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Technical Paper

Stress Generation in Large Pouch Cells Under Cycling and Abuse Conditions

2024-04-09
2024-01-2196
Pouch cells are increasingly popular form factors for the construction of energy storage systems in electric vehicles of all classes. Knowledge of the stress generated by these higher capacity pouch cells is critical to properly design battery modules and packs for both normal and abnormal operation. Existing literature predominantly offers data on smaller pouch cells with capacities of less than 10 Ah, leaving a gap in our understanding of the behavior of these larger cells. This experimental study aimed to bridge this knowledge gap by measuring loads and stresses in constrained 65 Ah pouch cells under both cycling and abuse conditions. To capture the desired responses, a load cell was located within a robust fixture to measure cell stress in real time after the application of a preload of approximately 30 kilograms or 294 N, equivalent to a pressure of 0.063 bar, with a fixed displacement.
Technical Paper

Post-Mortem Analysis of DAAAC and Conventionally Aged Aftertreatment Systems

2023-10-31
2023-01-1656
Upcoming regulations from CARB and EPA will require diesel engine manufacturers to validate aftertreatment durability with full useful life aged components. To this end, the Diesel Aftertreatment Accelerated Aging Cycle (DAAAC) protocol was developed to accelerate aftertreatment aging by accounting for hydrothermal aging, sulfur, and oil poisoning deterioration mechanisms. Two aftertreatment systems aged with the DAAAC protocol, one on an engine and the other on a burner system, were directly compared to a reference system that was aged to full useful life using conventional service accumulation. After on-engine emission testing of the fully aged components, DOC and SCR catalyst samples were extracted from the aftertreatment systems to compare the elemental distribution of contaminants between systems. In addition, benchtop reactor testing was conducted to measure differences in catalyst performance.
Technical Paper

Numerical Study of Dual Fuel Methanol/Diesel Combustion under Engine-like Condition

2023-09-29
2023-32-0121
Alternative fuels such as methanol can significantly reduce greenhouse gas (GHG) emissions when used in internal combustion engines (ICEs). This study characterized the combustion of methanol, methanol/diesel, and methanol/renewable diesel numerically. Numerical findings were also compared with engine experiments using a single-cylinder engine (SCE). The engine was operated under a dual-fuel combustion mode: methanol was fumigated at the intake port, and diesel was injected inside the cylinder. The characteristic of ignition delay trend as methanol concentration increased is being described at low temperature (low engine load) and high temperature (high engine load) conditions.
Journal Article

Low Ambient Temperature Impact on a Low NOX Demonstration System

2023-04-11
2023-01-0361
In 2020, CARB adopted the low NOX omnibus ruling, which provided revisions to on-road heavy duty engine compliance standards and certification practices. As part of the updates to the regulation, CARB has introduced a new in-use vehicle testing process that broadens the operation modes tested and considers the manufacturer’s intended vehicle application. Compared to the previous method, or the Not-to-Exceed approach, cold start and low ambient temperature provisions were included as part of the updates. The inclusion of low temperature operation requires the OEMs to design a robust engine and aftertreatment package that extends NOX conversion performance. The following work discusses the NOX emissions performance impact in a low temperature ambient environment. The engine and aftertreatment system evaluated was designed to comply with CARB’s low NOX regulations. The cycles tested included the CARB Southern NTE cycle and an FTP-LLC protocol.
Technical Paper

DAAAC Protocol for Durability Demonstration of Diesel Aftertreatment Systems: Emissions Performance Validation

2022-08-30
2022-01-1015
Aftertreatment durability demonstration is a required validation exercise for on-road medium and heavy-duty diesel engine certification. The demonstration is meant to validate emissions compliance for the engine and aftertreatment system at full useful life or FUL. Current certification practices allow engine manufacturers to complete partial aging and then extrapolate emissions performance results to FUL. While this process reduces the amount of service accumulation time, it does not consider changes in the aftertreatment deterioration rate. Rather, deterioration is assumed to occur at a linear rate, which may lead to false conclusions relating to emissions compliance. With CARB and EPA’s commitment to the reduction of criteria emissions, emphasis has also been placed on revising the existing certification practices. The updated practices would require engine manufacturers to certify with an aftertreatment system aged to FUL.
Journal Article

Development of Steady State NO2:NOX Control via an Independent Nitric Decomposition System for the Exhaust Composition Transient Operation Laboratory

