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Three-way catalysts are used in gasoline vehicles for simultaneous purifying nitrogen oxide, carbon monoxide, and hydrocarbon in recent years. However, the reduction of ammonia emission generated in the three-way catalyst is pressing issue. In EURO 7, ammonia will also be subject to the Real Driving Emissions regulation, and its emissions must be reduced. Previous studies have shown that ammonia emissions are higher under fuel-rich conditions, suggesting that differences in driving behavior have a significant impact on ammonia emissions in real-world driving, which includes various driving environments. In this study, driving tests were conducted on a direct- injection gasoline vehicle equipped with a three-way catalyst and Portable Emission Measurement System and Sensor-based Emission Measurement System to investigate the actual ammonia emissions on actual roads.

A multi-functional membrane filter was developed through deposition of agglomerated Three-Way Catalyst particles with a size of 1 ~ 2 microns on the conventional bare particulate filter. The filtration efficiency reaches almost 100 % from the beginning of soot trapping with a low pressure drop and both reductions of NO and CO emission were achieved.

In recent years, particulate matter (PM) emitted from direct-injection gasoline vehicles is becoming an increasingly concerning problem. In addition, it is often reported that ammonia (NH3) is emitted from gasoline vehicles equipped with a three-way catalyst. These emissions might be largely emitted especially when driving in on-road driving conditions. In this study, we investigated the emissions, NOx, NH3, and PM/PN (particulate number) of a light-duty direct-injection gasoline vehicle when driving on actual roads. Using a small direct-injection gasoline vehicle equipped with a three-way catalyst, experiment was conducted 8 times on the same route, and these emissions were measured. In this study, vehicle specific power (VSP) was introduced, which can be calculated using vehicle parameters, vehicle speed, and road gradient. The effects of parameters acquired through on-board diagnostics (OBD) port and VSP on emissions were investigated.

Compression ignition engines provide superior thermal efficiency over other internal combustion engines. Unfortunately the combustion process is diffusive combustion, meaning a lot of fuel is impinged the on the piston and cylinder wall. This creates cooling loss coupled with smoke, CO and THC. Minimization of the nozzle orifice diameter is a simple method widely used to shorten spray penetration. However, decreasing the nozzle orifice diameter also decreases fuel flow rate resulting in a prolonged injection and combustion process and reducing thermal efficiency. An offset orifice nozzle causes less fuel impingement by shorter fuel spray penetration without significant reduction of fuel flow rate. The offset orifice nozzle was made by shifting its alignment from the center of the sac to the edge of the sac following the swirl direction. A counterbore design was applied to maintain constant orifice length.

In a state-of-the-art lean-burn spark ignition engine, a strong in-cylinder flow field with enhanced turbulence intensity is formed, and understanding the wall heat transfer mechanism of such a complex flow is required. The flow velocity and temperature profiles inside the wall boundary layer are strongly related to the heat transfer mechanism. In this study, two-dimensional three-component (2D3C) velocity distribution near the piston top surface was measured during the compression stroke in a strong tumble flow using a rapid compression and expansion machine (RCEM) and a stereoscopic micro-PIV system. The bore, stroke, compression ratio, and compression time were 75 mm, 128 mm, 15, and 30 ms (equivalent to 1000 rpm), respectively.

Every year, exhaust gas regulations are getting stricter with the intention to solve the average air pollution problem, however, local roadside pollution is still a pressing issue. In order to solve this local roadside pollution problem, it is necessary to evaluate and/or predict “where” and “how much” pollutants such as NOx are emitted. To predict the local roadside pollution, it is necessary to collect emissions data from various kinds of vehicles driving on real-world and analyze them. In recent years, Real Driving Emission regulations using PEMS (Portable Emission Measurement System) have been introduced mainly in Europe. A typical PEMS configuration can weigh close to 100 kg however, and its weight affects the driving conditions of vehicles running on actual roads. In this study, we focused on the analysis of real-world emissions using SEMS (Sensor-based Emission Measurement System).

CI engines provide higher thermal efficiency compared to other internal combustion engines. On the other hand large amounts of smoke and NOx are produced during combustion. Smoke and NOx can be reduced by applying Premixed Charge Compression Ignition (PCCI) combustion. Unfortunately, the problems of PCCI combustion include unstable start of combustion and limited operating range. The multi-pulse ultrahigh pressure injection allows fuel to control PCCI combustion. The objective of offset orifice nozzle is to improve mixture formation and shorten spray penetration in order to increase thermal efficiency and control PCCI combustion. The offset orifice nozzle was designed by shift orifice aliment from into the sac center to edge of sac follow swirl direction. Counter bore design was applied to offset orifice nozzle in order to keep the constant orifice length as standard nozzle.

