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The fuel property effects on first cycle mixture preparation were assessed by measuring the in-cylinder fuel equivalence ratio (Φ) with a Fast Flame Ionization Detector (FFID) using four different fuels. The Engine Coolant Temperature (ECT) was varied between -6°C and 80°C. The Φ values increased with both ECT and amount of injected fuel mass. The delivery fraction (fraction of the injected fuel that went into the combustible charge), however, increased with ECT but decreased with increase in injected fuel. The minimum required injected mass to produce a combustible mixture increased sharply with decrease in ECT below 20°C. There was, however, no single fuel parameter that would correlate with the measurements over the entire temperature range. Instead, the minimum required injected mass correlated to different distillation points on the ASTM distillation curve; e.g. at ECT of -6°C, it correlated to T20; at 40°C, it correlated to T50.

A strategy to facilitate the mixture preparation process in PFI engines is to delay the Intake Valve Opening (IVO) by shifting the cam phasing so that the cylinder pressure is sub-atmospheric when the valve opens. The physics of the effect are discussed in terms of the pressure differential between the manifold and the cylinder, and the resulting flow and charge temperature history. The effect was evaluated by measuring the equivalence ratio of the trapped charge and the exhaust HC emissions in the first cycle of cranking in a 2.4L engine. When the IVO timing was changed from 18° BTDC to 21° ATDC, the in-cylinder fuel equivalence ratio increased by approximately 10%. This increase was attributed mainly to the enrichment of the charge by displacing the leaner mixture at the top of the cylinder in the period between BDC and IVC. The exhaust HC, however, increased by 40%. No conclusive explanation was established for this increase in HC emissions.

The effects of highly heated fuel on diesel combustion were studied experimentally in a rapid compression machine. A pure fuel, dodecane, heated up to and beyond its critical temperature, was injected into a diesel combustion chamber with the air charge at a compression ratio of 18.2 to 1. The ignition delay was found to decrease with the increase of fuel temperature. The delay decreased to almost zero (within the limit of the accuracy of the instrumentation) at fuel temperatures above 600K. This decrease of delay was explained in terms of a thermal ignition model. For the short ignition delay combustions, the premixed burning phase could not be detected from the heat release data. The mixing controlled burning phases of the heated and unheated fuels however, were not much different; in particular, there was no rapid mixing phenomenon when the fuel temperature was above critical.