2022-03-29
2022-01-0548
Southwest Research Institute (SwRI) utilizes the burner-based Exhaust Composition Transient Operation LaboratoryTM (ECTO-Lab) to accurately simulate transient engines and replicate real exhaust that is produced by light and heavy-duty engines for aftertreatment aging and evaluations. This system can generate and dose NOX over transient cycles from a range of 20 ppm to 1200 ppm where the NOX is generated by the in-situ decomposition and combustion of a fuel-bound, nitrogen containing compound. During the combustion and decomposition of the nitrogen containing compound over 95 % of the NOX generated is in the form of NO. To authentically simulate exhaust gases, it is necessary to account for the distribution of the NO to the NO2. Since previous work has established that the decomposition of nitric acid can be utilized as a method to generate NO2, the objective of this project was to develop control of NO and NO2 within SwRI’s ECTO-Lab through the decomposition of nitric acid.
Journal Article

A Comparative Study of Lithium-Ion Cathode Chemistry Correlations with Emissions Initiated by Nail Penetration Abuse in the Presence of an Immersive Coolant

2022-03-29
2022-01-0707
Internal short-circuit in cells/batteries is a phenomenon where there is direct electrical contact between the positive and negative electrodes leading to thermal runaway. The nail penetration tests were used to simulate an internal short circuit within the battery, where a conductive nail was used to pierce the battery cell separator membrane which provided direct electrical contact between the positive and negative electrodes. The batteries tested during this work were common batteries used in existing automotive applications, and they included a nickel manganese cobalt (NMC) battery from a Chevrolet Bolt, a lithium manganese oxide (LMO) battery from a Chevrolet Volt, and a lithium iron phosphate (LFP) battery in a hybrid transit bus. The battery abuse and emissions tests were designed to intentionally drive the three different battery chemistries into thermal runaway while measuring battery temperatures, battery voltages and gaseous emissions.
Journal Article

A Comparative Study of Lithium-Ion Cathode Chemistry Correlations with Emissions Initiated by Nail Penetration Abuse in the Presence of an Immersive Coolant

2022-03-29
2022-01-0715
Internal short-circuit in cells/batteries is a phenomenon where there is direct electrical contact between the positive and negative electrodes leading to thermal runaway. The nail penetration tests were used to simulate an internal short circuit within the battery, where a conductive nail was used to pierce the battery cell separator membrane which provided direct electrical contact between the positive and negative electrodes. The batteries tested during this work were common batteries used in existing automotive applications, and they included a nickel manganese cobalt (NMC) battery from a Chevrolet Bolt, a lithium manganese oxide (LMO) battery from a Chevrolet Volt, and a lithium iron phosphate (LFP) battery in a hybrid transit bus. The battery abuse and emissions tests were designed to intentionally drive the three different battery chemistries into thermal runaway while measuring battery temperatures, battery voltages and gaseous emissions.
Technical Paper

Improving Heavy Duty Natural Gas Engine Efficiency: A Systematic Approach to Application of Dedicated EGR

2020-04-14
2020-01-0818
The worldwide trend of tightening CO2 emissions standards and desire for near zero emissions is driving development of high efficiency natural gas engines for a low CO2 replacement of traditional diesel engines. A Cummins Westport ISX12 G was previously converted to a Dedicated EGR® (D-EGR®) configuration with two out of the six cylinders acting as the EGR producing cylinders. Using a systems approach, the combustion and turbocharging systems were optimized for improved efficiency while maintaining the potential for achieving 0.02 g/bhp-hr NOX standards. A prototype variable nozzle turbocharger was selected to maintain the stock torque curve. The EGR delivery method enabled a reduction in pre-turbine pressure as the turbine was not required to be undersized to drive EGR. A high energy Dual Coil Offset (DCO®) ignition system was utilized to maintain stable combustion with increased EGR rates.
Technical Paper

Solid Particle Number and Ash Emissions from Heavy-Duty Natural Gas and Diesel w/SCRF Engines

2018-04-03
2018-01-0362
Solid and metallic ash particle number (PN) and particulate matter (PM) mass emission measurements were performed on a heavy-duty (HD) on-highway diesel engine and a compressed natural gas (CNG) engine. Measurements were conducted under transient engine operation that included the FTP, WHTC and RMC. Both engines were calibrated to meet CARB ultra low NOX emission target of 0.02 g/hp-hr, a 90% reduction from current emissions limit. The HD diesel engine final exhaust configuration included a number of aftertreatement sub-systems in addition to a selective catalytic reduction filter (SCRF). The stoichiometric CNG engine final configuration included a closed coupled Three Way Catalyst (ccTWC) and an under floor TWC (ufTWC). The aftertreatment systems for both engines were aged for a full useful life (FUL) of 435,000 miles, prior to emissions testing. PM mass emissions from both engines were comparable and well below the US EPA emissions standard.
Journal Article

