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Heat transfer to the combustion chamber walls constitutes a significant portion of the overall energy losses over the working cycle of a direct injection (DI) diesel engine. In the last few decades, numerous research efforts have been devoted to investigating the prospects of boosting efficiency by insulating the combustion chamber. Relatively few studies have focused on the prospects of reducing emissions by applying combustion chamber insulation. A main purpose of this study is to assess the potential of reducing in-cylinder soot as well as boosting aftertreatment performance by means of partially insulating the combustion chamber. Based on the findings from a conceptual study, a Low Heat Rejection (LHR) design, featuring a Nimonic 80A insert into an Aluminum piston, was developed and tested experimentally at various loads in a single-cylinder Hatz-engine.

An optimum combustion chamber was designed for a reverse-tumble wall-controlled gasoline direct-injection engine by systematically optimizing each design element of the combustion system. The optimization was based on fuel-economy, hydrocarbon, combustion-stability and smoke measurements at a 2000 rev/min test-point representation of road-load operating condition. The combustion-chamber design parameters that were optimized in this study included: piston-bowl depth, piston-bowl opening width, piston-bowl-volume ratio, exhaust-side squish height, bowl-lip draft angle, distance between spark-plug electrode and piston-bowl lip, spark-plug-electrode length, and injector spray-cone angle. No attempt was made to optimize the gross engine parameters such as bore and stroke or the intake system, since this study focused on optimizing a reverse-tumble wall-controlled gasoline direct-injection variant of an existing port-fueled injection engine.

Superior fuel economy was achieved for a small-displacement spark-ignition direct-injection (SIDI) engine by optimizing the stratified combustion operation. The optimization was performed using computational analyses and subsequently testing the most promising configurations experimentally. The fuel economy savings are achieved by the use of a multihole injector with novel spray shape, which allows ultra-lean stratification for a wide range of part-load operating conditions without compromising smoke and hydrocarbon emissions. In this regard, a key challenge for wall-controlled SIDI engines is the minimization of wall wetting to prevent smoke, which may require advanced injection timings, while at the same time minimizing hydrocarbon emissions, which may require retarding injection and thereby preventing over-mixing of the fuel vapor.

The equipment for collecting dilute exhaust samples involves the use of bag materials (i.e., Tedlar®) that emit hydrocarbons that contaminate samples. This study identifies a list of materials and treatments to produce bags that reduce contamination. Based on the average emission rates, baked Tedlar®, Capran® treated with alumina deposition, supercritical CO2 extracted Kynar® and supercritical CO2 extracted Teflon NXT are capable of achieving the target hydrocarbon emission rate of less than 15 ppbC per 30 minutes. CO2 permeation tests were also performed. Tedlar, Capran, Kynar and Teflon NXT showed comparable average permeation rates. Based on the criteria of HC emission performance, changes in measured CO2 concentration, ease of sealing, and ease of surface treatment, none of the four materials could be distinguished from one another.

When hydrogen is added to a gasoline fueled spark ignition engine the lean limit of the engine can be extended. Lean running engines are inherently more efficient and have the potential for significantly lower NOx emissions. In the engine concept examined here, supplemental hydrogen is generated on-board the vehicle by diverting a fraction of the gasoline to a plasmatron where a partial oxidation reaction is initiated with an electrical discharge, producing a plasmatron gas containing primarily hydrogen, carbon monoxide, and nitrogen. Two different gas mixtures were used to simulate the plasmatron output. An ideal plasmatron gas (H2, CO, and N2) was used to represent the output of the theoretically best plasmatron. A typical plasmatron gas (H2, CO, N2, and CO2) was used to represent the current output of the plasmatron. A series of hydrogen addition experiments were also performed to quantify the impact of the non-hydrogen components in the plasmatron gas.

The super-ultra-low-emission-vehicle (SULEV) non-methane organic gas (NMOG) hydrocarbon exhaust standard as legislated by the state of California LEV II regulations is 10 milligrams per mile. This requires that the associative instrumentation must be capable of accurately and precisely determining total hydrocarbons (THC) concentrations on the order of 10 parts per billion-carbon (ppbC) for vehicle tests run under optimum conditions on a bag mini-diluter (BMD) test site. The flame ionization detector (FID) is the standard instrument used in the measurement of THC. Currently, there are many instrument manufacturers that produce these types of analyzers. This paper studies the limit of detection and accuracy capabilities of one of these instruments, the Beckman 400A FID. In addition, the paper shows evidence that supports that this “state of technology” as described by this instrument, is sufficient to meet the demands of the today's most stringent, vehicle emission standards.

The Automotive Industry/Government Emissions Research CRADA (AIGER) has been working to develop a new methodology for the direct determination of nonmethane hydrocarbons (DNMHC) in vehicle testing. This new measurement technique avoids the need for subtraction of a separately determined methane value from the total hydrocarbon measurement as is presently required by the Code of Federal Regulations. This paper will cover the historical aspects of the development program, which was initiated in 1993 and concluded in 2002. A fast, gas chromatographic (GC) column technology was selected and developed for the measurement of the nonmethane hydrocarbons directly, without any interference or correction being caused by the co-presence of sample methane. This new methodology chromatographically separates the methane from the nonmethane hydrocarbons, and then measures both the methane and the backflushed, total nonmethane hydrocarbons using standard flame ionization detection (FID).

Flammability tests were conducted on one control HVAC module and two experimental automotive HVAC modules containing flame retardant chemicals. The HVAC modules were exposed to a heptane pool fire. All three HVAC modules burned under these conditions. The mass loss rates of the control and experimental HVAC modules were similar. The flame retardant chemicals caused a 50% reduction in the heat produced, a 751 - 897% increase in the carbon monoxide produced, a 4,867 - 5,567% increase in the gaseous hydrocarbon produced, and a 3,875 - 4,725% increase in the smoke produced when the HVAC modules burned under these conditions. These quantitative results are consistent with visual observations made during these tests that the experimental HVAC modules produced substantially more smoke than the control HVAC module.

Copolymer materials have been used for the collection of vehicle exhaust gas samples since the inception of regulatory standards. Some of these copolymers contain N,N-dimethylacetamide (DMA), which is added to improve the physical properties of the copolymer and eliminate manufacturing problems. DMA is highly soluble in water, and in effect is rinsed from the emission bag surface by humid exhaust gas samples. This study shows that DMA can thus incorrectly add to test vehicle overall hydrocarbon emissions. The DMA contribution can be significant for lower level emission vehicles. This study introduces a new bag material, KYNAR®, which significantly reduces this interference.