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Pouch cells are increasingly popular form factors for the construction of energy storage systems in electric vehicles of all classes. Knowledge of the stress generated by these higher capacity pouch cells is critical to properly design battery modules and packs for both normal and abnormal operation. Existing literature predominantly offers data on smaller pouch cells with capacities of less than 10 Ah, leaving a gap in our understanding of the behavior of these larger cells. This experimental study aimed to bridge this knowledge gap by measuring loads and stresses in constrained 65 Ah pouch cells under both cycling and abuse conditions. To capture the desired responses, a load cell was located within a robust fixture to measure cell stress in real time after the application of a preload of approximately 30 kilograms or 294 N, equivalent to a pressure of 0.063 bar, with a fixed displacement.

The widely accepted best practice for spark-ignition combustion is the four-valve pent-roof chamber using a central sparkplug and incorporating tumble flow during the intake event. The bulk tumble flow readily breaks up during the compression stroke to fine-scale turbulent kinetic energy desired for rapid, robust combustion. The natural gas engines used in medium- and heavy-truck applications would benefit from a similar, high-tumble pent-roof combustion chamber. However, these engines are invariably derived from their higher-volume diesel counterparts, and the production volumes are insufficient to justify the amount of modification required to incorporate a pent-roof system. The objective of this multi-dimensional computational study was to develop a combustion chamber addressing the objectives of a pent-roof chamber while maintaining the flat firedeck and vertical valve orientation of the diesel engine.

According to the Annual Energy Outlook 2022 (AEO2022) report, almost 30% of the transport sector will still use internal combustion engines (ICE) until 2050. The transportation sector has been actively seeking different methods to reduce the CO2 emissions footprint of fossil fuels. The use of lower carbon-intensity fuels such as Renewable Diesel (RD) can enable a pathway to decarbonize the transport industry. This suggests the need for experimental or advanced numerical studies of RD to gain an understanding of its combustion and emissions performance. This work presents a numerical modeling approach to study the combustion and emissions of RD. The numerical model utilized the development of a reduced chemical kinetic mechanism for RD’s fuel chemistry. The final reduced mechanism for RD consists of 139 species and 721 reactions, which significantly shortened the computational time from using the detailed mechanism.

Conventional diesel combustion (CDC) is known to provide high efficiency and reliable engine performance, but often associated with high particulate matter (PM) and nitrogen oxides (NOX) emissions. Combustion of fossil diesel fuel also produces carbon dioxide (CO2), which acts as a harmful greenhouse gas (GHG). Renewable and low-carbon fuels such as renewable diesel (RD) and methanol can play an important role in reducing harmful criteria and CO2 emissions into the atmosphere. This paper details an experimental study using a single-cylinder research engine operated under dual-fuel combustion using methanol and RD. Various engine operating strategies were used to achieve diesel-like fuel efficiency. Measurements of engine-out emissions and in-cylinder pressure were taken at test conditions including low-load and high-load operating points.

Upcoming regulations from CARB and EPA will require diesel engine manufacturers to validate aftertreatment durability with full useful life aged components. To this end, the Diesel Aftertreatment Accelerated Aging Cycle (DAAAC) protocol was developed to accelerate aftertreatment aging by accounting for hydrothermal aging, sulfur, and oil poisoning deterioration mechanisms. Two aftertreatment systems aged with the DAAAC protocol, one on an engine and the other on a burner system, were directly compared to a reference system that was aged to full useful life using conventional service accumulation. After on-engine emission testing of the fully aged components, DOC and SCR catalyst samples were extracted from the aftertreatment systems to compare the elemental distribution of contaminants between systems. In addition, benchtop reactor testing was conducted to measure differences in catalyst performance.

Alternative fuels such as methanol can significantly reduce greenhouse gas (GHG) emissions when used in internal combustion engines (ICEs). This study characterized the combustion of methanol, methanol/diesel, and methanol/renewable diesel numerically. Numerical findings were also compared with engine experiments using a single-cylinder engine (SCE). The engine was operated under a dual-fuel combustion mode: methanol was fumigated at the intake port, and diesel was injected inside the cylinder. The characteristic of ignition delay trend as methanol concentration increased is being described at low temperature (low engine load) and high temperature (high engine load) conditions.

Dedicated-EGR™ (D-EGR™) is a concept where the exhaust of one dedicated cylinder (D-Cyl) is routed into the intake thus producing EGR to be used by the whole engine. The D-Cyl operates rich of stochiometric which produces syngas that enhances the EGR stream permitting faster combustion and greater knock mitigation. Operating an engine using D-EGR improves the knock resistance which can permit a higher compression ratio (CR) thereby increasing efficiency. One challenge of traditional D-EGR is that the D-Cyl combustion becomes unstable operating with both rich and EGR dilute conditions. Therefore, the ‘Split Intake D-EGR’ concept seeks to resolve this problem by feeding fresh air to the D-Cyl, thus allowing even richer operation in the D-Cyl which further increases the H2 and CO yield thereby enhancing the efficiency benefits.