Methanol Fuel Testing on Port Fuel Injected Internal-Only EGR, HPL-EGR and D-EGR® Engine Configurations

2017-10-08
2017-01-2285
The primary focus of this investigation was to determine the hydrogen reformation, efficiency and knock mitigation benefits of methanol-fueled Dedicated EGR (D-EGR®) operation, when compared to other EGR types. A 2.0 L turbocharged port fuel injected engine was operated with internal EGR, high-pressure loop (HPL) EGR and D-EGR configurations. The internal, HPL-EGR, and D-EGR configurations were operated on neat methanol to demonstrate the relative benefit of D-EGR over other EGR types. The D-EGR configuration was also tested on high octane gasoline to highlight the differences to methanol. An additional sub-task of the work was to investigate the combustion response of these configurations. Methanol did not increase its H2 yield for a given D-EGR cylinder equivalence ratio, even though the H:C ratio of methanol is over twice typical gasoline.
Journal Article

Design and Implementation of a D-EGR® Mixer for Improved Dilution and Reformate Distribution

2017-03-28
2017-01-0647
The Dedicated EGR (D-EGR®) engine has shown improved efficiency and emissions while minimizing the challenges of traditional cooled EGR. The concept combines the benefits of cooled EGR with additional improvements resulting from in-cylinder fuel reformation. The fuel reformation takes place in the dedicated cylinder, which is also responsible for producing the diluents for the engine (EGR). The D-EGR system does present its own set of challenges. Because only one out of four cylinders is providing all of the dilution and reformate for the engine, there are three “missing” EGR pulses and problems with EGR distribution to all 4 cylinders exist. In testing, distribution problems were realized which led to poor engine operation. To address these spatial and temporal mixing challenges, a distribution mixer was developed and tested which improved cylinder-to-cylinder and cycle-to-cycle variation of EGR rate through improved EGR distribution.
Journal Article

Automated Driving Impediments

2016-09-27
2016-01-8007
Since the turn of the millennium, automated vehicle technology has matured at an exponential rate, evolving from research largely funded and motivated by military and agricultural needs to a near-production market focused on everyday driving on public roads. Research and development has been conducted by a variety of entities ranging from universities to automotive manufacturers to technology firms demonstrating capabilities in both highway and urban environments. While this technology continues to show promise, corner cases, or situations outside the average driving environment, have emerged highlighting scenarios that impede the realization of full automation anywhere, anytime. This paper will review several of these corner cases and research deficiencies that need to be addressed for automated driving systems to be broadly deployed and trusted.
Technical Paper

Fuel Effects Study with In-Use Two-Stroke Motorcycles and All-Terrain-Vehicles

2013-10-14
2013-01-2518
This paper covers work performed for the California Air Resources Board and US Environmental Protection Agency by Southwest Research Institute. Emission measurements were made on four in-use off-road two-stroke motorcycles and all-terrain vehicles utilizing oxygenated and non-oxygenated fuels. Emission data was produced to augment ARB and EPA's off-road emission inventory. It was intended that this program provide ARB and EPA with emission test results they require for atmospheric modeling. The paper describes the equipment and engines tested, test procedures, emissions sampling methodologies, and emissions analytical techniques. Fuels used in the study are described, along with the emissions characterization results. The fuel effects on exhaust emissions and operation due to ethanol content and fuel components is compared.
Technical Paper

Comparison of SCR Catalyst Performance on RMC SET Emission Cycle between an Engine and a High Flow Burner Rig

2013-04-08
2013-01-1070
Government agencies like EPA play an important role through regulation to reduce emissions and fuel consumption and to drive technological developments to reduce the environmental impact of burning petroleum fuels. Emissions testing and control is one of the leading and growing fields in the development of modern vehicles. Recently, Cummins Emissions Solutions (CES) and Southwest Research Institute (SwRI) worked jointly in order to achieve a method to conduct emissions testing efficiently and effectively. The collaborative work between the two organizations led to the usage of FOCAS HGTR™ (a diesel-based burner test rig at SwRI) to simulate the exhaust conditions generated by a 2010 ISX Cummins production engine operating over an EPA standard Ramped Modal Cycle Supplemental Emissions Test (RMC SET) cycle.
Technical Paper

Numerical and Experimental Characterization of the Dual-Fuel Combustion Process in an Optically Accessible Engine

