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A combination of optical imaging diagnostics has been applied to the fuel jet of a direct-injection diesel engine to study the ignition and early soot formation processes. Measurements were made in an optically accessible direct-injection diesel engine of the “heavy-duty” size class at a representative medium speed (1200 rpm) operating condition. Two fuels were used, a 42.5 cetane number mixture of the diesel reference fuels and a new low-sooting fuel (needed to reduce optical attenuation at later crank angles) that closely matches both the cetane number and boiling point of the reference fuel mixture. The combustion and soot formation processes are found to be almost identical for both fuels. Ignition and early combustion were studied by imaging the natural chemiluminescence using a calibrated intensified video camera. The early soot development was investigated via luminosity imaging and simultaneous planar imaging of laser-induced incandescence (LII) and elastic scattering.