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Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.

This paper presents a large eddy simulation study of the liquid spray mixing with hot ambient gas in a constant volume vessel under engine-like conditions with the injection pressure of 1500 bar, ambient density 22.8 kg/m₃, ambient temperature of 900 K and an injector nozzle of 0.09 mm. The simulation results are compared with the experiments carried out by Pickett et al., under similar conditions. Under modern direct injection diesel engine conditions, it has been argued that the liquid core region is small and the droplets after atomization are fine so that the process of spray evaporation and mixing with the air is controlled by the heat and mass transfer between the ambient hot gas and central fuel flow. To examine this hypothesis a simple spray breakup model is tested in the present LES simulation. The simulations are performed using an open source compressible flow solver, in OpenFOAM.

Unburned hydrocarbon (UHC) and carbon monoxide (CO) emission sources are examined in an optical, light-duty diesel engine operating under low load and engine speed, while employing a highly dilute, partially premixed low-temperature combustion (LTC) strategy. The impact of engine load and charge dilution on the UHC and CO sources is also evaluated. The progression of in-cylinder mixing and combustion processes is studied using ultraviolet planar laser-induced fluorescence (UV PLIF) to measure the spatial distributions of liquid- and vapor-phase hydrocarbon. A separate, deep-UV LIF technique is used to examine the clearance volume spatial distribution and composition of late-cycle UHC and CO. Homogeneous reactor simulations, utilizing detailed chemical kinetics and constrained by the measured cylinder pressure, are used to examine the impact of charge dilution and initial stoichiometry on oxidation behavior.

The paper describes a novel method for calculating the residual gas fraction and the trapping efficiency in a 2 stroke engine. Assuming one dimensional compressible flow through the inlet and exhaust ports, the method estimates the instantaneous mass flowing in and out from the combustion chamber; later the residual gas fraction and trapping efficiency are estimated combining together the perfect displacement and perfect mixing scavenging models. It is assumed that when the intake port opens, the fresh mixture is pushing out the burned charge without any mixing and after a multiple of the time needed for the largest eddy to perform one rotation, the two gasses are instantly mixed up together and expelled. The result is a very simple algorithm that does not require much computational time and is able to estimate with high level of precision the trapping efficiency and the residual gas fraction in 2 stroke engines.

It has been known from multi-zone simulations that HCCI combustion can be significantly affected by temperature stratification of the in-cylinder gas. With the same combustion timing (i.e. crank angles at 50% heat release, denoted as CA50), large temperature stratification tends to prolong the combustion duration and lower down the in-cylinder pressure-rise-rate. With low pressure-rise-rate HCCI engines can be operated at high load, therefore it is of practical importance to look into more details about how temperature stratification affects the auto-ignition process. It has been realized that multi-zone simulations can not account for the effects of spatial structures of the stratified temperature field, i.e. how the size of the hot and cold spots in the temperature field could affect the auto-ignition process. This question is investigated in the present work by large eddy simulation (LES) method which is capable of resolving the in-cylinder turbulence field in space and time.

Nowadays for small-scale power generation there are electrochemical batteries and mini engines. Many efforts have been done for improving the power density of the batteries but unfortunately the value of 1 MJ/kg seems to be asymptotic. If the energy source is an organic fuel which has an energy density of around 29 MJ/kg with a minimum overall efficiency of only 3.5%, this device would surpass the batteries. This paper is the fifth of a series of publications aimed to study the HCCI combustion process in the milli domain at high engine speed in order to design and develop VIMPA, Vibrating Microengine for Low Power Generation and Microsystems Actuation. Previous studies ranged from general characterization of the HCCI combustion process by using metal and optical engines, to more specific topics for instance the influence of the boundary layer and quenching distance on the quality of the combustion.

In HCCI you do not have the same control of the combustion like in SI and Diesel engines. Controlling the start of a combustion event is a difficult task and requires feedback from previous cycles. This feedback can be retrieved from ion current measurements. By applying a voltage over the spark gap, ions will lead a current and a signal that represents the combustion in the cylinder will be retrieved. Voltages of 450 V were used. The paper describes a new method to enhance the combustion phasing from the Ion current trace in HCCI engines. The method is using the knowledge of how the signal should look. This is known due to the fact that the shape of the ion current signal is similar from cycle to cycle. This new observation is shown in the paper. Also the correlation between the ion current and CA50 was studied. Later the signals have been used for combustion feedback.

