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This paper describes the after-treatment technology that could be used to meet a future BS-VII standard, considering close-coupled SCR (cc-SCR) to help start NOx conversion earlier. Both active (Cu/Fe-SCR based) and passive (V-SCR based) systems have the potential to meet emission limits. V-SCR may be considered in the rear position because V-SCR shows a fast response with very low N2O formation. Next-gen V-SCR technology shows significantly improved performance and durability closer to Cu-SCR. The steady-state NOx conversions over Next-Gen V-SCR were better than BS-VI V-SCR in both fresh and aged-580°C/100h conditions. High durability was also observed after engine aging of 1000h (WHTC + high load). Another big challenge in BS VII could be the PN10 requirement. With enhanced filtration coating (EFC) technology, PN emissions drop drastically in comparison to Euro VI reference without EFC to meet a future BS VII.

Effective 1st April 2023, India's automotive emissions regulation has shifted from BS-VI Stage-1 to BS-VI Stage-2 standard the after-treatment systems need to demonstrate robust performance not just on the cycle, but also to demonstrate emissions for on-road Real Driving Emission (RDE) conditions. A stringent On-Board Diagnostics (OBD) strategy to monitor the real-time emission levels along with compliance Road Driving Emissions (RDEs) are focus areas for BS VI Stage-2 emission legislation. The maximum speed on MIDC is 90km/h in BS-VI Stage-1, Diesel Oxidation Catalyst (DOC)+Selective Catalyst Reduction Filter (SCRF®) was able to meet legislation at the lab, and now with the RDE cycle max speed of the vehicles under the M1 category <3.5 T will have the max permitted legal limit shall surpass 100 km/h for not around 3% of the span in the third phase of driving cycle for which max speed is up to 120 km/h.

Internal combustion engines will continue to be the leading power-train in the heavy-duty, on-highway sector as technologies like hydrogen, fuel cells, and electrification face challenges. Natural gas (NG) engines offer several advantages over diesel engines including near zero particle matter (PM) emissions, lower NOx emissions, lower capital and operating costs, availability of vast domestic NG resources, and lower CO2 emissions being the cleanest burning of all hydrocarbons (HC). The main limitation of this type of engine is the lower efficiency compared to diesel counterparts. Addressing the limitations (knock and misfire) for achieving diesel-like efficiencies is key to accomplishing widespread adoption, especially for the US market. With the aim to achieve high brake thermal efficiency (BTE), three (3) computational fluid dynamics (CFD) optimized pistons with three different compression ratios (CR) have been tested.

Diesel oxidation catalyst (DOC) is one of the critical catalyst components in modern diesel aftertreatment systems. It mainly converts unburned hydrocarbon (HC) and CO to CO2 and H2O before they are released to the environment. In addition, it also oxidizes a portion of NO to NO2, which improves the NOx conversion efficiency via fast SCR over the downstream selective catalytic reduction (SCR) catalyst. HC light-off tests, with or without the presence of NOx, has been typically used for DOC evaluation in laboratory. In this work, we aim to understand the influences of DOC light-off experimental conditions, such as initial temperature, initial holding time, HC species, with or without the presence of NOx, on the DOC HC light-off behavior. The results indicate that light-off test with lower initial temperature and longer initial holding time (at its initial temperature) leads to higher DOC light-off temperature.

The prediction accuracy of a three-way catalyst (TWC) model is highly associated with the ability of the model to incorporate the reaction kinetics of the emission process as a lambda function. In this study, we investigated the O2 and H2 concentration profiles of TWC reactions and used them as critical inputs for the development of a global TWC model. We presented the experimental data and global kinetic model showing the impact of thermal degradation on the performance of the TWC. The performance metrics investigated in this study included CH4, NOx, and CO conversions under lean, rich, and dithering light-off conditions to determine the kinetics of oxidation reactions and reduction/reforming/water-gas shift reactions as a function of thermal aging. The O2 and H2 concentrations were measured using mass spectrometry to track the change in the oxidation state of the catalyst and to determine the mechanism of the reactions under these light-off conditions.

Dynamic Skip Fire (DSF®) has been shown to significantly reduce CO2 on gasoline engines and has been in mass production since 2018. Diesel Dynamic Skip Fire (dDSF™) builds upon the technology and extends it to diesel engine applications. dDSF is an advanced cylinder deactivation technology that allows the deactivation of any number of cylinders dynamically to deliver the requested torque while maintaining acceptable noise, vibration, and harshness (NVH) performance. NOx regulations are becoming progressively more stringent on light, medium and heavy-duty (HD) diesel engines. Meeting low NOx standards is becoming increasingly challenging, especially in lightly loaded operating conditions where maintaining ideal aftertreatment system efficiency is difficult. Most existing techniques to increase aftertreatment temperatures at low loads incur a fuel consumption penalty, which increases greenhouse gas emissions.

