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Technical Paper

Effects of Ethanol Blending on the Reactivity and Laminar Flame Speeds of Gasoline, Methanol-to-Gasoline, and Ethanol-to-Gasoline Surrogates

2024-04-09
2024-01-2817
Ethanol blending is one method that can be used to reduce knock in spark ignition engines by decreasing the autoignition reactivity of the fuel and modifying its laminar flame speed. In this paper, the effects of ethanol blending on knock propensity and flame speed of petroleum and low-carbon gasoline fuels is analyzed. To do so, surrogate fuels were formulated for methanol-to-gasoline (MTG) and ethanol-to-gasoline (ETG) based on the fuels’ composition, octane number, and select physical properties; and 0-D and 1-D chemical kinetics simulations were performed to investigate reactivity and laminar flame speed, respectively. Results of MTG and ETG were compared against those of PACE-20, a well-characterized surrogate for regular E10 gasoline. Similarly to PACE-20, blending MTG and ETG with ethanol increases the fuel’s research octane number (RON) and sensitivity.
Technical Paper

Evaluation of Fully Sustainable Low Carbon Gasoline Fuels Meeting Japanese E10 Regular and Premium Octane Specifications

2023-09-29
2023-32-0165
Reducing the carbon emissions associated with ICE- containing vehicles is a complimentary step towards carbon neutrality alongside the introduction of vehicles using newer energy vectors. In this study, the authors investigated emissions and efficiency impact of fully renewable E10-grade gasoline fuels blended with sustainable components at both 90 RON and 96 RON in comparison with reference regular E0 and premium certification gasolines across a range of ICE vehicle applications. Both renewable fuels were blended to the Japan JIS K2022 2012 E10 specification. The study shows very low carbon gasolines are technically feasible and potentially have an important role to play in decarbonizing both new advanced technology ICE vehicles and, critically, the existing ICE vehicle parc in the transition towards a zero emissions future.
Technical Paper

Evaluation of Distinctive Oil Bores in Engine Crankshaft for Friction Reduction Purpose

2023-09-29
2023-32-0160
Internal combustion engines will play an important role in the coming decades, even considering targets of carbon neutrality for a sustainable future. This will be especially true in regions where pure electrified vehicle implementation is not yet practical, or for long-range heavy load transportation purposes, even in regions where BEV infrastructure is well established. HEV/PHEV’s importance and contribution to CO2 emission reduction together with carbon neutral fuels such as hydrogen, e-fuel and biomass fuel etc. will remain crucial regardless of region/transport sectors. In this respect, brake thermal efficiency improvements by friction reduction needs further investigation. This is especially so with the crankshaft bearings’ lubrication system, which can provide as much as 40% of the total mechanical losses in some cases. It is a well-established fact, that plain bearings require a minimum oil flow volume to maintain their real function rather than oil pressure.
Technical Paper

Colorimetric Sensor for Facile Identification of Methanol-Containing Gasoline

2017-03-28
2017-01-1288
Despite the fact that methanol is toxic to human health and causes serious damage to automobile engines and fuel system components, methanol-containing gasoline is becoming popular in some areas. Methanol demonstrates similar chemical properties to ethanol (which is already established as an additive to gasoline), so that it is difficult to identify methanol-containing gasoline without performing proper chemical analysis. In this study, we report a low-cost, portable, and easy-to-operate sensor that selectively changes color in response to methanol contained in gasoline. The colorimetric sensor will be useful for automobile users to avoid methanol-containing gasoline upon refueling.
Journal Article

Study of Oxide Supports for PEFC Catalyst

2017-03-28
2017-01-1179
Polymer electrolyte membrane fuel cell (PEFC) systems for fuel cell vehicles (FCVs) require both performance and durability. Carbon is the typical support material used for PEFC catalysts. However, hydrogen starvation at the anode causes high electrode potential states (e.g., 1.3 V with respect to the reversible hydrogen electrode) that result in severe carbon support corrosion. Serious damage to the carbon support due to hydrogen starvation can lead to irreversible performance loss in PEFC systems. To avoid such high electrode potentials, FCV PEFC systems often utilize cell voltage monitor systems (CVMs) that are expensive to use and install. Simplifying PEFC systems by removing these CVMs would help reduce costs, which is a vital part of popularizing FCVs. However, one precondition for removing CVMs is the adoption of a durable support material to replace carbon.
Journal Article

