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Computational fluid dynamics (CFD) model has been widely applied in internal combustion (IC) engine research. The integration of chemical kinetic model with CFD provides an opportunity for researchers to investigate the detailed chemical reactions for better understanding the combustion process of IC engines. However, the simulation using CFD has generally focused on the examination of primary parameters, such as temperature and species distributions. The detailed investigation on chemical reactions is limited. This paper presents the development of a post-processing tool capable of calculating the rate of production (ROP) of interested species with the known temperature, pressure, and concentration of each species in each cell simulated using CONVERGE-SAGE CFD model.

This paper presents the emission characteristics of a HCCI engine operation using n-heptane. The experiments were conducted in a single cylinder Co-operative Fuel Research (CFR) engine equipped with an air-assist port fuel injector. The effects of intake temperature, air/fuel ratio, compression ratio, turbo-charging, and EGR rate on exhaust emissions were explored. The analysis of the exhaust gases included oxides of nitrogen (NOx), nitrous oxide (N2O), carbon monoxide (CO), total hydrocarbon (THC), and soot. The hydrocarbon species present in exhaust gases and their concentrations at several operating conditions were also characterized. The strategies to obtain low HC, CO and NOx emissions are presented and discussed. The approaches to effectively retard HCCI combustion phase without deteriorating combustion efficiency are examined. It was found that HCCI combustion produces extremely low soot and NOx emissions.

The operation of S.I. engines on lean or diluents containing gaseous fuel-air mixtures is attractive in principle since it can provide improved fuel economy, reduced tendency to knock and low NOx emissions combined with a possible improvement to the operational life of the engine. However, the overall flame propagation rates then tend to drop sharply as the operational mixture is excessively leaned or diluted with CO2 or N2. The paper presents experimental data obtained in a single cylinder, variable compression ratio, S.I., CFR engine when operated on a number of gaseous fuels and some of their mixtures. A gradual leaning of the operating mixture can affect adversely in turn, emissions of CO and unburned fuel and cyclic variation. The extent of deterioration in these operating parameters is shown to correlate well with the corresponding values of the combustion period, a key combustion indicator. Similar effects were observed when adding diluents to stoichiometric CH4-air mixtures.