Gasoline Direct Injection (GDI) vehicles now make up the majority of European new car sales and a significant share of the existing car parc. Despite delivering measurable engine efficiency benefits, GDI fuel systems are not without issues. Fuel injectors are susceptible to the formation of deposits in and around the injector nozzles holes. It is widely reported that these deposits can affect engine performance and that different fuels can alleviate the buildup of those deposits. This project aims to understand the underlying mechanisms of how deposit formation ultimately leads to a reduction in vehicle performance. Ten GDI fuel injectors, with differing levels of coking were taken from engine testing and consumer vehicles and compared using a range of imaging and engine tests. At the time of writing, a new GDI engine test is being developed by the Co-ordinating European Council (CEC) to be used by the fuel and fuel additive industry.

Tailpipe particle number (PN) emission limits for heavy-duty diesel engines have been introduced as part of the off-highway Stage V standards. To meet the required limits a diesel particulate filter (DPF) with high filtration efficiency is required. The DPF relies on formation of a soot cake layer on the channel walls to achieve this high filtration efficiency. Off highway Stage V certification cycles are significantly higher in temperature than their on-highway counterparts, leading to difficulty in creating and maintaining a soot cake in the DPF. Hence for these applications meeting particle number requirements is challenging. To meet the high filtration efficiency requirements the DPF will have to reduce mean pore size, pore standard deviation, and increase wall thickness, in turn increasing backpressure, which results in a fuel consumption penalty. Another option is to evaluate the impact of temperature stable ash accumulation on DPF filtration efficiency.

The head gasket of an internal combustion engine acts as a critical seal between its cylinder block and heads. Typically, and ideally, a high horse power engine head gasket will be composed of elastomer fluid sealing elements in a carrier and combustion seal body composed of aluminum, brass, carbon steel, copper, nickel, and/or stainless steel etc. The head gaskets purpose is to seal high pressure combustion gases, coolant, and oil and to ensure no leakage of gases or fluids out of the block to head joint. Three major failure modes [1] for cylinder head gasket joint are; 1. Fluid or gas leakage due to low sealing pressure. 2. Head gasket (bead) cracking due to high gap alternation and 3. Gasket scrubbing/fretting due to pressure and temperature fluctuations causing relative movement in the joint. During engine operation, the head gasket design should be robust enough to prevent all failure modes and provide acceptable performance.

Advanced emission control systems for diesel engines usually include a combination of Diesel Oxidation Catalyst (DOC), Diesel Particulate Filter (DPF), Selective Catalytic Reduction (SCR), and Ammonia Slip Catalyst (ASC). The performance of these catalysts individually, and of the aftertreatment system overall, is negatively affected by the presence of oxides of sulfur, originating from fuel and lubricant. In this paper, we illustrated some key aspects of sulfur interactions with the most commonly used types of catalysts in advanced aftertreatment systems. In particular, DOC can oxidize SO2 to SO3, collectively referred to as SOx, and store these sulfur containing species. The key functions of a DOC, such as the ability to oxidize NO and HC, are degraded upon SOx poisoning. The impact of sulfur poisoning on the catalytic functions of a DPF is qualitatively similar to DOC.

For renewable fuels to displace petroleum, they must be compatible with emissions control devices. Pure biodiesel contains up to 5 ppm Na + K and 5 ppm Ca + Mg metals, which have the potential to degrade diesel emissions control systems. This study aims to address these concerns, identify deactivation mechanisms, and determine if a lower limit is needed. Accelerated aging of a production exhaust system was conducted on an engine test stand over 1001 h using 20% biodiesel blended into ultra-low sulfur diesel (B20) doped with 14 ppm Na. This Na level is equivalent to exposure to Na at the uppermost expected B100 value in a B20 blend for the system full-useful life. During the study, NOx emissions exceeded the engine certification limit of 0.33 g/bhp-hr before the 435,000-mile requirement.

Ambient temperature has significant impact on engine start ability and cold start emissions from diesel engines. These cold start emissions are accounted for substantial amount of the overall regulatory driving cycle emissions like NEDC or FTP. It is likely to implement the low temperature emissions tests for diesel vehicles, which is currently applicable only for gasoline vehicles. This paper investigates the potential of the intake heating strategy on reducing the driving cycle emissions from the latest generation of turbocharged common rail direct injection diesel engines at low ambient temperature conditions. For this investigation an air heater was installed upstream of the intake manifold and New European Driving Cycle (NEDC) tests were conducted at -7°C ambient temperature conditions for the different intake air temperatures. Intake air heating reduced the cranking time and improved the fuel economy at low ambient temperatures.

Future heavy-duty diesel (HDD) engines are designed to have higher engine out NOx, for improved fuel economy, while reduction of the emission control technology footprint is also desired. Consequently, higher NOx reduction across compact emission control systems is required. Selective catalytic reduction (SCR) catalyst coating combined with a wall flow particulate filter (SCRF®1) is a technology that enables abatement of NOx emissions in addition to oxidation of soot from diesel engine exhausts. Vanadia based-SCR is well known for NOx reduction and is active for hydrocarbon (HC) and particulate matter (PM) oxidation. This dual functionality (oxidation and reduction reactions) of the V.SCR catalysts plus the filtration achieved by the filter substrate can help certain diesel engine applications achieve the legislative limits with a reduced packaging volume.