Analysis of Influence of Snow Melting Agents and Soil Components on Corrosion of Decorative Chrome Plating

2016-04-05
2016-01-0539
The dissolution and exfoliation of chromium plating specific to Russia was studied. Investigation and analysis of organic compounds in Russian soil revealed contents of highly concentrated fulvic acid. Additionally, it was found that fulvic acid, together with CaCl2 (a deicing agent), causes chromium plating corrosion. The fulvic acid generates a compound that prevents reformation of a passivation film and deteriorates the sacrificial corrosion effectiveness of nickel.
Technical Paper

Improvement of Adhesion Properties between Epoxy Resin and Primer and between Primer and Ni Plating in Hybrid Vehicle Power Semiconductor Module under High Temperature Conditions

2016-04-05
2016-01-0500
In this report, adhesion mechanism between epoxy resin and primer and between primer and Ni platting in Hybrid vehicle (HV) was investigated. Adhesion forces are thought to be a combination of mechanical bond forces (such as anchor effect), chemical bond forces and physical bond forces (such as hydrogen bonding and Van der Waals force). Currently there is insufficient understanding of the adhesion mechanism. In particular, the extent to which the three bond forces contribute to adhesion strength. So the adhesion mechanism of polyimide primers was analyzed using a number of different methods, including transmission electron microscope (TEM) and atomic force microscope (AFM) observation, to determine the contributions of the three bonding forces. Molecular simulation was also used to investigate the relationship between adhesion strength and the molecular structure of the primer.
Technical Paper

Oxidation Stability of Diesel/Biodiesel Blends: Impact of Fuels Physical-Chemical Properties over Ageing During Storage and Accelerated Oxidation

2015-09-01
2015-01-1930
Current and future engine technologies and fuels are mutually dependent. The increased use of alternative fuels has been linked to deterioration in performance of injectors, fuel filters and engines as a result of insoluble deposit formation. The present work aimed to study the impact of Diesel/biodiesel blends formulation (biodiesel feedstock and content) and temperature on the oxidation stability based on total acid number (TAN). The biofuels used in the fuel matrix were: rapeseed, soy and palm methyl esters (RME, SME and PME respectively). The Diesel/biodiesel blends were made with 0%v/v, 5%v/v, 10% v/v and 20%v/v of biodiesel blended with additive-free new Diesel. The oxidation stability of Diesel/biodiesel blends was to evaluate during 6 months fuels storage, under 20°C and 40°C, and fuels severe oxidation into a reactor vessel to better understand the parameters leading to fuel oxidation on-board.
Technical Paper

Feasibility Study of Exhaust Emissions in a Natural Gas Diesel Dual Fuel (DDF) Engine

2012-09-10
2012-01-1649
The Diesel Dual Fuel (DDF) vehicle is one of the technologies to convert diesel vehicles for natural gas usage. The purpose of this research was to study the possibility of a DDF vehicle to meet emission standards for diesel vehicles. This research was done for small passenger vehicles and commercial vehicles. The exhaust emissions compliance of such vehicles in a New European Driving Cycle (NEDC) mode which was composed of Urban Driving Cycles (UDC) and an Extra Urban Driving Cycle (EUDC) was evaluated. (see APPENDIXFigure A1) In this study, the passenger vehicle engine, compliant with the EURO4 standard, was converted to a DDF engine. Engine bench tests under steady state conditions showed similar result to previous papers. Total hydrocarbon (HC) emission was extremely high, compared to diesel engine. The NEDC mode emissions of the DDF vehicle were estimated based on these engine bench test results.
Journal Article

Development of System Control for Rapid Warm-up Operation of Fuel Cell

2012-04-16
2012-01-1230
Cold weather operation has been a major issue for fuel cell hybrid vehicles (FCHV). To counteract the effects of low temperatures on FCHV operation, an approach for rapid warm-up operation based on concentration overvoltage increase and conversion efficiency decrease by limiting oxygen or hydrogen supply was adopted. In order to suppress increases in exhaust hydrogen concentration due to pumping hydrogen during rapid warm-up, dilution control using bypass air and reduction of concentration overvoltage by a minimum voltage guard were implemented. These approaches effectively control waste heat generation and suppress exhaust hydrogen concentrations during cold start and warm-up. These developments were incorporated into the 2008 Toyota FCHV-adv and it was confirmed that the rapid warm-up operation strategy allowed the FCHV-adv to be successfully and repeatedly started at -30°C.
Technical Paper

