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Physicochemical characteristics of particulate matters which are influenced by engine oil additives from engine combustion of diesel and synthetic biodiesel: hydrotreated vegetable oil (HVO) were successfully investigated using electron microscopy, electron dispersive x-ray spectroscopy and thermogravimetric analysis. The agglomerate structure of diesel PM, HVO PM and diesel blending lubricant PM are similar in micro-scales. However, nanostructure of soot is a spherical shape composed of curve line crystallites while the metal oxide ash nanostructure is composed of parallel straight line hatch patterns. The oxidation kinetics of fuel blending lubricant PMs are higher than neat fuel PMs due to catalytic effect of incombustible metal additives from engine lubricating oil.

The soot contamination in used engine oils of diesel engine vehicles was about 1% by weight. The soot and metal wear particle sizes might be in the range of 0-1 µm and 1-25 µm, respectively. The characteristics of soot affecting on metal wear was investigated. Soot particle contamination in diesel engine oil was simulated using carbon black. Micro-nanostructure of soot particles were studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and laser diffraction spectroscopy (LDS). The metal wear behavior was studied by means of a Four-Ball tribology test with wear measured. Wear roughness in micro-scale was investigated by high resolution optical microscopy (OM) , 3D rendering optical technique and SEM image processing method. It was found that the ball wear scar diameter increased proportionally to the soot primary particle size. The effect of biodiesel contamination were also increasing in wear scar diameter.

Diesel engines are high thermal efficiency because of high compression ratio but produce high concentration of particulate matter (PM) because of direct injection fuel diffusion combustion. PM must be removed from the exhaust gas to protect human health. This research describes biodiesel engine performance, efficiency and combustion behavior using combustion pressure analyzer. It was clearly observed that PM emitted from CI engines can be reduced by using renewable bio-oxygenated fuels. The morphology and nanostructure of fossil fuel and biofuel PMs were investigated by using a Scanning electron microscopy (SEM) and Transmission electron microscopy (TEM). The morphology of biodiesel and diesel doesn’t have much different in the viewpoint of particulate matter trapping using DPF micro surface pores. The agglomerated ultrafine particles and primary nanoparticles sizes of diesel and biodiesel engine’s PM are approximately 50-500 nm and 20-50 nm, respectively.

Primary energy source such as fossil fuel keep decreasing due to various kind of usage. According to less amount of the fossil fuel, human seeks for an alternative fuel source such as alcohol. Alcohol like ethanol can be produced easily from strarchy plant. But using alcohol as blended fuel with diesel fuel doesn't work well because alcohol has low cetane number, lack of lubricity and very low miscibility with diesel fuel. To overcome this, fumigation system or port fuel injection of alcohol seems interesting. Although it requires more complicate system but it can compensate the miscibility issue and alcohol can be used in higher dose to give more energy. Diesel engine produces a lot of emission such as NOx and some other carbon content emission like HC, CO and soot due to they run in lean condition as their characteristic. Modern diesel engines are now coupled with exhaust gas recirculation system to help reduce in main emission like NOx.

As well-known, the diesel engine has the highest thermal efficiency at the same load as compared with internal combustion engine but its disadvantage is particulate matter (PM) emitted to the atmosphere. The studies of this paper were divided into two parts. The first part studied the quantity of PM from the both diesel and biodiesel fuels at 80% load (2400 rpm) by the trapping process on diesel particulate filter (DPF) used in a partial flow dilution tunnel. The second part studied the regeneration process of PM under the flow rate of oxygen and nitrogen gas of 13.5 L/min with 10%, 15%, and 21% of oxygen gas. The result showed that amount of PM from biodiesel fuel was lower around two times than PM from diesel fuel. The duration in regeneration process of biodiesel's PM was shorter than diesel while increasing of oxygen percentage can reduce regeneration time.

The increase of air pollution and global warming is a threat for human life. Besides, the price of petroleum is increasing rapidly and the resources are diminishing. This obliged scientists and engineers to look for alternative sources of energy, which are cleaner and more sustainable. Biodiesel, defined as mono-alkyls of esters from vegetable oils and animals fat, is a cleaner renewable fuel and has been considered as the best alternative for petroleum based diesel fuel hence it can be used in any compression ignition engines without any significant modification. The main advantages of using biodiesel are its renewability and better quality of exhaust gas emissions due to their higher content of oxygen. The produce less soot and hence the feed stuck is plant it will regenerate the CO2 by the photosynthesis which ensures the renewability and reduces global warming.

Nanostructures of diesel and biodiesel engine particulate matters (PMs) were investigated by using a Transmission Electron Microscopy (TEM). The average single particle sizes of biodiesel and diesel PMs are approximately 30-40 nm and 50-60 nm, respectively. Image processing process was used to estimate each carbon platelet length by using TEM image. The average carbon platelet length of biodiesel and diesel PMs are in the range of 0.1-7.0 nm. Moreover, carbon atoms per cubic volume of PMs are approximately 500-900. The result shows that engine load and fuel property are strongly impact on the size of single particle and carbon atom density of particle. This is one of interesting behaviors need to be investigated for better understanding. The results of this research would be used as basic information for design and develop removing process of PM emitted from engine combustion which using in diesel and biodiesel fuels.

