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The growing demand for transportation fuels and the global emphasis on reducing greenhouse gas (GHG) emissions have led to increased interest in analyzing transport GHG emissions from the life-cycle perspective. Methanol, a potentially carbon-neutral fuel synthesized from CO2 and H2, has emerged as a promising candidate. This paper conducts a comprehensive life-cycle analysis (LCA) of the GHG emissions associated with the methanol production process, utilizing data inventory from China in 2019. To simulate the synthesis and distillation process of methanol, Aspen Plus is employed, using parameters obtained from actual plants. GHG emissions are then calculated using the GREET model, incorporating updated industry statistics and research findings. The CO2 necessary for methanol production is captured from factory flue gas.

Internal combustion engines will continue to be the leading power-train in the heavy-duty, on-highway sector as technologies like hydrogen, fuel cells, and electrification face challenges. Natural gas (NG) engines offer several advantages over diesel engines including near zero particle matter (PM) emissions, lower NOx emissions, lower capital and operating costs, availability of vast domestic NG resources, and lower CO2 emissions being the cleanest burning of all hydrocarbons (HC). The main limitation of this type of engine is the lower efficiency compared to diesel counterparts. Addressing the limitations (knock and misfire) for achieving diesel-like efficiencies is key to accomplishing widespread adoption, especially for the US market. With the aim to achieve high brake thermal efficiency (BTE), three (3) computational fluid dynamics (CFD) optimized pistons with three different compression ratios (CR) have been tested.

Diesel oxidation catalyst (DOC) is one of the critical catalyst components in modern diesel aftertreatment systems. It mainly converts unburned hydrocarbon (HC) and CO to CO2 and H2O before they are released to the environment. In addition, it also oxidizes a portion of NO to NO2, which improves the NOx conversion efficiency via fast SCR over the downstream selective catalytic reduction (SCR) catalyst. HC light-off tests, with or without the presence of NOx, has been typically used for DOC evaluation in laboratory. In this work, we aim to understand the influences of DOC light-off experimental conditions, such as initial temperature, initial holding time, HC species, with or without the presence of NOx, on the DOC HC light-off behavior. The results indicate that light-off test with lower initial temperature and longer initial holding time (at its initial temperature) leads to higher DOC light-off temperature.

The prediction accuracy of a three-way catalyst (TWC) model is highly associated with the ability of the model to incorporate the reaction kinetics of the emission process as a lambda function. In this study, we investigated the O2 and H2 concentration profiles of TWC reactions and used them as critical inputs for the development of a global TWC model. We presented the experimental data and global kinetic model showing the impact of thermal degradation on the performance of the TWC. The performance metrics investigated in this study included CH4, NOx, and CO conversions under lean, rich, and dithering light-off conditions to determine the kinetics of oxidation reactions and reduction/reforming/water-gas shift reactions as a function of thermal aging. The O2 and H2 concentrations were measured using mass spectrometry to track the change in the oxidation state of the catalyst and to determine the mechanism of the reactions under these light-off conditions.

Ethanol fuel blends with gasoline for spark ignition (SI) internal combustion engines are widely used on account of their advantages in terms of fuel economy and emissions reduction potential. The focus of this paper is to study the effects of these blends on combustion characteristics such as in-cylinder pressure profiles, gas-phase emissions (e.g., unburned hydrocarbons, NOx) and particulates (e.g., particulate matter and particle number) using both measurement campaigns and digital engineering workflows. Nineteen load-speed operating points in a 1L 3-cylinder GDI SI engine were measured and modelled. The measurements for in-cylinder pressure and emissions were repeated at each operating point for three types of fuel: gasoline (E0, 0% by volume of ethanol blend), E10 (10 % by volume of ethanol blend) and E20 (20% by volume of ethanol blend).

A heavy-duty diesel engine (ETH-LAV single cylinder MTU396 heavy duty research engine) was simulated by RANS and advanced reacting flow models to gain insight into its soot and NOx emissions. Due to symmetry, a section of the engine containing a single injector-hole was simulated. Dodecane was used as a surrogate to emulate the evaporation properties of diesel and a 22-step reaction mechanism for n-heptane was used to describe combustion. The Conditional Moment Closure (CMC) method was used as the combustion model in two ways. In a more conventional modelling approach, CMC was fully interfaced with the CFD and a two-equation model was employed for determining soot while the extended Zeldovich mechanism was used for NOx. In a second approach called the Imperfectly Stirred Reactor (ISR) method, the CMC equation was integrated over space and the previous RANS-CMC solution was further analysed in a post-processing step with the focus on soot.