Biodiesel Stability and its Effects on Diesel Fuel Injection Equipment

2012-04-16
2012-01-0860
The effects of biodiesel oxidation stability on diesel fuel injection equipment (FIE) behavior were investigated using newly developed test rig and methodology. On the test rig, biodiesel blend fuels were circulated through a fuel tank and a common rail injection system. Fuel injected from typical diesel injectors was returned into the fuel tank to enhance the speed of fuel degradation. The results showed that injector deposits could be reproduced on a test rig. It was observed that injector body temperature increase accelerates the degradation of fuel and therefore gives earlier FIE failure. Fuel renewal could partially restore the injection quantity after complete failure at low injection pressure, thus showing a potential cleaning effect on injector deposits when refueling a car.
Technical Paper

Ignition Characteristics of Hydrogen Jets in an Argon-Oxygen Atmosphere

2012-04-16
2012-01-1312
The ignition delay and combustion characteristics of hydrogen jets in an argon-oxygen atmosphere were investigated to provide fundamental data for operating an argon-circulated hydrogen internal combustion engine. Experiments were conducted in a constant-volume combustion vessel to study the effects of ambient temperature, ambient pressure, oxygen concentration and injection pressure on a pre-burning system. The hydrogen-jet penetration and flame were also investigated based on high-speed shadowgraph images. The experimental results indicated that the ignition delay (τ) increases as the ambient temperature (Ti) decreases, similar to the results obtained in an air atmosphere. The heat-release rate results also exhibited similar trends.
Technical Paper

A Study of Mixed-FAME and Trace Component Effects on the Filter Blocking Propensity of FAME and FAME Blends

2010-10-25
2010-01-2116
Previous studies have investigated the impacts of biofuel usage on the performance, drivability and durability of modern diesel engines and exhaust after-treatment systems including test work with different types, concentrations and mixtures of bio fuel components. During this earlier work vehicle fuel filter blocking issues were encountered during a field trial using various types of EN 14214 compliant Fatty Acid Methyl Ester (FAME) blended into EN 590 diesel. This paper summarises a subsequent literature review that was carried out looking into potential causes of this filter blocking and further work that was then carried out to expand on the findings. From this, a laboratory study was carried out to assess the increase in fuel filter blocking tendency (FBT) when various FAMEs from mixed sources were blended into EN 590 diesel at different concentrations, including levels above those currently allowed in the European market.
Journal Article

High-Efficiency and Low-NOx Hydrogen Combustion by High Pressure Direct Injection

2010-10-25
2010-01-2173
Hydrogen can be produced from various renewable energy sources, therefore it is predicted that hydrogen could play a greater role in meeting society's energy needs in the mid- to long-term. Conventional hydrogen engines have some disadvantages: higher cooling loss results in low thermal efficiency and abnormal combustion (backfire, pre-ignition, higher burning velocity) limits high load operation. Direct injection is an effective solution to overcome these disadvantages, but combustion methods that enable both high efficiency and low NOx have yet to be studied in enough detail. In this research, high-efficiency and low-NOx hydrogen combustion was investigated using a prototype high-pressure hydrogen injector (maximum 30 MPa). Experiments were carried out with a 2.2-liter 4-cylinder diesel engine equipped with a centrally mounted hydrogen injector, a toroidal shape combustion chamber, and a spark plug in the glow plug position.
Journal Article

The Impact of Diesel and Biodiesel Fuel Composition on a Euro V HSDI Engine with Advanced DPNR Emissions Control

2009-06-15
2009-01-1903
In an effort to reduce CO2 emissions, governments are increasingly mandating the use of various levels of biofuels. While this is strongly supported in principle within the energy and transportation industries, the impact of these mandates on the transport stock’s CO2 emissions and overall operating efficiency has yet to be fully explored. This paper provides information on studies to assess biodiesel influences and effects on engine performance, driveability, emissions and fuel consumption on state-of-the-art Euro IV compliant Toyota Avensis D4-D vehicles with DPNR aftertreatment systems. Two fuel matrices (Phases 1 & 2) were designed to look at the impact of fuel composition on vehicle operation using a wide range of critical parameters such as cetane number, density, distillation and biofuel (FAME) level and type, which can be found within the current global range of Diesel fuel qualities.
Technical Paper