Serious problems occur in an exhaust gas recirculation system due to an adhesive hard deposit. It is important to clarify the mechanism of the hard deposit formation to suppress it. In this study, the effect of exhaust gas composition on hard deposit formation was investigated. The amount of the hard deposit formed under various operating conditions while keeping the total hydrocarbon concentration constant was different. The component analyses of the exhaust gas and the hard deposit clarified that polycyclic aromatic hydrocarbon in the exhaust gas strongly affected the hard deposit formation.

Compression ignition (CI) engines provide higher thermal efficiency compared to other internal combustion engines although large amounts of NOx and soot are produced during combustion. NOx and soot emissions can be reduced by using Premixed Charge Compression Ignition (PCCI) combustion. However, the problems of PCCI combustion include limited operating range, unstable start of combustion and an increase in combustion noise. The multi-pulse ultrahigh pressure injection allows fuel to be injected near TDC, improving mixture formation and enhancing the possibility to extend the operating range of PCCI combustion. The objective of this paper is to control and extend the operating range of PCCI combustion using multi-pulse ultrahigh pressure injection. This has not been studied before. Combustion characteristics were investigated using apparent rate of heat release analysis, heat balance analysis, exhaust emission measurement and soot concentration measurement.

Nowadays, most manufacturers are looking for the improvement of lightweight parts and other components in the automobile field. Carbon fiber and glass fiber are the most effective materials for their requirement to reduce the weight in vehicles due to their light weight and high tensile strength. The diameter of carbon fiber is 6 μm while glass fiber diameter is 17 μm. The mechanical tensile force of carbon fiber and glass fiber are 430 N and 290 N respectively on fiber alone without matrix. Carbon fibers are gradually smaller in each filament due to tensile force. Approximately 5 mm are elongated for both carbon fiber and glass fiber in tensile test report. In current research, characteristic and tensile force of carbon fiber and glass fiber were investigated by using electron microscopy, Raman spectroscopy and XRD.

To adhere to stringent environmental regulations, SI (spark ignition) engines are required to achieve higher thermal efficiency. In recent years, EGR (exhaust gas recirculation) systems and lean-burn operation has been recognized as key technologies. Under such operating conditions, reducing CCV (cycle-to-cycle variation) in combustion is critical to the enhancement of overall engine performance. Flow-field CCV is one of the considerable factors affecting combustion in engines. Conventionally, in research on flow fields in SI engines, the ensemble average is used to separate the measured velocity field into a mean component and a fluctuation component, the latter of which contains a CCV component and a turbulent component. To extract the CCV of the flow field, previous studies employed spatial filter, temporal filter, and POD (proper orthogonal decomposition) methods.

The soot contamination in used engine oils of diesel engine vehicles was about 1% by weight. The soot and metal wear particle sizes might be in the range of 0-1 µm and 1-25 µm, respectively. The characteristics of soot affecting on metal wear was investigated. Soot particle contamination in diesel engine oil was simulated using carbon black. Micro-nanostructure of soot particles were studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and laser diffraction spectroscopy (LDS). The metal wear behavior was studied by means of a Four-Ball tribology test with wear measured. Wear roughness in micro-scale was investigated by high resolution optical microscopy (OM) , 3D rendering optical technique and SEM image processing method. It was found that the ball wear scar diameter increased proportionally to the soot primary particle size. The effect of biodiesel contamination were also increasing in wear scar diameter.

Diesel engines are high thermal efficiency because of high compression ratio but produce high concentration of particulate matter (PM) because of direct injection fuel diffusion combustion. PM must be removed from the exhaust gas to protect human health. This research describes biodiesel engine performance, efficiency and combustion behavior using combustion pressure analyzer. It was clearly observed that PM emitted from CI engines can be reduced by using renewable bio-oxygenated fuels. The morphology and nanostructure of fossil fuel and biofuel PMs were investigated by using a Scanning electron microscopy (SEM) and Transmission electron microscopy (TEM). The morphology of biodiesel and diesel doesn’t have much different in the viewpoint of particulate matter trapping using DPF micro surface pores. The agglomerated ultrafine particles and primary nanoparticles sizes of diesel and biodiesel engine’s PM are approximately 50-500 nm and 20-50 nm, respectively.

Primary energy source such as fossil fuel keep decreasing due to various kind of usage. According to less amount of the fossil fuel, human seeks for an alternative fuel source such as alcohol. Alcohol like ethanol can be produced easily from strarchy plant. But using alcohol as blended fuel with diesel fuel doesn't work well because alcohol has low cetane number, lack of lubricity and very low miscibility with diesel fuel. To overcome this, fumigation system or port fuel injection of alcohol seems interesting. Although it requires more complicate system but it can compensate the miscibility issue and alcohol can be used in higher dose to give more energy. Diesel engine produces a lot of emission such as NOx and some other carbon content emission like HC, CO and soot due to they run in lean condition as their characteristic. Modern diesel engines are now coupled with exhaust gas recirculation system to help reduce in main emission like NOx.

