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Further improvements in catalyst performance are required to help protect the atmospheric environment. However, from the viewpoint of resource availability, it is also necessary to decrease the amount of precious metals used at the active sites of the catalyst. Therefore, a high-performance three-way catalyst with an advanced coating layer has been developed to lower the amount of precious metal usage. Fuel efficiency improvement technologies such as high compression ratios and a large-volume exhaust gas recirculation (EGR) generally tend to increase the ratio of hydrocarbons (HC) to nitrogen oxides (NOx) in exhaust gas. This research focused on the palladium (Pd) loading depth in the coating layer with the aim of improving the hydrocarbon (HC) conversion activity of the catalyst.

Growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. One of the key technologies is a new OSC material that has low surface area (SA) and high OSC performance. We enhanced the pyrochlore- ceria/zirconia (CZ) which has a very small SA. In order to enhance the heat resistance and promote the OSC reaction, we selected and optimized the additive element. This material showed high OSC performance especially in the temperature range of 400 degrees or less. Another key technology is washcoat structure that has high gas diffusivity by making connected pore in the washcoat (New pore forming technology).

Countries and regions around the world are tightening emissions regulations in reaction to the increasing awareness of environmental conservation. At the same time, growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. This catalyst incorporates rhodium (Rh) clusters with a particle size of several nanometers, and stabilized CeO2-ZrO2 solid-solution (CZ) with a pyrochlore crystal structure as a high-volume oxygen storage capacity (OSC) material with a slow O2 storage rate.

The aim of this research is to develop the diesel combustion simulation (UniDES: Universal Diesel Engine Simulator) that incorporates multiple-injection strategies and in-cylinder composition changes due to exhaust gas recirculation (EGR), and that is capable of high speed calculation. The model is based on a zero-dimensional (0D) cycle simulation, and represents a multiple-injection strategy using a multi-zone model and inhomogeneity using a probability density function (PDF) model. Therefore, the 0D cycle simulation also enables both high accuracy and high speed. This research considers application to actual development. To expand the applicability of the simulation, a model that accurately estimates nozzle sac pressure with various injection quantities and common rail pressures, a model that accounts for the effects of adjacent spray interaction, and a model that considers the NOx reduction phenomenon under high load conditions were added.

A one-dimensional (1-D) micro-kinetic reaction model with considering mass transport inside porous washcoat was developed to promote an effective development of multi-functional catalysts. The validation of this model has been done successfully through the comparison with a set of basic experiments. A numerical simulation study was conducted for the various catalyst configurations of three-way catalysts under Federal Test Procedure (FTP75) condition. It was found that a double layer type had a significant advantage in the total mass emissions, especially in NOx emissions. The reaction mechanisms in these catalysts were numerically clarified from the view point of detailed reaction dynamics. We concluded that the utilization of the numerical simulation with the detailed chemistry was effective for the optimization of catalyst design.

The effects of an increasing boost pressure, a high EGR rate and a high injection pressure on exhaust emissions from an HSDI (High Speed Direct Injection) diesel engine were examined. The mechanisms were then investigated with both in-cylinder observations and 3DCFD coupled with ϕT-map analysis. Under a high-load condition, increasing the charging efficiency combined with a high injection pressure and a high EGR rate is an effective way to reduce NOx and soot simultaneously, which realized an ultra low NOx of 16ppm at 1.7MPa of IMEP (Indicated Mean Effective Pressure). The flame temperature with low NOx and low soot emissions is decreased by 260K from that with conventional emissions. Also, the distribution of the fuel-air mixture plot on a ϕT-map is moved away from the NOx and soot formation peninsula, compared to the conventional emissions case.

In recent years, problems such as global warming, the depletion of natural resources, and air pollution caused by emissions are emerging on a global scale. These problems call for efforts directed toward the development of fuel-efficient engines and exhaust gas reduction measures. As a solution to these issues, performance improvements should be achieved on the oil that lubricates the sliding sections of engines. This report points to features required of future engine oil-such as contribution to fuel consumption, minimized adverse effects on the exhaust gas aftertreatment system, and improved reliability achieved by sludge reduction-and discusses the significance of these features. For engine oil to contribution of engine oil to lower fuel consumption, we examined the effects of reduced oil viscosity on friction using gasoline and diesel engines.

