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Technical Paper

Semi-Volatile Organic Compounds from a Combined Dual Port Injection/Direct-Injection Technology Light-Duty Gasoline Vehicle

2019-09-09
2019-24-0051
Gasoline direct injection (GDI) has changed the exhaust composition in comparison with the older port fuel injection (PFI) systems. More recently, light-duty vehicle engine manufactures have combined these two technologies to take advantage of the knock benefits and fuel economy of GDI with the low particulate emission of PFI. These dual injection strategy engines have made a change in the combustion emission composition produced by these engines. Understanding the impact of these changes is essential for automotive companies and aftertreatment developers. A novel sampling system was designed to sample the exhaust generated by a dual injection strategy gasoline vehicle using the United States Federal Test Procedure (FTP). This sampling system was capable of measuring the regulated emissions as well as collecting the entire exhaust from the vehicle for measuring unregulated emissions.
Technical Paper

Polycyclic Aromatic Hydrocarbons in Diesel Engine Exhaust Both with and without Aftertreatment

2018-09-10
2018-01-1812
Since the conception of the internal combustion engine, smoky and ill-smelling exhaust was prevalent. Over the last century, significant improvements have been made in improving combustion and in treating the exhaust to reduce these effects. One group of compounds typically found in exhaust, polycyclic aromatic hydrocarbons (PAH), usually occurs at very low concentrations in diesel engine exhaust. Some of these compounds are considered carcinogenic, and most are considered hazardous air pollutants (HAP). Many methods have been developed for sampling, handling, and analyzing PAH. For this study, an improved method for dilute exhaust sampling was selected for sampling the PAH in diesel engine exhaust. This sampling method was used during transient engine operation both with and without aftertreatment to show the effect of aftertreatment.
Technical Paper

Effect of Lubricant Oil on Particle Emissions from a Gasoline Direct Injection Light-Duty Vehicle

2018-09-10
2018-01-1708
Gasoline direction injection (GDI) engines have been widely used by light-duty vehicle manufacturers in recent years to meet stringent fuel economy and emissions standards. Particulate Matter (PM) mass emissions from current GDI engines are primarily composed of soot particles or black carbon with a small fraction (15% to 20%) of semi-volatile hydrocarbons generated from unburned/partially burned fuel and lubricating oil. Between 2017 and 2025, PM mass emissions regulations in the USA are expected to become progressively more stringent going down from current level of 6 mg/mile to 1 mg/mile in 2025. As PM emissions are reduced through soot reduction, lubricating oil derived semi-volatile PM is expected to become a bigger fraction of total PM mass emissions.
Technical Paper

On-Road Monitoring of Low Speed Pre-Ignition

2018-09-10
2018-01-1676
To meet increasingly stringent emissions and fuel economy regulations, many Original Equipment Manufacturers (OEMs) have recently developed and deployed small, high power density engines. Turbocharging, coupled with gasoline direct injection (GDI) has enabled a rapid engine downsizing trend. While these turbocharged GDI (TGDI) engines have indeed allowed for better fuel economy in many light duty vehicles, TGDI technology has also led to some unintended consequences. The most notable of these is an abnormal combustion phenomenon known as low speed pre-ignition (LSPI). LSPI is an uncontrolled combustion event that takes place prior to spark ignition, often resulting in knock, and has been known to cause catastrophic engine damage. LSPI propensity depends on a number of factors including engine design, calibration, fuel properties and engine oil formulation. Several engine tests have been developed within the industry to better understand the phenomenon of LSPI.
Technical Paper

Achieving Fast Catalyst Light-Off from a Heavy-Duty Stoichiometric Natural Gas Engine Capable of 0.02 g/bhp-hr NOX Emissions

2018-04-03
2018-01-1136
Recently conducted work has been funded by the California Air Resources Board (CARB) to explore the feasibility of achieving 0.02 g/bhp-hr NOX emissions for heavy-duty on-road engines. In addition to NOX emissions, greenhouse gas (GHG), CO2 and methane emissions regulations from heavy-duty engines are also becoming more stringent. To achieve low cold-start NOX and methane emissions, the exhaust aftertreatment must be brought up to temperature quickly while keeping proper air-fuel ratio control; however, a balance between catalyst light-off and fuel penalty must be addressed to meet future CO2 emissions regulations. This paper details the work executed to improve catalyst light-off for a natural gas engine with a close-coupled and an underfloor three-way-catalyst while meeting an FTP NOX emission target of 0.02 g/bhp-hr and minimizing any fuel penalty.
Technical Paper