Dynamic Skip Fire (DSF®) has been shown to significantly reduce CO2 on gasoline engines and has been in mass production since 2018. Diesel Dynamic Skip Fire (dDSF™) builds upon the technology and extends it to diesel engine applications. dDSF is an advanced cylinder deactivation technology that allows the deactivation of any number of cylinders dynamically to deliver the requested torque while maintaining acceptable noise, vibration, and harshness (NVH) performance. NOx regulations are becoming progressively more stringent on light, medium and heavy-duty (HD) diesel engines. Meeting low NOx standards is becoming increasingly challenging, especially in lightly loaded operating conditions where maintaining ideal aftertreatment system efficiency is difficult. Most existing techniques to increase aftertreatment temperatures at low loads incur a fuel consumption penalty, which increases greenhouse gas emissions.

Gasoline Direct Injection (GDI) vehicles now make up the majority of European new car sales and a significant share of the existing car parc. Despite delivering measurable engine efficiency benefits, GDI fuel systems are not without issues. Fuel injectors are susceptible to the formation of deposits in and around the injector nozzles holes. It is widely reported that these deposits can affect engine performance and that different fuels can alleviate the buildup of those deposits. This project aims to understand the underlying mechanisms of how deposit formation ultimately leads to a reduction in vehicle performance. Ten GDI fuel injectors, with differing levels of coking were taken from engine testing and consumer vehicles and compared using a range of imaging and engine tests. At the time of writing, a new GDI engine test is being developed by the Co-ordinating European Council (CEC) to be used by the fuel and fuel additive industry.

Tailpipe particle number (PN) emission limits for heavy-duty diesel engines have been introduced as part of the off-highway Stage V standards. To meet the required limits a diesel particulate filter (DPF) with high filtration efficiency is required. The DPF relies on formation of a soot cake layer on the channel walls to achieve this high filtration efficiency. Off highway Stage V certification cycles are significantly higher in temperature than their on-highway counterparts, leading to difficulty in creating and maintaining a soot cake in the DPF. Hence for these applications meeting particle number requirements is challenging. To meet the high filtration efficiency requirements the DPF will have to reduce mean pore size, pore standard deviation, and increase wall thickness, in turn increasing backpressure, which results in a fuel consumption penalty. Another option is to evaluate the impact of temperature stable ash accumulation on DPF filtration efficiency.

The head gasket of an internal combustion engine acts as a critical seal between its cylinder block and heads. Typically, and ideally, a high horse power engine head gasket will be composed of elastomer fluid sealing elements in a carrier and combustion seal body composed of aluminum, brass, carbon steel, copper, nickel, and/or stainless steel etc. The head gaskets purpose is to seal high pressure combustion gases, coolant, and oil and to ensure no leakage of gases or fluids out of the block to head joint. Three major failure modes [1] for cylinder head gasket joint are; 1. Fluid or gas leakage due to low sealing pressure. 2. Head gasket (bead) cracking due to high gap alternation and 3. Gasket scrubbing/fretting due to pressure and temperature fluctuations causing relative movement in the joint. During engine operation, the head gasket design should be robust enough to prevent all failure modes and provide acceptable performance.

This paper investigates the energy efficiency and emissions benefits possible with connected and autonomous vehicles (CAVs). Such benefits could be instrumental in decarbonising the transport sector. The impact of CAV technology on operation, usage and specification of vehicles for optimised energy efficiency is considered. Energy consumption reductions of 55% – 66% are identified for a fully autonomous road transport system versus the present. 46% is possible for a CAV on today’s roads. Smoothing effects and reduced stoppage in the drive cycle achieve a 31% reduction in travel time if speed limits are not reduced. CAV powertrain optimised for different scenarios requires just 10 kW – 40 kW maximum power whilst the vehicle mass is reduced by up to 40% relative to current cars. Urban-optimised powertrain, with only 10 kW – 15 kW maximum power, allows energy consumption reductions of over 71%.

Advanced emission control systems for diesel engines usually include a combination of Diesel Oxidation Catalyst (DOC), Diesel Particulate Filter (DPF), Selective Catalytic Reduction (SCR), and Ammonia Slip Catalyst (ASC). The performance of these catalysts individually, and of the aftertreatment system overall, is negatively affected by the presence of oxides of sulfur, originating from fuel and lubricant. In this paper, we illustrated some key aspects of sulfur interactions with the most commonly used types of catalysts in advanced aftertreatment systems. In particular, DOC can oxidize SO2 to SO3, collectively referred to as SOx, and store these sulfur containing species. The key functions of a DOC, such as the ability to oxidize NO and HC, are degraded upon SOx poisoning. The impact of sulfur poisoning on the catalytic functions of a DPF is qualitatively similar to DOC.

For renewable fuels to displace petroleum, they must be compatible with emissions control devices. Pure biodiesel contains up to 5 ppm Na + K and 5 ppm Ca + Mg metals, which have the potential to degrade diesel emissions control systems. This study aims to address these concerns, identify deactivation mechanisms, and determine if a lower limit is needed. Accelerated aging of a production exhaust system was conducted on an engine test stand over 1001 h using 20% biodiesel blended into ultra-low sulfur diesel (B20) doped with 14 ppm Na. This Na level is equivalent to exposure to Na at the uppermost expected B100 value in a B20 blend for the system full-useful life. During the study, NOx emissions exceeded the engine certification limit of 0.33 g/bhp-hr before the 435,000-mile requirement.