2013-04-08
2013-01-1670
The dual-fuel combustion process of ethanol and n-heptane was characterized experimentally in an optically accessible engine and numerically through a chemical kinetic 3D-CFD investigation. Previously reported formaldehyde PLIF distributions were used as a tracer of low-temperature oxidation of straight-chained hydrocarbons and the numerical results were observed to be in agreement with the experimental data. The numerical and experimental evidence suggests that a change in the speed of flame propagation is responsible for the observed behavior of the dual-fuel combustion, where the energy release duration is increased and the maximum rate of pressure rise is decreased. Further, an explanation is provided for the asymmetrical energy release profile reported in literature which has been previously attributed to an increase in the diffusion-controlled combustion phase.
Journal Article

Determination of the PEMS Measurement Allowance for PM Emissions Regulated Under the Heavy-Duty Diesel Engine In-Use Testing Program

2012-04-16
2012-01-1250
This paper summarizes the Heavy-Duty In-Use Testing (HDUIT) measurement allowance program for Particulate Matter Portable Emissions Measurement Systems (PM-PEMS). The measurement allowance program was designed to determine the incremental error between PM measurements using the laboratory constant volume sampler (CVS) filter method and in-use testing with a PEMS. Two independent PM-PEMS that included the Sensors Portable Particulate Measuring Device (PPMD) and the Horiba Transient Particulate Matter (TRPM) were used in this program. An additional instrument that included the AVL Micro Soot Sensor (MSS) was used in conjunction with the Sensors PPMD to be considered a PM-PEMS. A series of steady state and transient tests were performed in a 40 CFR Part 1065 compliant engine dynamometer test cell using a 2007 on-highway heavy-duty diesel engine to quantify the accuracy and precision of the PEMS in comparison with the CVS filter-based method.
Technical Paper

Performance and Emissions of Diesel and Alternative Diesel Fuels in Modern Light-Duty Diesel Vehicles

2011-09-11
2011-24-0198
Conventional diesel fuel has been in the market for decades and used successfully to run diesel engines of all sizes in many applications. In order to reduce emissions and to foster energy source diversity, new fuels such as alternative and renewable, as well as new fuel formulations have entered the market. These include biodiesel, gas-to-liquid, and alternative formulations by states such as California. Performance variations in fuel economy, emissions, and compatibility for these fuels have been evaluated and debated. In some cases contradictory views have surfaced. “Sustainable”, “Renewable”, and “Clean” designations have been interchanged. Adding to the confusion, results from one fuel in one type of engine such as an older heavy-duty engine, is at times compared to that of another fuel in another type such as a modern light-duty engine. This study was an attempt to compare the performance of several fuels in identical environments, using the same engine, for direct comparison.
Technical Paper

A Test Method for Evaluating Feasibility of Lean Nitrous Oxide Traps

2011-01-19
2011-26-0030
The Lean NOx Trap (LNT) is a technology that could be used to reduce oxides of nitrogen from heavy-duty diesel engines to meet emissions standards (US 2010 and EURO 4/5/6). This paper describes a case-study for evaluating the feasibility of an LNT. LNTs suffer from sulfur poisoning and thermal aging limitations. Catalyst formulations allow reversal of sulfur poisoning through desulfation procedures. A case study was performed using a 7-liter diesel engine equipped with VGT, common rail fuel injection system, cooled EGR, oxidation catalyst and DPF. The LNT was positioned after the particulate filter. Gaseous raw emissions were measured from engine and various stages of aftertreatment. A Fourier Transform Infrared (FTIR) analyzer was used to characterize Ammonia and SO₂. Temperatures were measured in the substrate. Fast response NOx sensor allowed for continuous monitoring of the NOx in the LNT. A wide-range O₂ sensor was also utilized to measure equivalence ratio.
Journal Article

Performance and Emissions of Diesel and Alternative Diesel Fuels in a Heavy-duty Industry-Standard Older Engine

2010-10-25
2010-01-2281
Conventional diesel fuel has been in the market for decades and used successfully to run diesel engines of all sizes in many applications. In order to reduce emissions and to foster energy source diversity, new fuels such as alternative and renewable, as well as new fuel formulations have entered the market. These include biodiesel, gas-to-liquid, and alternative formulations by states such as California. Performance variations in fuel economy, emissions, and compatibility for these fuels have been evaluated and debated. In some cases contradictory views have surfaced. “Sustainable”, “Renewable”, and “Clean” designations have been interchanged. Adding to the confusion, results from one fuel in one type of engine such as an older heavy-duty engine, is at times compared to that of another type such as a modern light-duty. This study was an attempt to compare the performance of several fuels in an identical environment, using the same engine, for direct comparison.
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