Solid Particle Number and Ash Emissions from Heavy-Duty Natural Gas and Diesel w/SCRF Engines

2018-04-03
2018-01-0362
Solid and metallic ash particle number (PN) and particulate matter (PM) mass emission measurements were performed on a heavy-duty (HD) on-highway diesel engine and a compressed natural gas (CNG) engine. Measurements were conducted under transient engine operation that included the FTP, WHTC and RMC. Both engines were calibrated to meet CARB ultra low NOX emission target of 0.02 g/hp-hr, a 90% reduction from current emissions limit. The HD diesel engine final exhaust configuration included a number of aftertreatement sub-systems in addition to a selective catalytic reduction filter (SCRF). The stoichiometric CNG engine final configuration included a closed coupled Three Way Catalyst (ccTWC) and an under floor TWC (ufTWC). The aftertreatment systems for both engines were aged for a full useful life (FUL) of 435,000 miles, prior to emissions testing. PM mass emissions from both engines were comparable and well below the US EPA emissions standard.
Technical Paper

Cold Start HD FTP Test Results on Multi-Cylinder Opposed-Piston Engine Demonstrating Rapid Exhaust Enthalpy Rise to Achieve Ultra Low NOx

2018-04-03
2018-01-1378
The 2010 emission standards for heavy-duty diesel engines in the U.S. have established a limit for oxides of nitrogen (NOx) emissions of 0.20 g/bhp-hr., a 90% reduction from the previous emission standards. However, it has been projected that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with the 2010 emission standards, the upcoming National Ambient Air Quality Standards (NAAQS) requirement for ambient particulate matter and ozone will not be achieved in California without further significant reductions in NOx emissions from the heavy-duty vehicle fleet. Given this, there is potential of further reduction in NOx emissions limit standards for heavy duty engines in the US. Recently there have been extensive studies and publications focusing on ultra-low NOx after treatment technologies that help achieve up to 0.02g/bhp-hr. at tailpipe [1].
Technical Paper

Estimation of Intake Oxygen Mass Fraction for Transient Control of EGR Engines

2018-04-03
2018-01-0868
Cooled Exhaust Gas Recirculation (EGR) technology provides significant benefits such as better cycle efficiency, knock tolerance and lower NOx/PM emissions. However, EGR dilution also poses challenges in terms of combustion stability, power density and control. Conventional control schemes for EGR engines rely on a differential pressure sensor combined with an orifice flow model to estimate EGR flow rate. While EGR rate is an important quantity, intake O2 mass fraction may be a better indication of EGR, capturing quantity as well as “quality” of EGR. SwRI has successfully used intake O2 mass fraction as a controlled state to manage several types of EGR engines - dual loop EGR diesel engines, low pressure loop /dedicated EGR (D-EGR) gasoline engines as well as dual fuel engines. Several suppliers are currently developing intake O2 sensors but they typically suffer from limited accuracy, response time and reliability. Also, addition of a new sensor implies increased production costs.
Technical Paper

Achieving 0.02 g/bhp-hr NOx Emissions from a Heavy-Duty Stoichiometric Natural Gas Engine Equipped with Three-Way Catalyst

2017-03-28
2017-01-0957
It is projected that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with 2010 emission standards of 0.20 g/bhp-hr, the National Ambient Air Quality Standards (NAAQS) requirements for ambient ozone will not be met. It is expected that further reductions in NOX emissions from the heavy-duty fleet will be required to achieve compliance with the ambient ozone requirement. To study the feasibility of further reductions, the California Air Resources Board (CARB) funded a research program to demonstrate the potential to reach 0.02 g/bhp-hr NOX emissions. This paper details the work executed to achieve this goal on the heavy-duty Federal Test Procedure (FTP) with a heavy-duty natural gas engine equipped with a three-way catalyst. A Cummins ISX-12G natural gas engine was modified and coupled with an advanced catalyst system.
Journal Article

Achieving Ultra Low NOX Emissions Levels with a 2017 Heavy-Duty On-Highway TC Diesel Engine and an Advanced Technology Emissions System - Thermal Management Strategies

2017-03-28
2017-01-0954
The most recent 2010 emissions standards for heavy-duty engines have established a tailpipe limit of oxides of nitrogen (NOX) emissions of 0.20 g/bhp-hr. However, it is projected that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with 2010 emission standards, the National Ambient Air Quality Standards (NAAQS) requirement for ambient particulate matter and Ozone will not be achieved without further reduction in NOX emissions. The California Air Resources Board (CARB) funded a research program to explore the feasibility of achieving 0.02 g/bhp-hr NOX emissions.
Journal Article

