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To meet stringent emission standards, a considerable amount of development work is necessary to ensure suitable efficiency and durability of catalyst systems. The main challenge is to reduce the engine cold-start emissions. Close-coupled catalyst (CCC) provides fast light-off time by utilizing the energy in the exhaust gas. However, if some malfunction occurred during engine operation and the catalyst temperature exceeds 1050°C, the catalytic converter becomes deactivated and shows poor conversion efficiency. Close-coupled catalyst temperature was investigated under various engine operating conditions. All of the experiments were conducted with a 1.0L SI engine at 1500-4000 rpm. The engine was operated at no load to full load conditions. Exhaust gas temperature and catalyst temperature were measured as a function of lambda value (0.8-1.2), ignition timing (BTDC 30°-ATDC 30°) and misfire rates (0-28%).