Nowadays the power supplying systems have a fundamental importance for all small and portable devices. For low power applications, there are two main ways for producing power: electrochemical batteries and mini engines. Even though in recent years many developments have been carried out in improving the design of batteries, the energy density of 1MJ/kg seems to be an asymptotic value. If the energy source is a hydrocarbon fuel, whose energy density is 46 MJ/kg, with an overall efficiency of only 2.5 % it is possible to surpass the electrochemical batteries. On the other hand, having a mini engine, as energy source, implies three main problems: vibrations, noise and emissions. A light (230 g) model airplane engine with a displacement volume of 4.11 cm3 and a geometrical compression ratio of 13.91 has been studied. The work carried out in this paper can be divided basically in three parts.

In this paper a fast NOx model is presented which can be used for engine optimization, aftertreatment control or virtual mapping. A cylinder pressure trace is required as input data. High calculation speed is obtained by using table interpolation to calculate equilibrium temperatures and species concentrations. Test data from a single-cylinder engine and from a complete six-cylinder engine have been used for calibration and validation of the model. The model produces results of good agreement with emission measurements using approximately 50 combustion product zones and a calculation time of one second per engine cycle. Different compression ratios, EGR rates, injection timing, inlet pressures etc. were used in the validation tests.

The main benefit of HCCI engines compared to SI engines is improved fuel economy. The drawback is the diluted combustion with a substantially smaller operating range if not some kind of supercharging is used. The reasons for the higher brake efficiency in HCCI engines can be summarized in lower pumping losses and higher thermodynamic efficiency, due to higher compression ratio and higher ratio of specific heats if air is used as dilution. In the low load operating range, where HCCI today is mainly used, other parameters as friction losses, and cooling losses have a large impact on the achieved brake efficiency. To initiate the auto ignition of the in-cylinder charge a certain temperature and pressure have to be reached for a specific fuel. In an engine with high in-cylinder cooling losses the initial charge temperature before compression has to be higher than on an engine with less heat transfer.

Autoignition of a homogeneous mixture is very sensitive to operating conditions, therefore fast control is necessary for reliable operation. There exists several means to control the combustion phasing of an Homogeneous Charge Compression Ignition (HCCI) engine, but most of the presented controlled HCCI result has been performed with single-input single-output controllers. In order to fully operate an HCCI engine several output variables need to be controlled simultaneously, for example, load, combustion phasing, cylinder pressure and emissions. As these output variables have an effect on each other, the controller should be of a structure which includes the cross-couplings between the output variables. A Model Predictive Control (MPC) controller is proposed as a solution to the problem of load-torque control with simultaneous minimization of the fuel consumption and emissions, while satisfying the constraints on cylinder pressure.

Heavy trucks contribute significantly to the overall air pollution, especially NOx and PM emissions. Models to predict the emissions from heavy trucks in real world on road conditions are therefore of great interest. Most such models are based on data achieved from stationary measurements, i.e. engine maps. This type of “quasi stationary” models could also be of interest in other applications where emission models of low complexity are desired, such as engine control and simulation and control of exhaust aftertreatment systems. In this paper, results from quasi stationary calculations of fuel consumption, CO, HC, NOx and PM emissions are compared with time resolved measurements of the corresponding quantities. Measurement data from three Euro 3-class engines is used. The differences are discussed in terms of the conditions during transients and correction models for quasi stationary calculations are presented. Simply using engine maps without transient correction is not sufficient.

In this paper the combustion chamber wall temperature was measured by the use of thermographic phosphor. The temperature was monitored over a large time window covering a load transient. Wall temperature measurement provide helpful information in all engines. This temperature is for example needed when calculating heat losses to the walls. Most important is however the effect of the wall temperature on combustion. The walls can not heat up instantaneously and the slowly increasing wall temperature following a load transient will affect the combustion events sucseeding the transient. The HCCI combustion process is, due to its dependence on chemical kinetics more sensitive to wall temperature than Otto or Diesel engines. In depth knowledge about transient wall temperature could increase the understanding of transient HCCI control. A “black box” state space model was derived which is useful when predicting transient wall temperature.

A five-cylinder diesel engine, converted to a single cylinder operated optical engine is run in Homogeneous Charge Compression Ignition (HCCI) mode. A blend of iso-octane and n-heptane is used as fuel. An experimental study of the horizontal boundary layer between the main combustion and the non-reacting surface of the combustion chamber is conducted as a function of speed, load, swirl and injection strategy. The combustion behaviour is monitored by chemiluminescence measurements. For all cases an interval from -10 to 16 crank angles after top dead center (CAD ATDC) in steps of one CAD are studied. One image-intensified camera observes the boundary layer up close from the side through a quartz cylinder liner while a second camera has a more global view from below to see more large scale structure of the combustion. The averaged chemiluminescence intensity from the HCCI combustion is seen to scale well with the rate of heat release.