Diesel engines are the versatile power source and is widely used in passenger car and commercial vehicle applications. Environmental temperature conditions, fuel quality, fuel injection strategies and lubricant have influence on cold start performance of the diesel engines. Strategies to overcome the cold start problem at very low ambient temperature include preheating of intake air, coolant, cylinder block. The present research work investigates the effect of coolant temperatures on passenger car diesel engine’s performance and exhaust emission characteristics during the cold start at cold ambient temperature conditions. The engine is soaked in the -7°C environment for 6 hours. The engine coolant is preheated to the desired coolant temperatures of 10 and 20°C by an external heater and the start ability tests were performed.

In recent years magnetic resonance imaging (MRI) has been shown to be an attractive method for fluid flow visualization. In this work, we show how MRI velocimetry techniques can be used to non-invasively investigate and visualize the hydrodynamics of exhaust gas in a diesel particulate filter (DPF), both when clean and after loading with diesel engine exhaust particulate matter. The measurements have been used to directly measure the gas flow in the inlet and outlet channels of the DPF, both axial profiles along the length and profiles across the channel diameter. Further, from this information we show that it is possible to indirectly ascertain the superficial wall-flow gas velocity and the soot loading profiles along the filter channel length.

One field-returned DPF loaded with a high amount of ash is examined using experimental and modeling approaches. The ash-related design factors are collected by coupling the inspection results from terahertz spectroscopy with a calibrated DPF model. The obtained ash packing density, ash layer permeability and ash distribution profile are then used in the simulation to assess the ash impact on DPF backpressure and regeneration behaviors. The following features have been observed during the simulation: 1 The ash packing density, ash layer permeability and ash distribution profile should be collected at the same time to ensure the accurate prediction of ash impact on DPF backpressure. Missing one ash property could mislead the measurement of the other two parameters and thus affects the DPF backpressure estimation. 2 The ash buildup would gradually increase the frequency for the backpressure-based active soot regeneration.

In this contribution, nuanced changes of a commercial Cu-SSZ-13 catalyst with hydrothermal aging, which have not been previously reported, as well as their corresponding impact on SCR functions, are described. In particular, a sample of Cu-SSZ-13 was progressively aged between 550 to 900°C and the changes of performance in NH3 storage, oxidation functionality and NOx conversion of the catalyst were measured after hydrothermal exposure at each temperature. The catalysts thus aged were further characterized by NH3-TPD, XRD and DRIFTS techniques for structural changes. Based on the corresponding performance and structural characteristics, three different regimes of hydrothermal aging were identified, and tentatively as assigned to “mild”, “severe” and “extreme” aging. Progressive hydrothermal aging up to 750°C decreased NOx conversion to a small degree, as well as NH3 storage and oxidation functions.

The high global warming potential of nitrous oxide (N2O) led to its inclusion in the list of regulated greenhouse gas (GHG) pollutants [1, 2]. The mitigation of N2O on aftertreatment catalysts was shown to be ineffective as its formation and decomposition temperatures do not overlap. Therefore, the root causes for N2O formation were investigated to enable the catalyst architectures and controls development for minimizing its formation. In a typical heavy-duty diesel exhaust aftertreatment system based on selective catalytic reduction of NOx by ammonia derived from urea (SCR), the main contributors to tailpipe N2O are expected to be the undesired reaction between NOx and NH3 over SCR catalyst and NH3 slip in to ammonia slip catalyst (ASC), part of which gets oxidized to N2O.

Combustion behaviour and emissions characteristics of different blending ratios of diesel and gasoline fuels (Dieseline) were investigated in a light-duty 4-cylinder compression-ignition (CI) engine operating on partially premixed compression ignition (PPCI) mode. Experiments show that increasing volatility and reducing cetane number of fuels can help promote PPCI and consequently reduce particulate matter (PM) emissions while oxides of nitrogen (NOx) emissions reduction depends on the engine load. Three different blends, 0% (G0), 20% (G20) and 50% (G50) of gasoline mixed with diesel by volume, were studied and results were compared to the diesel-baseline with the same combustion phasing for all experiments. Engine speed was fixed at 1800rpm, while the engine load was varied from 1.38 to 7.85 bar BMEP with the exhaust gas recirculation (EGR) application.

This study investigates the potential of using a partial flow filter (PFF) to assist a wall flow diesel particulate filter (DPF) and reduce the need for active regeneration phases that increase engine fuel consumption. First, the filtration efficiency of the PFF was studied at several engine operating conditions, varying the filter space velocity (SV), through modification of the exhaust gas flow rate, and engine-out particulate matter (PM) concentration. The effects of these parameters were studied for the filtration of different particle size ranges (10-30 nm, 30-200 nm and 200-400 nm). For the various engine operating conditions, the PFF showed filtration efficiency over 25% in terms of PM number and mass. The PFF filtration behaviour was also investigated at idle engine operation producing a high concentration of nuclei particulates for which the filter was able to maintain 60% filtration efficiency.