and cylinder, internal pressure of the cylinder, irradiant heat around the vehicle, sound pressure levels when the pressure relief device (PRD) was activated, and damage to the vehicle and surrounding flammable objects. The results revealed that vehicles equipped with compressed hydrogen gas cylinders are not more dangerous than CNC or gasoline vehicles, even in the event of a vehicle fire.
Technical Paper

Effect of Alcohol Fuels on Fuel-Line Materials of Gasoline Vehicles

2005-10-24
2005-01-3708
In 1999, some Japanese fuel suppliers sold highly concentrated alcohol fuels, which are mixtures of gasoline and oxygenates, such as alcohol or ether, in amounts of 50% or more. In August 2001, it was reported that some vehicle models using the highly concentrated alcohol fuels encountered fuel leakage and vehicle fires due to corrosion of the aluminum used for the fuel-system parts. The Ministry of Economy, Trade and Industry (METI) and the Ministry of Land, Infrastructure and Transport Government of Japan (MLIT) jointly established the committee on safety for highly concentrated alcohol fuels in September 2001. The committee consisted of automotive technology and metal corrosion experts knowledgeable about preventing such accidents and ensuring user safety. Immersion tests were conducted on metals and other materials used for the fuel-supply system parts to determine the corrosion resistance to each alcohol component contained in the highly concentrated alcohol fuels.
Technical Paper

Analysis of Low Concentration Aldehyde and Ketone Compounds in Automotive Exhaust Gas by New Collection Reagent.

2005-05-11
2005-01-2152
Acidified 2,4-dinitrophenylhydrazine (DNPH) solution, or DNPH-impregnated cartridges are commonly used for the collection of automotive exhaust carbonyl compounds. There are some DNPH-carbonyl compounds in not in use DNPH cartridges and DNPH solution. Furthermore, concentrations of automotive exhaust carbonyl compounds are decreasing according to improvement of the purification technology for automotive exhaust. Automotive exhaust carbonyl compounds become to be difficult to be analyzed with DNPH collection method, because of these two reasons. It is thought that reliable analysis of acrolein in automotive exhaust is very difficult because concentration of DNPH-acrolein in extracted solution is not stable. Furthermore, it is found out that DNPH-acrolein in DNPH-cartridge is disappeared for short time storage in this research.
Technical Paper

Study of Antiknock Performance Under Various Octane Numbers and Compression Ratios in a DISI Engine

2003-05-19
2003-01-1804
This paper presents a study of antiknock performance under various octane numbers and compression ratios in a direct injection spark ignition (DISI) gasoline engine. The relationship between the octane number and engine performance in the DISI engine-the engine torque and the break specific fuel consumption (BSFC)-was investigated in comparison with a multipoint injection (MPI) engine. Due to the improvement in the charging efficiency and the advance of the ignition timing by cooled aspiration, the engine torque of the DISI engine was improved over that of the MPI engine. It was also found that the octane number requirement (ONR) was reduced. In addition, the possibility of engine performance enhancement at high compression ratios was studied. At high compression ratios, the engine torque is reduced due to the heavy knocking when low octane gasoline is used. However, an improvement in the engine torque has been observed with high octane gasoline.
Technical Paper

Fuel-Cell Vehicle Fuels: Evaluating the Reforming Performance of Gasoline Components

2003-03-03
2003-01-0414
Fuel cell vehicles (FCVs) are an emerging transportation technology, with a potential to provide very low vehicle emissions and significant improvements in fuel efficiency. The choice of a fuel for FCVs must consider several critical issues, including the availability of a distribution and storage infrastructure, manufacturing cost and capital requirements,energy efficiency, and performance. Gasoline, one of the candidate fuels, is noteworthy not only for its existing infrastructure, but because it has the possibility of usage for both FCVs and conventional internal combustion engines. Gasoline consists of different types of hydrocarbons, including paraffins, naphthens, olefins and aromatics - - with carbon numbers distributed over a wide range. Gasoline also contains a variety of sulfur compounds and selected additives in small amounts., In some cases gasoline also contains oxygenates such as MTBE and ethanol.
Technical Paper

Evaluation of the Effect of Fuel Composition and Gasoline Additives on Combustion Chamber Deposits

1996-10-01
962012
Since 1992 some vehicles have experienced engine knock or rapping noise during cold starts that is caused by combustion chamber deposit interference (CCDI) To better understand the CCDI phenomena, engine dynamometer studies were conducted. Results show that base gasoline composition and detergent additive compositions have significant effects on combustion chamber deposit (CCD) build-up In addition to engine testing, thermogravimetric analysis (TGA) was used to determine a correlation between unwashed gum and CCD levels
Technical Paper

Application of a Mini-Dilution Tube in the Study of Fuel Effects on Stratified Charge Engine Emissions and Combustion

1981-10-01
811198
A mini-dilution tube to measure particulate emissions is described and results obtained in an application are presented. The application selected is a study of fuel effects on stratified charge engine emission and combustion characteristics. The mini-dilution tube was developed to provide a capability for particulate measurements with dynamometer engines. The device has been demonstrated to yield particulate mass results agreeing to within 10 percent of those with a full scale tunnel in steady state tests with diesel powered vehicles. A PROCO engine modified by incorporation of Torch Ignition was used in the study. Fuels were a wide cut gasoline, methanol and Indolene Clear gasoline. The engine was operated at a speed of 1250 rpm with an indicated mean effective pressure of 390 kPa. Spark timing, injection timing, EGR and equivalence ratio were varied.
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