This work investigates the effects of ignition improvers on the ignition and combustion characteristics of hydrous ethanol with 5% by weight water and 1% by weight Lauric acid (Eh95) under simulated diesel engine conditions using the rapid compression and expansion machine (RCEM). Results indicate that hydrous ethanol with commercial additive (ED95) and hydrous ethanol with 5% by weight glycerol ethoxylate in hydrous ethanol exhibit a near identical rate-of-pressure-rise and heat release rate. Ignition delay of hydrous ethanol with 5% by weight glycerol ethoxylate is shorter, but hydrous ethanol with 1% by weight glycerol ethoxylate has longer ignition delay time and different combustion characteristics compared with hydrous ethanol with commercial additive (ED95). Hydrous ethanol with 1% by weight glycerol ethoxylate and hydrous ethanol with 5% by weight glycerol ethoxylate are considered suitable fuels for high compression-ratio diesel engines.

The increasing of global energy demand and stringent pollution regulations have promoted research on alternative fuels. In Thailand, ethanol, can be produced from many sources of national agriculture products as renewable fuel, which was strongly promoted by government due to its many merits for use in transportation field. In this study, combustion characteristics of ethanol-gasoline blend (20%, 85%, and 100%) as well as pure gasoline (E0) were investigated by using a swirl-generated constant volume combustion chamber. Flame propagations of different fuel blends were observed by high speed Schlieren photography technique while pressure history data were recorded for detailed combustion analysis. Combustion behavior, combustion duration and rate of pressure rise of all tested fuels were investigated in various swirl intensities and equivalence ratios. In addition, effect of swirl intensities and ethanol concentration on lean misfire limit were also discussed.

The present study aims to investigate the parameters affecting cold start characteristics of ethanol at low temperature, and suggest a solution to avoid cold starting problem without the installation of second fuel tank. The testing engine is a 125cc volume displacement, single-cylinder four strokes SI engine with fuel injection and ignition timing system controlled by ECU (electronic control unit). The cold starting performance tests were extensively conducted with different percentages of ethanol blends, surrounding temperatures, heating inside combustion chamber, heater injector, pre-cranking without fuel injection, and amount of fuel injection. From the experimental results, when using ethanol fuel in conventional engine, the problem of cold starting was observed at surrounding temperature lower than 20°C for ethanol. Increasing of injection duration can lower the possible cold start temperature of neat ethanol.

Energy optimal control theory (EOC) is applied to the energy flow control of a hybrid electric vehicle. Since the differential equation is solved analytically, the control law can be easily implemented in real time. Because the objective function is described in power form that permits negative value, not only the energy consumption is minimized but also the energy regeneration by the motor is maximized. In the simulation for the 10-mode driving, it is shown that the fuel cost of EOC is 15% lower than the rule based control (RBC).

Through microscopic visualization experiments, a process generally known as depth filtration was shown to be caused by surface pores. Moreover, the existence of a soot cake layer was an important advantage for filtration performance because it could trap most of the particulates. We proposed an ideal diesel particulate filter (DPF), in which a silicon carbide (SiC) nanoparticle membrane (made from a mixture of 80 nm and 500 nm powders) instead of a soot cake was sintered on the DPF wall surface; this improved the filtration performance at the beginning of the trapping process and reduced energy consumption during the regeneration process. The proposed filter was called a diesel particulate membrane filter (DPMF). A diesel fuel lamp was used in the trapping process to verify the trapping and oxidation mechanisms of ultrafine particulate matter. Thus, the filtration performance of the membrane filters was shown to be better than that of conventional DPFs.

A new solar furnace system using a stationary elliptic dish and heliostats is proposed. Since the elliptic dish has two focuses (an upper focus and a lower focus) for elliptic geometry, this system has three advantages. The first is enable to fix a solar reactor on the ground, the second to expand the heliostat field largely, and the third to concentrate the direct solar radiation in a small area around the lower focus. The horizontal deviation from the lower focus of the direct solar radiation was estimated within ±1.2m for the heliostat field of 100m and the tower-reflector height of 70m. The system using the elliptic dish and heliostats is available as high-concentration system due to large scale of solar energy.

Multi-step water splitting with Mn-ferrite(MnFe2O4)/sodium carbonate(Na2CO3) system accompanying endothermic reaction was investigated for converting solar energy into chemical energy. This water splitting is caused by the oxidation-reduction of manganese ion in the Mn-ferrite. Multi-water splitting with MnFe2O4/Na2CO3 system was consisted of three steps. The first step was hydrogen generation at 1073K. The second step was oxygen release at 1273K. The third step was Na2CO3 reproduction at 873K. The mechanism of multi-water splitting has been considered by XRD, chemical analysis of colorimetry and back titration. The temperature range 873 to 1273K is quite lower than those studied on the solar furnace reaction (O2 releasing step) in two-step water splitting (1500-2300K). This lower temperature range would permit further progress in converting the direct solar energy into chemical energy.

A new energy extraction and utilization system for low grade solid fuels such as coal and wastes is proposed, where solid fuels are gasified with high temperature air. The syngas is first cooled in a waste heat recovery boiler to extract its sensible thermal energy followed by conventional low temperature gas cleaning. A part of this cleaned-up syngas is used for high temperature air preheating while the rest is used for various energy utilization and conversion systems such as industrial furnaces, boilers and gas turbines. Experimental demonstration results for two main components, i.e. a gasifier and a high temperature air preheater are reported.