Diesel engine is one the effective solutions for reducing CO2 and recognized as a leading candidate for mitigating global warming. To comply with increasingly stringent emission standards, all diesel engines require some sort of NOx control systems such as selective catalytic reduction (SCR) systems. The SCR catalyst for reducing NOx from diesel engines is classified into two groups, urea-SCR and HC-SCR catalyst, respectively. Although the urea-SCR catalyst is widely recognized as promising de-NOx technology in respect to the NOx conversion efficiency, it have some outstanding issues such as ammonia slip, urea injection, storage space, freezing and some infrastructures for supplying urea water solutions. In an attempt to overcome the inherent shortcoming of existing urea-SCR catalyst, hydrocarbons have been considered as alternative reducing agents for SCR process, instead of NH3.

Nanostructures of diesel and biodiesel engine particulate matters (PMs) were investigated by using a Transmission Electron Microscopy (TEM). The average single particle sizes of biodiesel and diesel PMs are approximately 30-40 nm and 50-60 nm, respectively. Image processing process was used to estimate each carbon platelet length by using TEM image. The average carbon platelet length of biodiesel and diesel PMs are in the range of 0.1-7.0 nm. Moreover, carbon atoms per cubic volume of PMs are approximately 500-900. The result shows that engine load and fuel property are strongly impact on the size of single particle and carbon atom density of particle. This is one of interesting behaviors need to be investigated for better understanding. The results of this research would be used as basic information for design and develop removing process of PM emitted from engine combustion which using in diesel and biodiesel fuels.

This work investigates the effects of ignition improvers on the ignition and combustion characteristics of hydrous ethanol with 5% by weight water and 1% by weight Lauric acid (Eh95) under simulated diesel engine conditions using the rapid compression and expansion machine (RCEM). Results indicate that hydrous ethanol with commercial additive (ED95) and hydrous ethanol with 5% by weight glycerol ethoxylate in hydrous ethanol exhibit a near identical rate-of-pressure-rise and heat release rate. Ignition delay of hydrous ethanol with 5% by weight glycerol ethoxylate is shorter, but hydrous ethanol with 1% by weight glycerol ethoxylate has longer ignition delay time and different combustion characteristics compared with hydrous ethanol with commercial additive (ED95). Hydrous ethanol with 1% by weight glycerol ethoxylate and hydrous ethanol with 5% by weight glycerol ethoxylate are considered suitable fuels for high compression-ratio diesel engines.

The increasing of global energy demand and stringent pollution regulations have promoted research on alternative fuels. In Thailand, ethanol, can be produced from many sources of national agriculture products as renewable fuel, which was strongly promoted by government due to its many merits for use in transportation field. In this study, combustion characteristics of ethanol-gasoline blend (20%, 85%, and 100%) as well as pure gasoline (E0) were investigated by using a swirl-generated constant volume combustion chamber. Flame propagations of different fuel blends were observed by high speed Schlieren photography technique while pressure history data were recorded for detailed combustion analysis. Combustion behavior, combustion duration and rate of pressure rise of all tested fuels were investigated in various swirl intensities and equivalence ratios. In addition, effect of swirl intensities and ethanol concentration on lean misfire limit were also discussed.

In order to investigate the combustion phenomena in a combustion chamber of the diesel engine at transient operations, the simultaneous measurements of temperatures of flame and wall surface in a combustion chamber were conducted. The new technique for simultaneous measurements of flame temperature and wall surface was developed. Laser-Induced phosphorescence was used for the measurement of wall surface temperature which was coupled with the flame temperature measurement by a two-color pyrometry. The NOx and soot emissions were also measured simultaneously in transient operations. The relation between the temporal changes of emissions and temperatures of flame and surface wall are discussed. The results show that the temporal change of NOx emission during transient operation is similar to that of the average gas temperature in a chamber. On the other hand, the temporal change of soot emission is similar to neither that of flame temperature nor that of average gas temperature.

Particulate matter (PM) trapping and oxidation in regeneration on the surface of a diesel particulate catalyst-membrane filter (DPMFs) were investigated in detail using an all-in-focus optical microscope. The DPMF consists of two-layer sintered filters, where a SiC-nanoparticle membrane (made from a mixture of 80 nm and 500 nm powders) covers the surface of a conventional SiC filter. Using a visualization experiment, it was shown that PMs were trapped homogeneously along fine surface pores of the membrane's top surface, whereas in the regeneration process, the particulates in contact with the membrane may have been oxidized with some catalytic effect of the SiC nanoparticles. A soot cake was reacted continuously on the nanoparticles since pushed by a gas flow. The oxidation temperature of particulate trapped on the SiC-nanoparticle membrane was about 75 degrees lower than that on the conventional diesel particulate filters (DPF) without a catalyst.