An air hybrid is a vehicle with an ICE modified to also work as an air compressor and air motor. The engine is connected to two air reservoirs, normally the atmosphere and a high pressure tank. The main benefit of such a system is the possibility to make use of the kinetic energy of the vehicle otherwise lost when braking. The main difference between the air hybrid developed in this paper and earlier air hybrid concepts is the introduction of a pressure tank that substitutes the atmosphere as supplier of low air pressure. By this modification, a very high torque can be achieved in compressor mode as well as in air motor mode. A model of an air hybrid with two air tanks was created using the engine simulation code GT-Power. The results from the simulations were combined with a driving cycle to estimate the reduction in fuel consumption.

High-speed laser diagnostics was utilized for single-cycle resolved studies of the formaldehyde distribution in the combustion chamber of an HCCI engine. A multi-YAG laser system consisting of four individual Q-switched, flash lamp-pumped Nd:YAG lasers has previously been developed in order to obtain laser pulses at 355 nm suitable for performing LIF measurements of the formaldehyde molecule. Bursts of up to eight pulses with very short time separation can be produced, allowing capturing of LIF image series with high temporal resolution. The system was used together with a high-speed framing camera employing eight intensified CCD modules, with a frame-rate matching the laser pulse repetition rate. The diagnostic system was used to study the combustion in a truck-size HCCI engine, running at 1200 rpm using n-heptane as fuel. By using laser pulses with time separations as short as 70 μs, cycle-resolved image sequences of the formaldehyde distribution were obtained.

Autoignition of a homogeneous mixture is very sensitive to operating conditions. Therefore fast combustion phasing control is necessary for reliable operation. There are several means to control the combustion phasing of a Homogeneous Charge Compression Ignition (HCCI) engine. This paper presents cycle-to-cycle cylinder individual control results from a six-cylinder HCCI engine using a Variable Valve Actuation (VVA) system. As feedback signal, the crank angle for 50% burned, based on cylinder pressure, is used. Three control structures are evaluated, Model Predictive Control (MPC), Linear Quadratic Gaussian control (LQG) and PID control. In the control design of the MPC and LQG controller, dynamic models obtained by system identification were used. Successful experiments were performed on a port-injected six-cylinder heavy-duty Diesel engine operating in HCCI mode.

A naturally aspirated in-line six-cylinder 2.9-litre Volvo engine is operated in Homogeneous Charge Compression Ignition (HCCI) mode, using camshafts with low lift and short duration generating negative valve overlap. Standard port fuel injection is used and pistons and cylinder head are unchanged from the automotive application. HCCI through negative valve overlap is recognized as one of the possible implementation strategies of HCCI closest to production. It is important to gain knowledge of the constraints and limits on the possible operating region. In this work, the emphasis is on investigating how cycle-to-cycle and cylinder-to-cylinder deviations limit the operating region, how these effects change in different parts of the operating region and how they can be controlled. At low load the cycle-to-cycle phenomena cause periodic behavior in combustion timing; together with cylinder deviations this is found responsible for decreasing the operating regime.

Exhaust Emissions from lean burn natural gas engines may not always be as low as the potential permits, especially engines with open loop lambda control. These engines can produce much higher emissions than a comparable diesel engine without exhaust gas after treatment. Even if the engine has closed loop lambda control, emissions are often unacceptably high for future emission regulations. A three way catalyst is, today, the best way to reduce hazardous emissions. The drawback is that the engine has to operate with a stoichiometric mixture and this leads to; higher heat losses, higher pumping work at low to medium loads, higher thermal stress on the engine and higher knock tendency (requiring lower compression ratio, and thus lower brake efficiency). One way to reduce these drawbacks is to dilute the stoichiometric mixture with EGR. This paper compares lean burn operation with operation at stoichiometric conditions diluted with EGR, and using a three way catalyst.

Piston temperature experiments were conducted in a single-cylinder heavy-duty Diesel research engine, based on the Volvo Powertrain D12C engine both by use of optical temperature sensitive phosphor and of thermocouples mounted on the piston surface. In the former case, a thin coating of a suitable thermographic phosphor was applied to the areas on the piston surface to be investigated. The optical measurements of piston temperatures made involved use of an optical window and of an endoscope. The possibility of using optical fibres into guide light in and out of the engine was also investigated. Results of the optical and of the thermocouple measurements were compared and were also related to more global data with the aim of exploring the use of thermographic phosphors for piston- temperature measurements in Diesel engines. Thermographic phosphors thermometry was found to represent an alternative to the thermocouple method since it easily can be applied to various piston geometries.