Achieving Ultra Low NOX Emissions Levels with a 2017 Heavy-Duty On-Highway TC Diesel Engine - Comparison of Advanced Technology Approaches

2017-03-28
2017-01-0956
The 2010 emissions standards for heavy-duty engines have established a limit of oxides of nitrogen (NOX) emissions of 0.20 g/bhp-hr. However, the California Air Resource Board (ARB) projects that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with 2010 emission standards, the National Ambient Air Quality Standards (NAAQS) requirement for ambient particulate matter (PM) and Ozone will not be achieved without further reduction in NOX emissions. The California Air Resources Board (CARB) funded a research program to explore the feasibility of achieving 0.02 g/bhp-hr NOX emissions.
Journal Article

Achieving Ultra Low NOX Emissions Levels with a 2017 Heavy-Duty On-Highway TC Diesel Engine and an Advanced Technology Emissions System - NOX Management Strategies

2017-03-28
2017-01-0958
Recent 2010 emissions standards for heavy-duty engines have established a limit of oxides of nitrogen (NOX) emissions of 0.20 g/bhp-hr. However, CARB has projected that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with 2010 emission standards, the National Ambient Air Quality Standards (NAAQS) requirement for ambient particulate matter and Ozone will not be achieved without further reduction in NOX emissions. The California Air Resources Board (ARB) funded a research program to explore the feasibility of achieving 0.02 g/bhp-hr NOX emissions. This paper details engine and aftertreatment NOX management requirements and model based control considerations for achieving Ultra-Low NOX (ULN) levels with a heavy-duty diesel engine. Data are presented for several Advanced Technology aftertreatment solutions and the integration of these solutions with the engine calibration.
Journal Article

Design and Implementation of a D-EGR® Mixer for Improved Dilution and Reformate Distribution

2017-03-28
2017-01-0647
The Dedicated EGR (D-EGR®) engine has shown improved efficiency and emissions while minimizing the challenges of traditional cooled EGR. The concept combines the benefits of cooled EGR with additional improvements resulting from in-cylinder fuel reformation. The fuel reformation takes place in the dedicated cylinder, which is also responsible for producing the diluents for the engine (EGR). The D-EGR system does present its own set of challenges. Because only one out of four cylinders is providing all of the dilution and reformate for the engine, there are three “missing” EGR pulses and problems with EGR distribution to all 4 cylinders exist. In testing, distribution problems were realized which led to poor engine operation. To address these spatial and temporal mixing challenges, a distribution mixer was developed and tested which improved cylinder-to-cylinder and cycle-to-cycle variation of EGR rate through improved EGR distribution.
Journal Article

Extension of Analytical Methods for Detailed Characterization of Advanced Combustion Engine Emissions

2016-10-17
2016-01-2330
Advanced combustion strategies used to improve efficiency, emissions, and performance in internal combustion engines (IC) alter the chemical composition of engine-out emissions. The characterization of exhaust chemistry from advanced IC engines requires an analytical system capable of measuring a wide range of compounds. For many years, the widely accepted Coordinating Research Council (CRC) Auto/Oil procedure[1,2] has been used to quantify hydrocarbon compounds between C1 and C12 from dilute engine exhaust in Tedlar polyvinyl fluoride (PVF) bags. Hydrocarbons greater than C12+ present the greatest challenge for identification in diesel exhaust. Above C12, PVF bags risk losing the higher molecular weight compounds due to adsorption to the walls of the bag or by condensation of the heavier compounds. This paper describes two specialized exhaust gas sampling and analytical systems capable of analyzing the mid-range (C10 - C24) and the high range (C24+) hydrocarbon in exhaust.
Journal Article

Automated Driving Impediments

2016-09-27
2016-01-8007
Since the turn of the millennium, automated vehicle technology has matured at an exponential rate, evolving from research largely funded and motivated by military and agricultural needs to a near-production market focused on everyday driving on public roads. Research and development has been conducted by a variety of entities ranging from universities to automotive manufacturers to technology firms demonstrating capabilities in both highway and urban environments. While this technology continues to show promise, corner cases, or situations outside the average driving environment, have emerged highlighting scenarios that impede the realization of full automation anywhere, anytime. This paper will review several of these corner cases and research deficiencies that need to be addressed for automated driving systems to be broadly deployed and trusted.
Technical Paper

