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In recent years, the dimethyl ether (DME) fuel has been attracting attention as an alternative engine in terms of diesel utilization. This is (a) because its cetane number is close to that of diesel fuel, (b) an innovative chemical process has been developed to produce DME efficiently from natural gas and coal, and (c) DME as a fuel has fewer environment-polluting characteristics than diesel fuel. Inasmuch as DME fuel have lower molecular weights, a molecular C-O bond, and are much more volatile or evaporative than diesel fuel, it is possible to control particulate matters much more easily when DME is used instead of diesel fuel. As for NOx, however, even when using DME, there still remain problems under stringent exhaust gas regulations. Developed and optimized accordingly has been the NOx storage-reduction (NSR) system, using the DME engine with a common-rail injection system. The NSR system is coated with an NOx storage catalyst principally comprised of Pt and Rh.