Natural gas homogeneous charge compression ignition (HCCI) engines require high compression ratios and intake air heating because of the high auto-ignition temperature of natural gas. In the first study, the natural gas fueled HCCI combustion with internal exhaust gas recirculation (EGR) was achieved without an intake air heater. The effects of the combustion chamber configuration, turbocharging, and external EGR were investigated for expanding the operating range. As a result, it was cleared that the combination of internal / external EGR and turbocharging is effective for expanding the HCCI operational range toward high loads. Meanwhile, the HCCI combustion characteristics at high engine speeds were unstable because of an insufficient reaction time for auto-ignition. Although the engine operation with a richer air-fuel ratio was effective for improving the combustion stability, the combustion noise (CN) was at an unacceptable level.

In order to enhance the catalytic performance of the NOx Storage-Reduction Catalyst (NSR Catalyst), the sulfur tolerance of the NSR catalyst was improved by developing new support and NOx storage materials. The support material was developed by nano-particle mixing of ZrO2-TiO2 and Al2O3 in order to increase the Al2O3-TiO2 interface and to prevent the ZrO2-TiO2 phase from sintering. A Ba-Ti oxide composite material was also developed as a new NOx storage material containing highly dispersed Ba. It was confirmed that the sulfur tolerance and activity of the developed NSR catalyst are superior to that of the conventional one.

A concept of dual-fuel, Premixed Compression Ignition (PCI) combustion controlled by two fuels with different ignitability has been developed to achieve drastically low NOx and smoke emissions. In this system, isooctane, which was used to represent high-octane gasoline, was supplied from an intake port and diesel fuel was injected directly into an engine cylinder at early timing as ignition trigger. It was found that the ignition timing of this PCI combustion can be controlled by changing the ratio of amounts of injected two fuels and combustion proceeds very mildly by making spatial stratifications of ignitability in the cylinder even without EGR, as preventing the whole mixture from igniting simultaneously. The operable range of load, where NOx and smoke were less than 10ppm and 0.1 FSN, respectively, was extended up to 1.2MPa of IMEP using an intake air boosting system together with dual fueling.

In conventional gasoline engine vehicles, three-way catalysts are used to simultaneously remove HC, CO and NOx from the exhaust gas. The effectiveness of the catalyst to remove these harmful species depends strongly on the oxygen concentration in the exhaust gas. Deterioration of three-way catalyst results in a reduction in its purification activity and OSC (oxygen storage capacity). In this investigation, additive elements were used to enhance the durability and OSC of the catalyst support material. An optimized formulation of a CeO2-ZrO2 and a ZrO2 material was developed to have excellent durability, improved OSC, enhanced interaction between precious metals and support materials, and increase thermal stability. Using these newly developed support materials, catalysts with increased performance was designed.

NOx reduction activity in an oxidizing exhaust gas was significantly improved by discharging non-thermal plasma and catalysts (plasma assisted catalysis). We investigated effective catalyst for plasma assisted catalysis in view of hydrocarbon-selective catalytic reduction(HC-SCR). Plasma assist was effective for γ-alumina and alkali or alkaline earth metals loaded zeolite and γ-alumina showed the highest NOx conversion among these catalysts. On the other hand, Plasma assist was not effective for Cu-ZSM-5 and Pt loaded catalyst. The NOx conversion for the plasma assisted γ-alumina decreased by formation of a deposit on the catalyst below 400°C. It is shown that indium loading on γ-alumina improved the NOx reduction activity and suppressed the degradation of the NOx reduction activity at 300°C with plasma assist.

The stratification feature of DI gasoline combustion was studied by using a constant volume combustion vessel. An index of stratification degree, defined as volumetric burning velocity, has been proposed based on the thermodynamic analysis of the indicated pressure data. The burning feature analysis using this stratification degree and the fuel vapor concentration measurement using He-Ne laser ray absorption method were carried out for the swirl nozzle spray with 90° cone angle and the slit nozzle spray with 60° fan angle. Ambient pressure and ambient temperature were changed from atmospheric condition to 0.5∼0.6 MPa and 465 K, respectively. Air Swirl with swirl ratio of 0∼1.0 were added for the 90° swirl nozzle spray. Single component fuels with different volatility and self-ignitability from each other were used besides gasoline fuel. The major findings are as follows. High ambient temperature improves stratification degree due to the enhanced fuel vaporization and vapor diffusion.