The underbody of a truck is responsible for an appreciable portion of the vehicle’s aerodynamic drag, and thus its fuel consumption. This paper investigates experimentally the flow around side-skirts, a common underbody aerodynamic device which is known to be effective at reducing vehicle drag. A full, 1/10 scale European truck model is used. The chassis of the model is designed to represent one that would be found on a typical trailer, and is fully reconfigurable. Testing is carried out in a water towing tank, which allows the correct establishment of the ground flow and rotating wheels. Optical access into the underbody is possible through the clear working section of the facility. Stereoscopic and planar Particle Image Velocimetry (PIV) set-ups are used to provide both qualitative images of and quantitative information on the flow field.

Ambient temperature has significant impact on engine start ability and cold start emissions from diesel engines. These cold start emissions are accounted for substantial amount of the overall regulatory driving cycle emissions like NEDC or FTP. It is likely to implement the low temperature emissions tests for diesel vehicles, which is currently applicable only for gasoline vehicles. This paper investigates the potential of the intake heating strategy on reducing the driving cycle emissions from the latest generation of turbocharged common rail direct injection diesel engines at low ambient temperature conditions. For this investigation an air heater was installed upstream of the intake manifold and New European Driving Cycle (NEDC) tests were conducted at -7°C ambient temperature conditions for the different intake air temperatures. Intake air heating reduced the cranking time and improved the fuel economy at low ambient temperatures.

Diesel engines are the versatile power source and is widely used in passenger car and commercial vehicle applications. Environmental temperature conditions, fuel quality, fuel injection strategies and lubricant have influence on cold start performance of the diesel engines. Strategies to overcome the cold start problem at very low ambient temperature include preheating of intake air, coolant, cylinder block. The present research work investigates the effect of coolant temperatures on passenger car diesel engine’s performance and exhaust emission characteristics during the cold start at cold ambient temperature conditions. The engine is soaked in the -7°C environment for 6 hours. The engine coolant is preheated to the desired coolant temperatures of 10 and 20°C by an external heater and the start ability tests were performed.

Gasoline direct injection (GDI) engines have become very attractive in transportation due to several benefits over preceding engine technologies. However, GDI engines are associated with higher levels of particulate matter (PM) emissions, which is a major concern for human health. The aim of this work is to broaden the understanding of the effect of hydrogen combustion and the influence of the three way catalytic converter (TWC) on PM emission characteristics. The presence of hydrogen in GDI engines has been reported to reduce fuel consumption and improve the combustion process, making it possible to induce higher rates of EGR. A prototype exhaust fuel reformer build for on-board vehicle hydrogen-rich gas (reformate) production has been integrated within the engine operation and studied in this work.

In recent years magnetic resonance imaging (MRI) has been shown to be an attractive method for fluid flow visualization. In this work, we show how MRI velocimetry techniques can be used to non-invasively investigate and visualize the hydrodynamics of exhaust gas in a diesel particulate filter (DPF), both when clean and after loading with diesel engine exhaust particulate matter. The measurements have been used to directly measure the gas flow in the inlet and outlet channels of the DPF, both axial profiles along the length and profiles across the channel diameter. Further, from this information we show that it is possible to indirectly ascertain the superficial wall-flow gas velocity and the soot loading profiles along the filter channel length.

Microreactor, engine bench tests and modelling studies have been carried out to understand the influence of cold start (low temperatures) on the performance of NH3/urea-SCR automotive exhaust aftertreatment systems. Water storage experiments using Simultaneous Thermal Analysis (STA) coupled with numerical modelling demonstrated that the exo/endo-therms associated with water adsorption and desorption at temperatures below 150°C strongly influence the catalyst temperature. Appreciable amounts of NO and NO2 could be stored on the catalyst during reactor or engine testing in the absence of any NH3 (blank tests). Modelling studies at different inlet NO2/NOx ratios demonstrated some of the influences of these surface adsorbed species on the performance of the SCR system during cold start.

One field-returned DPF loaded with a high amount of ash is examined using experimental and modeling approaches. The ash-related design factors are collected by coupling the inspection results from terahertz spectroscopy with a calibrated DPF model. The obtained ash packing density, ash layer permeability and ash distribution profile are then used in the simulation to assess the ash impact on DPF backpressure and regeneration behaviors. The following features have been observed during the simulation: 1 The ash packing density, ash layer permeability and ash distribution profile should be collected at the same time to ensure the accurate prediction of ash impact on DPF backpressure. Missing one ash property could mislead the measurement of the other two parameters and thus affects the DPF backpressure estimation. 2 The ash buildup would gradually increase the frequency for the backpressure-based active soot regeneration.