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The trace contaminant control system (TCCS) located in the International Space Station's (ISS) U.S. laboratory module employs physical adsorption, thermal catalytic oxidation, and chemical adsorption to remove trace chemical contamination produced by equipment offgassing and anthropogenic sources from the cabin atmosphere. The chemical adsorption stage, consisting of a packed bed of granular lithium hydroxide (LiOH), is located after the thermal catalytic oxidation stage and is designed to remove acid gas byproducts that may be formed in the upstream oxidation stage. While in service on board the ISS, the LiOH bed exhibited a change in flow resistance that leading to flow control difficulties in the TCCS. Post flight evaluation revealed LiOH granule size attrition among other changes. An experimental program was employed to investigate mechanisms hypothesized to contribute to the change in the packed bed's flow resistance.

A habitable atmosphere is a fundamental requirement for human spaceflight. To meet this requirement, the cabin atmosphere must be constantly scrubbed to maintain human life and system functionality. The primary system for atmospheric scrubbing of the US on-orbit segment (USOS) of the International Space Station (ISS) is the Trace Contaminant Control System (TCCS). As part of the Environmental Control and Life Support Systems' (ECLSS) atmosphere revitalization rack in the US Lab, the TCCS operates continuously, scrubbing trace contaminants generated primarily by two sources: the metabolic off-gassing of crew members and the off-gassing of equipment in the ISS. It has been online for approximately 95% of the time since activated in February 2001. The TCCS is comprised of a charcoal bed, a catalytic oxidizer, and a lithium hydroxide post-sorbent bed, all of which are designed to be replaced on-orbit when necessary.

The design and operation of crewed spacecraft requires identifying and evaluating chemical compounds that may present reactivity and compatibility risks with the environmental control and life support (ECLS) system. Such risks must be understood so that appropriate design and operational controls, including specifying containment levels, can be instituted or an appropriate substitute material selected. Operational experience acquired during the International Space Station (ISS) program has found that understanding ECLS system and environmental impact presented by thermal control system working fluids is imperative to safely operating any crewed space exploration vehicle. Perfluorocarbon fluids are used as working fluids in thermal control fluid loops on board the ISS. Also, payload hardware developers have identified perfluorocarbon fluids as preferred thermal control working fluids.