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New 2A/F systems different from usual A/F-O2 systems are being developed to cope with strict regulation of exhaust gas. In the 2A/F systems, 2A/F sensors are equipped in front and rear of a three-way catalyst. The A/F-O2 systems are ideas which use a rear O2 to detect exhaust gas leaked from three-way catalyst early and feed back. On the other hand, the 2A/F systems are ideas which use a rear A/F sensor to detect nearly stoichiometric gas discharged from the three-way catalyst accurately, and to prevent leakage of exhaust gas from the three-way catalyst. Therefore, accurate detection of nearly stoichiometric gas by the rear A/F sensor is the most importrant for the 2A/F systems. In general, the A/F sensors can be classified into two types, so called, one-cell type and two-cell type. Because the one-cell type A/F sensors don’t have hysteresis, they have potential for higher accuracy.

Countries and regions around the world are tightening emissions regulations in reaction to the increasing awareness of environmental conservation. At the same time, growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. This catalyst incorporates rhodium (Rh) clusters with a particle size of several nanometers, and stabilized CeO2-ZrO2 solid-solution (CZ) with a pyrochlore crystal structure as a high-volume oxygen storage capacity (OSC) material with a slow O2 storage rate.

Toyota Motor Corporation is developing a series of engines belonging to its ESTEC (Economy with Superior Thermal Efficient Combustion) development concept. This paper describes the development of 8NR-FTS after the subsequent launch of the 2.0-liter DI Turbocharged 8AR-FTS. 8NR-FTS is a 1.2-liter inline 4-cylinder spark ignition downsized turbocharged direct injection (DI) gasoline engine. By following the same basic concepts as 8AR-FTS engine [1], the 8NR-FTS incorporates various fuel efficient technologies such as a cylinder head with an integrated exhaust manifold, the Atkinson cycle using the center-spooled variable valve timing with mid-position lock system (VVT-iW), and intensified in-cylinder turbulence to achieve high-speed combustion.

In this paper, a control strategy to switch NSR (NOx storage and reduction) function from standard DeNOx by rich combustion to DiAir (Diesel NOx After-treatment by Adsorbed Intermediate Reductants) and additional advantages to use HCI (Hydrocarbon Injector) during desulfation were introduced. Investigations under a transient cycle suggest that NOx conversion with DiAir is strongly affected by preliminary NOx storage condition in the NSR catalyst. To avoid NOx breakthrough just after starting HC dosing for DiAir, a rich operation to reduce stored NOx was shown to be important and high NOx conversion could be maintained using this control strategy under a transient cycle. Furthermore, by combining HCI and in-cylinder post injection, usage of rich condition for NSR DeSOx can be expand to wider engine speed and load area.

At the engine restart, when the temperature of the catalytic converter is low, additional fuel consumption would be required to warm up the catalyst for controlling exhaust emission.The aim of this study is to find a thermally optimal way to reduce fuel consumption for the catalyst warm up at the engine restart, by improving the thermal retention of the catalytic converter in the cool down process after the previous trip. To make analysis of the thermal flow around the catalytic converter, a 2-D thermal flow model was constructed using the thermal network method. This model simulates the following processes: 1) heat conduction between the substrate and the stainless steel case, 2) heat convection between the stainless steel case and the ambient air, 3) heat convection between the substrate and the gas inside the substrate, 4) heat generation due to chemical reactions.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).

Premixed diesel combustion modes including low temperature combustion and MK combustion are expected to realize smokeless and low NOx emissions. As ignition must be delayed until after the end of fuel injection to establish these combustion modes, methods for active ignition control are being actively pursued. It is reported that alcohols including methanol and ethanol strongly inhibit low temperature oxidation in HCCI combustion offering the possibility to control ignition with alcohol induction. In this research improvement of diesel combustion and emissions by ethanol intake port injection for the promotion of premixing of the in-cylinder injected diesel fuel, and by increased EGR for the reduction of combustion temperature.

