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La1-xAxNi1-yByO3 nanostructured perovskite-type oxides catalysts (where A = Na, K, Rb and B = Cu; x = 0, 0.2 and y = 0, 0.05, 0.1), also supporting 2% in weight of gold, were prepared via the so-called “Solution Combustion Synthesis (SCS)” method, and characterized by means of XRD, BET, FESEM-EDS and TEM analyses. The performance of these catalysts evaluated. The 2 wt.% Au-La0.8K0.2Ni0.9Cu0.1O3 showed the best performance with a peak carbon combustion temperature of 367°C and the half conversion of CO reached at 141°C. The same nanostructured catalyst, deposited by in situ SCS directly over a SiC filter and tested on real diesel exhaust gases, fully confirmed the encouraging results obtained on the powder catalyst.

La1-xAxNi1-yByO3 nanostructured perovskite-type oxides catalysts (where A = Na, K, Rb and B = Cu; x = 0, 0.2 and y = 0, 0.05, 0.1), also supporting 2% in weight of gold, were prepared via the so-called “Solution Combustion Synthesis (SCS)” method, and characterized by means of XRD, BET, FESEM-EDS and TEM analyses. The performance of these catalysts towards the simultaneous oxidation of soot and CO was evaluated. The 2 wt.% Au-La0.8K0.2Ni0.9Cu0.1O3 showed the best performance with a peak carbon combustion temperature of 367 °C and the half conversion of CO reached at 141 °C. The same nanostructured catalyst, deposited by in situ SCS directly over a SiC filter and tested on real diesel exhaust gases, fully confirmed the encouraging results obtained on the powder catalyst.

Nano-structured perovskite-type oxides catalysts La1-xAxFe1-yByO3 (where A = Na, K, Rb and B = Cu), prepared by the Solution Combustion Synthesis (SCS) method and characterized by BET, XRD, FESEM, AAS and catalytic activity tests in microreactors and engine bench, proved to be effective in the simultaneous removal of soot and NO, the two prevalent pollutants in diesel exhaust gases in the temperature range 350-450°C. The best compromise between soot and nitrogen oxide abatement was shown by La-K-Cu-FeO3 catalyst which displayed the highest catalytic activity towards carbon combustion and the highest NO conversion activity.

Nano-structured bulk Li-substituted La-Cr perovskites were prepared, characterized, tested in comparison with the reference LaCrO3. The progressive increase in the Li content of the catalysts induces an increase in the catalytic activity owing to the enhancement of the amount of weakly chemisorbed oxygen O-species, key players in the soot oxidation mechanism. However, beyond 20% Cr substitution with Li, part of this latter metal was segregated as LiCrO2. The best single-phase catalyst (La0.8Cr0.8Li0.2O3) was already active well below 350°C. Catalytic traps were prepared by in situ combustion synthesis within cordierite and SiC wall-flow filters on the basis of the above catalysts and tested on real diesel exhaust gases in an engine bench, fully confirming the encouraging results obtained on powder catalysts.