Analysis of Degradation Mechanism of Lead-Free Materials

2009-04-20
2009-01-0260
The use of lead-free (Pb-free) solder and plating in onboard electronic components has accelerated rapidly in recent years, but solutions have yet to be found for the issues of whisker generation in tin (Sn) plating and crack initiation in Pb-free solder, despite widespread research efforts. Analysis of the whisker generation mechanism has focused on internal energy levels and crystal orientation, and analysis of the crack initiation mechanism in Pb-free solder has examined changes in the grain boundaries of Sn crystals.
Technical Paper

Development of Fuel Cell Hybrid Vehicle by Toyota -Durability-

2009-04-20
2009-01-1002
Various issues must be resolved before sustainable mobility can be achieved, the most important of which are reacting to energy supply and demand, and lowering CO2 emissions. At present, the fact that the vast majority of vehicles run on conventional oil is regarded as a problem for which Toyota Motor Corporation (TMC) is developing various technological solutions. Fuel cell (FC) technology is one of the most promising of these solutions. A fuel cell is an extremely clean device that uses hydrogen and oxygen to generate power without emitting substances like CO2, NOx, or PM during operation. Its energy efficiency is high and it is widely expected to form the basis of the next generation of powertrains. Since 1992, TMC has been working to develop the main components of fuel cell vehicles, including the fuel cell itself, and the high pressure hydrogen tank and hybrid systems.
Technical Paper

Impact Study of High Biodiesel Blends on Performance of Exhaust Aftertreatment Systems

2008-10-06
2008-01-2494
Biodiesel Fuel (BDF) Research Work Group works on identifying technological issues on the use of high biodiesel blends (over 5 mass%) in conventional diesel vehicles under the Japan Auto-Oil Program started in 2007. The Work Group conducts an analytical study on the issues to develop measures to be taken by fuel products and vehicle manufacturers, and to produce new technological findings that could contribute to the study of its introduction in Japan, including establishment of a national fuel quality standard covering high biodiesel blends. For evaluation of the impacts of high biodiesel blends on performance of diesel particulate filter system, a wide variety of biodiesel blendstocks were prepared, ranging from some kinds of fatty acid methyl esters (FAME) to another type of BDF such as hydrotreated biodiesel (HBD). Evaluation was mainly conducted on blend levels of 20% and 50%, but also conducted on 10% blends and neat FAME in some tests.
Technical Paper

Effects of RME30 on Exhaust Emissions and Combustion in a Diesel Engine

2008-10-06
2008-01-2499
Considering the popularity of biodiesel fuels for diesel vehicles, the impacts of rapeseed oil methyl ester (RME), which is the most utilized biodiesel fuel in Europe, on tailpipe emissions from a diesel passenger car was investigated. In this study, 30% RME blended diesel fuel (RME30) was used and the comparison of tailpipe emissions between RME30 and a reference diesel fuel was conducted using a test vehicle with the latest engine and aftertreatment system. The results of the investigation reveal that RME30 generates about the same amount of NOx in tailpipe emissions as diesel fuel, and less HC, CO, and PM. These phenomena occurred in spite of attaching catalysts to the test vehicle, and therefore suggesting that the NOx conversion efficiency of the catalysts for RME30 is equal to that for diesel fuel. The injection rate for RME30 was the same as that for diesel fuel.
Technical Paper

The Impact of RON on SI Engine Thermal Efficiency

2007-07-23
2007-01-2007
Recently, global warming and energy security have received significant attention. Thus an improvement of the vehicle fuel economy is strongly required. For engines, one effective way is to improve the engine thermal efficiency. Raising compression ratio [1] or turbo charging technologies have potential to achieve high thermal efficiency. However knock does not allow the high thermal efficiency. Knock depends on the fuel composition and the pressure and temperature history of unburnt end-gas [2-3]. For fuels, RON is well known for describing the anti knock quality. High RON fuels have high anti knock quality and result in higher thermal efficiency. This paper investigates the impact of high RON fuels on the thermal efficiency by using high compression ratio engine, turbo charged engine, and lean boosted engine [4]. Finally, it is shown that the high thermal efficiency can be approached with high RON gasoline and ethanol.
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