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Validation of a vehicle simulation model of the Chevrolet Volt 2016 was conducted. The Chevrolet Volt 2016 is equipped with the new “Voltec” extended-range propulsion system introduced into the market in 2016. The second generation Volt powertrain system operates in five modes, including two electric vehicle modes and three extended-range modes. Model development and validation were conducted using the test data performed on the chassis dynamometer set in a thermal chamber of Argonne National Laboratory’s Advanced Powertrain Research Facility. First, the components of the vehicle, such as the engine, motor, battery, wheels, and chassis, were modeled, including thermal aspects based on the test data. For example, engine efficiency changes dependent on the coolant temperature, or chassis heating or air-conditioning operations according to the ambient and cabin temperature, were applied.