Newly designed gears are subject to higher loads that demand a steel that is capable of greater pitting resistance. The application of shot peening to gears has been increasing to improve tooth root strength, but pitting resistance had not been necessarily high. This study examines the effect of alloying additions mainly on tempering resistance and the formation of a non-martensitic layer. The developed high Si-Mo type steel shows excellent pitting resistance, even in shot peened gears, as compared to that of conventional steels due to high tempering resistance and the thin, uniform non-martensitic layer. This new steel is of practical use in some multi-speed automatic transmission gears.

A new, free-cutting steel, hereafter referred to as “non-lead-added free-cutting steel”, has been developed with the intention of replacing currently applied lead containing free cutting steel. The ultimate goal of this project is to provide a new lead-free steel grade that will contribute to the removal of environmentally harmful substances from automobile parts. In this project, we have targeted the development of a material that would demonstrate levels of machinability and other mechanical properties equivalent to those of the conventional free-cutting steel to which sulfur (S), lead (Pb) and calcium (Ca) or combinations, thereof have been added. The fine dispersion of sulfide, modified by adding Mg and Ca, is most effective in enhancing the chip breakability that would otherwise deteriorate due to the absence of lead. The practical application of the non-lead-added free-cutting steel has rendered the goal of total removal of lead from special steel products highly obtainable.

The Vapor Reducing Fuel Tank System (Bladder Tank System) using a flexible plastic membrane (Bladder Membrane) was newly developed in order to reduce the amount of vaporized gasoline in a steel fuel tank. This Bladder Membrane is flexible to expand in proportion to a fuel volume and prevents the permeation of the vaporized gasoline. As a result of our initial study for various materials, we decided to apply a multi-layer plastic material which could achieve both low fuel permeability and good flexibility. This multi-layer material consists of polyethylene(PE) for structural material and polyamide(PA) for low permeability. The modulus of the PE needs to achieve a sufficient flexibility in order to keep the movement of the membrane. While PA material must have not only low fuel permeability but also strong adhesion with the structural material of PE. We also clarify the membrane design to keep a good flexibility and to reduce a strain.

This paper describes the development of alloy cast iron that can be used for the cutting edges of the trimming die of a press die. Usually, a block of tool steel or steel casting is inserted at the cutting edge of the trimming die of a press die. However, we unified the structure part and the cutting-edge part of a press die with alloy cast iron. As it can''t bear as the cutting edge in this state, the cutting edge is processed by flame-hardening. After the flame- hardening, we developed the alloy cast iron so that enough hardness may be obtained by natural air cooling. Thereby, the machining of the installation seat of the cutting edge decreased and the expense of dies has been reduced.

In October 1998, a new mass-produced car with titanium engine-valves was released from TOYOTA Motor Corporation. Both intake and exhaust valves were manufactured via a newly developed cost-effective P/M forging process. Furthermore, the material which was specially designed for the exhaust one is a unique titanium metal matrix composite (MMC). This paper discusses the materials and manufacturing methods used. The tensile, fatigue strength and creep resistance of the MMC are always superior to those for the typical heat-resistant steel of 21-4N. Both valves have achieved sufficient durability and reliability with a manufacturing cost acceptable for mass-produced automobile parts.

This paper presents the numerical simulation method to predict the deactivation process of three-way catalytic converters. Three-way catalytic converter's deactivation typically results from thermal and chemical mechanisms. The major factor of thermal deactivation is the sintering of noble metal particles, which is known to depend on the ageing temperature and the oxygen concentration in the exhaust gas. The chemical deactivation is mainly caused by the poisoning, which has two effects on the catalyst deactivation. One effect is the loss of the catalyst activity, which is expressed by reduced frequency factors of reaction rates. Another effect is the suppression of the noble metal sintering. Poison deposits prevent the noble metal particles from moving in the washcoat, assisted by the reduced thermal loading of reaction heats, which is caused by the loss of the catalyst activity. Modeling these deactivation factors, we propose the rate expression of noble metal sintering.

