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The 12 V advanced start stop systems can offer 5-8% fuel economy improvement over a conventional vehicle. Although the fuel economy is not as high as those of mild to full hybrids, its low implementation cost makes it an attractive electrification solutions for vehicles. As a result, the 12 V advanced start stop technology has been evolving fast in recent years. On one hand, battery suppliers are offering a variety of energy storage solutions such as stand-alone lead acid, stand-alone LFP/Graphite, dual batteries of lead acid parallel with NMC/LTO, LMO/LTO, NMC/Graphite, and capacitors, etc. For dual battery solutions, the architecture also varies from passive parallel connection to active switching. On the other hand, OEM are considering to leverage a lot more use out of traditional 12 V SLI (start, light, and ignition) for functions such as power steering, air conditioning, heater, etc.

Lithium plating is an important failure factor for lithium ion battery with carbon-based anodes and therefore preventing lithium plating has been a critical consideration in designs of lithium ion battery and battery management system. The challenges are: How to determine the charging current limits which may vary with temperature, state of charge, state of health, and battery operations? Where are the optimization rooms in battery design and management system without raising plating risks? Due to the complex nature of lithium plating dynamics it is hard to detect and measure the plating by any of experimental means. In this work we developed an electrochemical model that explicitly includes lithium plating reaction. It enables both determination of plating onset and quantification of plated lithium. We have studied the effects of charging pulses on homogenous plating in order to provide guidance for lithium ion battery design in hybrid applications.

Power limit estimation of a lithium-ion battery system plays an important balancing role of optimizing the battery design cost, maximizing for power and energy, and protecting the battery from abusive usage to achieve the intended life. The power capability estimation of any given lithium-ion battery system is impacted by the variability of many sources, such as cell and system components resistance, temperature, cell capacity, and real time state of charge and state of health estimation errors. This causes a distribution of power capability among battery packs that are built to the same design specification. We demonstrated that real time power limit estimation can only partially address the system variability due to the errors introduced by itself. Integrating feedback control algorithms with the lithium-ion battery model maximizes the battery power capability, improves the battery robustness to variabilities, and reduces the real time estimation errors.

The microhybrid electric vehicle (MHEV) has increasingly received attention since it holds promise for significant increases in fuel economy vs. traditional gasoline vehicles at a lower price point than hybrid vehicles. Passive parallel connection of the traditional 12V lead acid battery and a high power lithium ion battery has been identified as a potential architecture that will facilitate fuel economy improvements with minimal changes to the electrical network. Enabling a passive dual-battery connection requires a design match between the two batteries, including characteristics such as battery size and resistance, so that the performance can be optimized. In this work we have developed a hybrid model that couples electrochemical model of lithium ion battery (NMC-Graphite as an example) and an equivalent circuit model of lead acid battery in order to study the behavior of 12V dual-battery microhybrid architectures.

Cell balancing is a key function of battery management system (BMS) that is implemented to maximize the battery's available capacity and service life. The increasing demand of larger and better performance pack has raised the need to investigate the various cell balancing techniques so that the energy of the battery can be fully realized. In this work we develop a phenomenological model in order to quantify the benefits of passive balancing and active balancing. The electrical response of a model pack consisting of serially connected lithium ion cells is simulated with Matlab. The effects of the variance of cell capacity, internal resistance, self-discharge rates, pack configuration and size are studied. The possible optimization rooms for implementing passive and active balancing are suggested.