As an alternative fuel, renewable diesel (RD) could improve the performance of conventional internal combustion engines (ICE) because of its difference in fuel properties. With almost no aromatic content in the fuel, RD produces less soot emissions than diesel. The higher cetane number (CN) of RD also promotes ignition of the fuel, which is critical, especially under low load, and low reactivity conditions. This study tested RD fuel in a heavy-duty single-cylinder engine (SCE) under compression-ignition (CI) operation. Test condition includes low and high load points with change in exhaust gas recirculation (EGR) and start of injection (SOI). Measurements and analysis are provided to study combustion and emissions, including particulate matters (PM) mass and particle number (PN). It was found that while the combustion of RD and diesel are very similar, PM and PN emissions of RD were reduced substantially compared to diesel.

A physics-based spark ignition model was developed and integrated into a commercial CFD code. The model predicted the spark discharge process based on the electrical parameters of the secondary ignition circuit, tracked the spark motion as it was stretched by in-cylinder gas motion, and determined the resulting energy deposition to the gas. In concert with the existing kinetic solver in the CFD code, the resulting ignition and flame propagation processes were simulated. The model results have been validated against both imaging rig experiments of the spark in moving air and against engine experimental data. The model was able to replicate the key features of the spark and to capture the cyclic variability of high-dilution combustion when multiple engine cycles were simulated.

In 2020, CARB adopted the low NOX omnibus ruling, which provided revisions to on-road heavy duty engine compliance standards and certification practices. As part of the updates to the regulation, CARB has introduced a new in-use vehicle testing process that broadens the operation modes tested and considers the manufacturer’s intended vehicle application. Compared to the previous method, or the Not-to-Exceed approach, cold start and low ambient temperature provisions were included as part of the updates. The inclusion of low temperature operation requires the OEMs to design a robust engine and aftertreatment package that extends NOX conversion performance. The following work discusses the NOX emissions performance impact in a low temperature ambient environment. The engine and aftertreatment system evaluated was designed to comply with CARB’s low NOX regulations. The cycles tested included the CARB Southern NTE cycle and an FTP-LLC protocol.

Stringent emissions regulations and the need for lower tailpipe emissions are pushing the development of low-carbon alternative fuels. H2 is a zero-carbon fuel that has the potential to lower CO2 emissions from internal combustion engines (ICEs) significantly. Moreover, this fuel can be readily implemented in ICEs with minor modifications. Batteries can be argued to be a good zero tailpipe emission solution for the light-duty sector; however, medium and heavy-duty sectors are also in need of rapid decarbonization. Current strategies for H2 ICEs include modification of the existing spark ignition (SI) engines to run on port fuel injection (PFI) systems with minimal changes from the current compressed natural gas (CNG) engines. This H2 ICE strategy is limited by knock and pre-ignition. One solution is to run very lean (lambda >2), but this results in excessive boosting requirements and may result in high NOx under transient conditions.

The automotive sector is rapidly transitioning to decarbonized, electric vehicles solutions. However, due to challenges with such rapid adoption, Internal combustion engines (ICE) are expected to be used for decades to come. In this transition period it is important to continue to improve ICE efficiency. A key design parameter to increase ICE efficiency is the compression ratio. For gasoline engines, the compression ratio is limited so as to avoid knock. Engine designers can employ several strategies to mitigate knock and enable higher compression ratios. In this study, a new methodology has been developed to compare various knock mitigation strategies. By comparing the knock limited load at a given combustion phasing the expected compression ratio increase can be inferred.

Interaction between a diesel spray and piston plays a significant role in overall combustion and emissions performance in compression-ignition engines. It is essential to design the lip feature respective to spray targeting and the following charge motion for combustion systems that rely on spray-piston interaction strongly, such as a stepped-lip piston. This study used a numerical campaign using computational fluid dynamics (CFD) simulation to optimize a stepped-lip combustion system at a 22:1 compression ratio (CR) for both performance and emissions. This is a substantial step up in CR from the stock value of 17:1 for the same engine platform. A machine learning model was used to identify the best combination of features from a design space involving hundreds of potential piston designs and injector nozzle configurations. This study provides a discussion on the general combustion characteristics of the stepped-lip combustion system and the sensitivity of the design parameters.

Aftertreatment durability demonstration is a required validation exercise for on-road medium and heavy-duty diesel engine certification. The demonstration is meant to validate emissions compliance for the engine and aftertreatment system at full useful life or FUL. Current certification practices allow engine manufacturers to complete partial aging and then extrapolate emissions performance results to FUL. While this process reduces the amount of service accumulation time, it does not consider changes in the aftertreatment deterioration rate. Rather, deterioration is assumed to occur at a linear rate, which may lead to false conclusions relating to emissions compliance. With CARB and EPA’s commitment to the reduction of criteria emissions, emphasis has also been placed on revising the existing certification practices. The updated practices would require engine manufacturers to certify with an aftertreatment system aged to FUL.