The anti-shudder effect of ATF additives and their mechanisms have been investigated. Anti-shudder durability was evaluated using an automatic transmission (AT) on an engine stand under continuously slip-controlled condition. The addition of over-based Ca-sulfonate and friction modifier (FM) remarkably improved the anti-shudder durability of ATF. The surface roughness of the contact area (contact area roughness) of the clutch plates was measured by an electron probe surface roughness analyzer. To evaluate the boundary frictional properties of the adsorbed film formed, the friction coefficient of the clutch plates in the absence of oil was examined after the anti-shudder durability test. It was found that shudder occurrence was strongly correlated with the contact area roughness and the boundary frictional property of the steel plate surface. Large contact area roughness and low boundary friction were preferred to prevent shudder.

This paper describes the application of a life prediction method for stainless steel exhaust manifolds. Examination of the exhaust manifold cracks indicated that many of the failures could be attributed to out-of-phase thermal fatigue due to compressive strains that occur at high temperatures. Therefore, the plastic strain range was used as the crack initiation criteria. In addition, the comparison of the calculated thermal fatigue stress-strain hysteresis to the experimental hysteresis made it clear that it was essential to use the stress-strain data that was obtained through tensile and compression testing by keeping the test specimens at the maximum temperature of the thermal fatigue test mode. A finite element crack prediction method was developed using the aforementioned material data and good results were obtained.

The 1ZZ-FE engine is a newly developed in-line 4-cylinder, 1.8-liter, DOHC 4-valve engine mounted in the new Corolla. Abounding in new technologies including the laser-clad valve seat, high-pressure die-cast aluminum cylinder block, and the small-pitch chain drive DOHC, coupled with the fundamentally reviewed basic specifications, the new engine is compact and lightweight, offering high performance and good fuel economy. Anticipating even more stringent emission regulations in the future, in addition to the revision of the engine body, the layout of the exhaust system has been improved to enhance warm-up performance of the converter.

New ductile cast iron flywheel integrated with gear and its manufacturing process were developed to reduce the manufacturing steps and cost compared with conventional flywheel around which a steel ring gear is fit. In this process, the ring gear teeth around a cast iron flywheel are formed directly in net shape and free from any defect by the hot form-rolling method, followed by the thermomechanical treatment in a short time. The gear is superior to that made by the conventional hobbing and heat treatment in accuracy, strength and anti-wear property.

A newly-developed time resolved exhaust gas analysis system was utilized in this study. The hydrocarbon compositions upstream and downstream of the catalytic converter were investigated during cold start and warm up of the Federal Test Procedure(FTP), with three fuels of different aromatic contents. Although engine-out hydrocarbon emissions had high concentrations right after cold start, the specific reactivity was low. This can be explained by the selective adsorption of the high boiling point components which had a high Maximum Incremental Reactivity (MIR) in the intake manifold and engine-oil films. Thereafter, the high boiling point components were desorbed rapidly and consequently specific reactivity increased. Hydrocarbon adsorption of high boiling point components and hydrocarbon conversion of low boiling point components occurred simultaneously on the catalyst during warm up.

To meet the requirements for higher horsepower and torque as well as lower fuel consumption and emissions, we have developed a new “Intelligent Variable Valve Timing (VV-i)” system. It gives continuously variable intake cam phasing by up to 60 degrees crank angle (CA) . This system not only increases WOT output by optimizing intake valve closing timing but also reduces fuel consumption and NOx/ HC emissions under part load by increasing intake and exhaust valve overlap on 4 stroke Spark Ignited engines. VVT-i has been applied to optimize a new 3-liter inline 6 engine for higher torque and at the same time better fuel economy with continuous and wide-range cam phasing.

Catalyst specifications and converter layouts were studied to identify the high conversion performance under various in-use driving conditions, high mileage intervals and extended life cycle. The effects of volumes, configuration, selection and loading distribution of precious metals, additive components and substrate type for catalyst were studied on engine dynamometers and vehicle tests to optimize a catalyst converter system. Moreover, model gas experiments were conducted to analyze deterioration mechanisms and conversion characteristics of catalysts. As a result, the concept of a divided catalyst converter system, which provides separate functions for a close-coupled and an under-floor catalyst, was found to be effective for the future exhaust system. For reducing HC emissions, the close-coupled catalyst should warm up quickly and resist a high temperature. The under-floor catalyst, located at a rather low temperature position, is durable and maintains high NOx conversion.