Evaluation of Cold Start Technologies on a 3L Diesel Engine

2016-04-05
2016-01-0823
Increasingly stringent emissions regulations require that modern diesel aftertreatment systems must warm up and begin controlling emissions shortly after startup. While several new aftertreatment technologies have been introduced that focus on lowering the aftertreatment activation temperature, the engine system still needs to provide thermal energy to the exhaust for cold start. A study was conducted to evaluate several engine technologies that focus on improving the thermal energy that the engine system provides to the aftertreatment system while minimizing the impact on fuel economy and emissions. Studies were conducted on a modern common rail 3L diesel engine with a custom dual loop EGR system. The engine was calibrated for low engine-out NOx using various combustion strategies depending on the speed/load operating condition.
Technical Paper

Comparison of Hydrocarbon Measurement with FTIR and FID in a Dual Fuel Locomotive Engine

2016-04-05
2016-01-0978
Exhaust emissions of non-methane hydrocarbon (NMHC) and methane were measured from a Tier 3 dual-fuel demonstration locomotive running diesel-natural gas blend. Measurements were performed with the typical flame ionization detector (FID) method in accordance with EPA CFR Title 40 Part 1065 and with an alternative Fourier-Transform Infrared (FTIR) Spectroscopy method. Measurements were performed with and without oxidation catalyst exhaust aftertreatment. FTIR may have potential for improved accuracy over the FID when NMHC is dominated by light hydrocarbons. In the dual fuel tests, the FTIR measurement was 1-4% higher than the FID measurement of. NMHC results between the two methods differed considerably, in some cases reporting concentrations as much as four times those of the FID. However, in comparing these data it is important to note that the FTIR method has several advantages over the FID method, so the differences do not necessarily represent error in the FTIR.
Technical Paper

Investigation of Urea Derived Deposits Composition in SCR Systems and Their Potential Effect on Overall PM Emissions

2016-04-05
2016-01-0989
Ideally, complete thermal decomposition of urea should produce only two products in active Selective Catalytic Reduction (SCR) systems: ammonia and carbon dioxide. In reality, urea thermal decomposition reaction includes the formation of isocyanic acid as an intermediate product. Being highly reactive, isocyanic acid can initiate the formation of larger molecular weight compounds such as cyanuric acid, biuret, melamine, ammeline, ammelide, and dicyandimide [1,2,3,4]. These compounds can be responsible for the formation of deposits on the walls of the decomposition reactor in urea SCR systems. Composition of these deposits varies with temperature exposure, and under certain conditions, can create oligomers such as melam, melem, and melon [5, 6] that are difficult to remove from exhaust systems. Deposits can affect the efficiency of the urea decomposition, and if large enough, can inhibit the exhaust flow.
Technical Paper

Demonstration of a Novel, Off Road, Diesel Combustion Concept

2016-04-05
2016-01-0728
There are numerous off-road diesel engine applications. In some applications there is more focus on metrics such as initial cost, packaging and transient response and less emphasis on fuel economy. In this paper a combustion concept is presented that may be well suited to these applications. The novel combustion concept operates in two distinct operation modes: lean operation at light engine loads and stoichiometric operation at intermediate and high engine loads. One advantage to the two mode approach is the ability to simplify the aftertreatment and reduce cost. The simplified aftertreatment system utilizes a non-catalyzed diesel particulate filter (DPF) and a relatively small lean NOx trap (LNT). Under stoichiometric operation the LNT has the ability to act as a three way catalyst (TWC) for excellent control of hydrocarbons (HC), carbon monoxide (CO) and nitrogen oxides (NOx).
Technical Paper

Detailed Characterization of Criteria Pollutant Emissions from D-EGR® Light Duty Vehicle

2016-04-05
2016-01-1006
In this study, the criteria pollutant emissions from a light duty vehicle equipped with Dedicated EGR® technology were compared with emissions from an identical production GDI vehicle without externally cooled EGR. In addition to the comparison of criteria pollutant mass emissions, an analysis of the gaseous and particulate chemistry was conducted to understand how the change in combustion system affects the optimal aftertreatment control system. Hydrocarbon emissions from the vehicle were analyzed usin g a variety of methods to quantify over 200 compounds ranging in HC chain length from C1 to C12. The particulate emissions were also characterized to quantify particulate mass and number. Gaseous and particulate emissions were sampled and analyzed from both vehicles operating on the FTP-75, HWFET, US06, and WLTP drive cycles at the engine outlet location.
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