Heavy-duty (HD) internal combustion engines (ICE) have achieved quite high brake thermal efficiencies (BTE) in recent years. However, worldwide GHG regulations have increased the pace towards zero CO2 emissions. This, in conjunction with the ICE reaching near theoretical efficiencies means there is a fundamental lower limit to the GHG emissions from a conventional diesel engine. A large factor in achieving lower GHG emissions for a given BTE is the fuel, in particular its hydrogen to carbon ratio. Substituting a fuel like diesel with compressed natural gas (CNG) can provide up to 25% lower GHG at the same BTE with a sufficiently high substitution rate. However, any CNG slip through the combustion system is penalized heavily due to its large global warming potential compared to CO2. Therefore, new technologies are needed to reduce combustion losses in CNG-diesel dual fuel engines.

Southwest Research Institute (SwRI) utilizes the burner-based Exhaust Composition Transient Operation LaboratoryTM (ECTO-Lab) to accurately simulate transient engines and replicate real exhaust that is produced by light and heavy-duty engines for aftertreatment aging and evaluations. This system can generate and dose NOX over transient cycles from a range of 20 ppm to 1200 ppm where the NOX is generated by the in-situ decomposition and combustion of a fuel-bound, nitrogen containing compound. During the combustion and decomposition of the nitrogen containing compound over 95 % of the NOX generated is in the form of NO. To authentically simulate exhaust gases, it is necessary to account for the distribution of the NO to the NO2. Since previous work has established that the decomposition of nitric acid can be utilized as a method to generate NO2, the objective of this project was to develop control of NO and NO2 within SwRI’s ECTO-Lab through the decomposition of nitric acid.

Advanced diesel combustion systems continue to push the peak cylinder pressure limit of engines upward to allow high-efficiency combustion with high compression ratios (CR). The air-standard Otto and Diesel cycles indicate increased compression ratios lead to higher cycle efficiency. The study presented here describes the development and demonstration of a high-efficiency diesel combustion system. The study used both computational and experimental tools to develop the combustion system fully. Computational fluid dynamics (CFD) simulations were carried out to evaluate combustion with two combustion systems at a compression ratio of 22:1 with a Wave piston design (based on the production Volvo Wave piston). Analysis of combustion performance and emissions were performed to confirm the improvements these piston designs offered relative to the baseline combustion system for the engine. Companion single-cylinder engine (SCE) experiments were performed to validate the simulation results.

Simulating high amounts of exhaust gas recirculation in spark ignited engines to predict combustion using the currently available CFD modeling approaches is a challenge and does not always give reasonable matches with experimental observations. One of the reasons for the mismatch lies with the secondary circuit treatment of the ignition coil and the resulting energy deposition or a complete lack of it thereof. An ignition modeling approach is developed in this work which predicts the energy transfer from the electrical circuit to the gases in the combustion chamber leading to flame kernel growth under high EGR and high gas flow velocity conditions. Secondary circuit sub-model includes secondary side of the coil, spark plug and spark gap. The sub-model calculates the delivered energy to the gas based on given circuit properties and total initial electrical energy.

Water injection is an effective method for knock control in spark-ignition engines. However, the requirement of a separate water source and the cost and complexity associated with a fully integrated system creates a limitation of this method to be used in volume production engines. The engine exhaust typically contains 10-15% water vapor by volume which could be condensed and potentially stored for future use. In this study, the exhaust condensate composition was assessed for its use as an effective replacement for distilled water. Specifically, condensate samples were collected pre and post-three-way catalyst (TWC) and analyzed for acidity and composition. The composition of the pre and post-TWC condensates was found to be similar however, the pre-TWC condensate was mildly acidic. The mild acidity has the potential to corrode certain components in the intake air circuit.

The dedicated exhaust gas recirculation (D-EGR®) concept developed by Southwest Research Institute (SwRI) has demonstrated a thermal efficiency increase on several spark-ignited engines at both low and high-load conditions. Syngas (H2+CO) is produced by the dedicated cylinder (D-cyl) which operates at a rich air-fuel ratio. The syngas helps to stabilize combustion under highly dilute conditions at low loads as well as mitigating knock at high loads. The D-cyl produces all the EGR for the engine at a fixed rate of approximately 25% EGR for a four-cylinder engine and 33% EGR for a six-cylinder engine. The D-cyl typically runs up to an equivalence ratio of 1.4 for gasoline-fueled engines, beyond which the combustion becomes unstable due to the decreasing laminar burning velocity caused by rich conditions. Conventional active-fueled and passive pre-chambers have benefits of inducing multi-site ignition and enhancing turbulence in the main chamber.