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An SAE 5W-20 ILSAC GF-2 gasoline engine oil, which improves vehicle fuel efficiency by more than 1.5% relative to conventional SAE 5W-30 gasoline engine oils, was newly developed. And the target that 1.5% fuel efficiency improvement remains more than 10,000km was also achieved. The viscosity of this oil was optimized to satisfy both fuel economy and anti-wear performances. MoDTC and thiadiazole were added to achieve the target.

This paper describes lubricant technology to enhance the durability of the low friction performance of gasoline engine oils which were formulated with molybdenum dithiodicarbamates (MoDTCs) as friction modifiers. This paper also describes an evaluation method which consists of three tests: (1) Our in-house rig test to simulate oil deterioration in an engine stand; (2) Quantitative analysis of MoDTC and ZnDTP in oils and; (3) A friction test (SRV). It was found that the low friction performance of fuel economy engine oils deteriorated primarily due to the consumption of MoDTC and ZnDTP. Calcium salicylates had better durability of low friction performance than calcium sulfonates. Furthermore, sulfurized compounds enhanced the durability. Based on these findings, an experimental oil was formulated.

A bench engine test for evaluating the fuel efficiency of automotive crankcase oils using modern engines was developed. The fuel consumption was primarily proportional to the viscosity of the oils down to 5 mm2/s at operating temperatures, indicating that the use of low-viscosity oil was effective in improving fuel efficiency. This may be because the oil film would be formed easily, since sliding parts, such as valve train systems, in modern engines are finely finished. Organo molybdenum dithiocarbamates were effective in improving fuel efficiency at high temperature. A 2.7% improvement in fuel efficiency relative to conventional SAE 10W-30 oils was achieved by the combination of low-viscosity SAE 5W-20 oils and organo molybdenum dithiocarbamates under constant operating conditions with engine speed 1,500 rpm and torque 37.2 N•m.

It is widely known that pellet-typed catalysts are deactivated by phosphorus (ZnDTP) that comes from engine oils. In this paper, the poisoning of monolithic three-way catalysts and oxygen sensors by engine oils is studied. First, catalysts and oxygen sensors were poisoned on the engine bench by test oils in which the quantity of phosphorus and ash was varied. Next, performance of the catalysts and sensors alone was examined and the vehicle exhaust emission at FTP mode was measured on a chassis dynamometer. The results indicate that phosphorus in engine oils poisons the monolithic catalyst and the oxygen sensor resulting in deterioration of the vehicle NOx exhaust emission. However, Ca sulfonate and Mg sulfonate detergents act by restraining phosphorus poisoning of the catalyst and the oxygen sensor. Through analysis of the catalyst and sensor surfaces, it is concluded that phosphorus poisons the catalyst and sensor forming a dense coating.

Fuel economy is one of the most important performance features for modern engine oils. For some time now, fuel efficient engine oils (called Energy Conserving II or EC-II) have been available in the marketplace. However, the performance of EC-II oils is only 2.7% Equivalent Fuel Economy Improvement (EFEI) as measured by the ASTM Sequence VI Engine Test. To meet future industry needs, more fuel efficient engine oils are desirable. In order to achieve this, a study of highly fuel efficient engine oils was initiated. An initial target of 3.9% EFEI was selected and several candidate oils were evaluated, some of which exceeded this target. The oils were evaluated using a chassis dynamometer using the U. S. EPA mode. The test results may be summarized: 5W-30 Prototype Oil containing MoDTC showed between 1.6 and 2.6% better fuel economy than conventional 5W-30 and 10W-30 EC-II oils. There was an optimum viscosity for maximum fuel economy using the EPA testing mode.