Behavior of sprays formed by slit nozzle as well as swirl nozzles with the spray cone angle in the range of 40° ∼110 ° were studied in a constant volume N2 gas chamber. The fuels used are iso-pentane, n-heptane, benzene and gasoline. The ambient pressure and temperature were raised up to 1.0 MPa and 465 K, respectively. The injection pressure was mainly set at 8 MPa. Spray penetrates at an almost constant speed for a while after injection start and begins to decelerate at a certain point. This point was judged as breakup point, based on a momentum theory on spray motion, the observation of spray inside and the analysis of the spray front reacceleration which occurs under highly volatile condition.

The stoichiometric direct injection gasoline engines have higher torque performance than the port injection engines, as the volumetric efficiency can be increased due to the cooling effects of charging air by the fuel evaporation in the cylinder. They need only 3-way catalyst, leading to the cost down. However there exists the injection timing (region) that increased volumetric efficiency does not lead to higher torque. In order to investigate the phenomena, the in-cylinder mixture formation process has been analyzed by the LIF and the CFD techniques. As the results, it has been revealed that the phenomena are caused by the inhomogeneous mixture distribution before the ignition timing.

In direct-injection (DI) gasoline engines, spray characteristics greatly affect engine combustion. For the rapid development of new gasoline direct-injectors, it is necessary to predict the spray characteristics accurately by numerical analysis based on the injector nozzle geometry. In this study, two-phase flow inside slit nozzle injectors is calculated using the volume of fluid method in a three-dimensional CFD. The calculation results are directly applied to the boundary conditions of spray calculations, of which the submodels are recently developed to predict spray formation process in direct injection gasoline engines. The calculation results are compared with the experiments. Good agreements are obtained for typical spray characteristics such as spray shape, penetration and Sauter mean diameter at both low and high ambient pressures. Two slit nozzle injectors of which the slit thickness is different are compared.

The catalyst of the crystalline ceramics known as a perovskite-type oxide was designed and controlled at the atomic level in order to create a new function for self-regeneration of precious metals in a usage ambience without auxiliary treatment. We have already reported that a catalyst with Pd supported on the perovskite-type oxide has higher activity than a catalyst with Pd supported on alumina. It was also found that Pd supported on the perovskite catalyst is finely dispersed [1, 2 and 3] The object of this study was to investigate the mechanism of self-regeneration by using hyper-analytical facilities. XAFS analysis, at SPring-8 (8 GeV), revealed that Pd is in six-fold coordinations with oxygen in a perovskite crystal, which indicating that Pd occupies the B site of the unit formula of ABO3 in the perovskite crystal structure under oxidation atmosphere.

A new stratified charge combustion system has been developed for direct injection gasoline engines. The special feature of this system is employment of a thin fan-shaped fuel spray formed by a slit nozzle. The stratified mixture is produced by the combination of this fan-spray and a shell-shaped piston cavity. Both under-mixing and over-mixing of fuel in the stratified mixture is reduced by this system. This combustion system does not require distinct charge motion such as tumble or swirl, which enables intake port geometry to be simplified to improve full load performance. The effects of the new system on engine performance at part load are improved fuel consumption and reduced smoke, CO and HC emissions, obviously at medium load and medium engine speed. HC emissions at light load are also improved even with high EGR conditions.

A multi-component fuel vaporization model is developed for numerical analysis of specific fuel component behaviors in port-fuel-injection(PFI) gasoline engines. In order to specify the differences of in-cylinder fuel distribution among its components, three-dimensional calculations of intake flow, spray and vapor motion of each component are performed with respect to engine wall temperature and the distillation characteristics of the fuel. Simultaneous measurements of in-cylinder behaviors of different volatility components in the fuel are also carried out using a laser-induced fluorescence (LIF) technique to validate the calculation results. In both measurements and calculations, the same fuels are used, which are composed of seven or eight components to simulate the distillation characteristics of two kinds of gasoline. The in-cylinder vapor amount of high and low volatility components is compared between the calculations and the experiments.

The effect of the chemical reactivity of diesel fuel on PM formation was investigated using a flow reactor and a shock tube. Reaction products from the flow-reactor pyrolysis of the three diesel fuels used for the engine tests in Part 1(1) (“Base”, “Improved” and Swedish “Class-1”) were analyzed by gas chromatography. At 850C, Swedish “Class-1” fuel was found to produce the most PM precursors such as benzene and toluene among the three fuels, even though it contains very low amounts of aromatics. The chemical analyses described in Part 1 revealed that “Class-1” contains a large amount of branched and cyclic structures in the saturated hydrocarbon portion of the fuel. These results suggest that the presence of such branched and ring structures can increase exhaust PM emissions.