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Technical Paper

Potential use of graphene composites in epoxy resin as anticorrosive painting in automotive industry

2024-01-08
2023-36-0139
Steel represents more than 50% of weight in vehicles, being more susceptible to corrosion processes. Corrosion studies in these components are of great industrial and economic interest, and anticorrosive coatings with efficiency of superior protection is still a relevant area in materials research. Paintings from inorganic and organic hybrid compounds have been used to produce more effective and efficient coatings. Among polymeric coatings, epoxy resin is considered one of the most used anticorrosion coatings, mainly due its excellent protective properties. High barrier level is reached by reinforcing the coatings with inorganic fillers such heavy metal, nanoparticles, silica, and now more recently, carbon-based materials, like graphene and its derivatives.
Technical Paper

A systematic review on smart coatings for automotive applications

2024-01-08
2023-36-0126
Corrosion affects all industrial sectors where metals or metal alloys are used in their structures. In the automotive industry, the continuous search for lightweight parts has increased the demand for effective corrosion protection, in order to improve vehicle performance without compromising durability and safety. In this scenario, coatings are essential elements to preserve and protect vehicle parts from various environmental aggressions. Automotive coatings can be classified into primers, topcoats, clearcoats, and specialty coatings. Primers provide corrosion resistance and promote adhesion between the substrate and topcoat. Topcoats provide color, gloss, and durability to the coating system, while clearcoats enhance the appearance and durability of the finish. Specialty coatings provide additional properties, such as scratch resistance, chemical resistance, and UV protection.
Technical Paper

Development of a 5-Component Diesel Surrogate Chemical Kinetic Mechanism Coupled with a Semi-Detailed Soot Model with Application to Engine Combustion and Emissions Modeling

2023-08-28
2023-24-0030
In the present work, five surrogate components (n-Hexadecane, n-Tetradecane, Heptamethylnonane, Decalin, 1-Methylnaphthalene) are proposed to represent liquid phase of diesel fuel, and another different five surrogate components (n-Decane, n-Heptane, iso-Octane, MCH (methylcyclohexane), Toluene) are proposed to represent vapor phase of diesel fuel. For the vapor phase, a 5-component surrogate chemical kinetic mechanism has been developed and validated. In the mechanism, a recently updated H2/O2/CO/C1 detailed sub-mechanism is adopted for accurately predicting the laminar flame speeds over a wide range of operating conditions, also a recently updated C2-C3 detailed sub-mechanism is used due to its potential benefit on accurate flame propagation simulation. For each of the five diesel vapor surrogate components, a skeletal sub-mechanism, which determines the simulation of ignition delay times, is constructed for species C4-Cn.
Journal Article

Improving Keyhole Stability during Laser Welding of AA5xxx Alloys

2022-03-29
2022-01-0247
Laser welding of the magnesium-bearing AA5xxx aluminum alloys is often beset by keyhole instability, especially in the lap through joint configuration. This phenomenon is characterized by periodic collapse of the keyhole leaving large voids in the weld zone. In addition, the top surface can exhibit undercut and roughness. In full penetration welds, keyhole instability can also produce a spikey root and severe top surface concavity. These discontinuities could prevent a weld from achieving engineering specification compliance, pose a craftsmanship concern, or reduce the strength and fatigue performance of the weld. In the case of a full penetration weld, a spikey root could compromise part fit-up and corrosion protection, or damage adjacent sheet metal, wiring, interior components, or trim.
Journal Article

Low-Cost Magnesium Alloy Sheet Component Development and Demonstration Project

2022-03-29
2022-01-0248
Most of the applications of magnesium in lightweighting commercial cars and trucks are die castings rather than sheet metal, and automotive applications of magnesium sheet have typically been experimental or low-volume serial production. The overarching objective of this collaborative research project organized by the United States Automotive Materials Partnership (USAMP) was to develop new low-cost magnesium alloys, and demonstrate warm-stamping of magnesium sheet inner and outer door panels for a 2013 MY Ford Fusion at a fully accounted integrated component cost increase over conventional steel stamped components of no more than $2.50/lb. saved ($5.50/kg saved). The project demonstrated the computational design of new magnesium (Mg) alloys from atomistic levels, cast new experimental alloy ingots and explored thermomechanical rolling processes to produce thin Mg sheet of desired textures.
Technical Paper

Cast Magnesium Subframe Development-Corrosion Mitigation Strategy and Testing

2021-04-06
2021-01-0279
A cast magnesium AE44 subframe was designed and manufactured for a C Class sedan to reduce weight and improve vehicle fuel economy. Corrosion mitigation strategies were developed to reduce the likelihood of galvanic corrosion. Both a proving ground vehicle corrosion test and a laboratory component corrosion test were conducted. The vehicle test result demonstrated that the corrosion mitigation strategies were effective. They also provided lessons learned on clearance between magnesium and steel components and options to improve the subframe’s corrosion resistance. The magnesium subframe achieved 5 kg (32%) weight reduction from the equivalent steel subframe and met all the required structural performance targets.
Journal Article

Graphene Coating as a Corrosion Protection Barrier for Metallic Terminals in Automotive Environments

2021-04-06
2021-01-0354
Inside an automobile, hundreds of connectors and electrical terminals in various locations experience different corrosive environments. These connectors and electrical terminals need to be corrosion-proof and provide a good electrical contact for a vehicle’s lifetime. Saltwater and sulfuric acid are some of the main corrosion concerns for these electrical terminals. Currently, various thin metallic layers such as gold (Au), silver (Ag), or tin (Sn) are plated with a nickel (Ni) layer on copper alloy (Cu) terminals to ensure reliable electrical conduction during service. Graphene due to its excellent chemical stability can serve as a corrosion protective layer and prevent electrochemical oxidation of metallic terminals. In this work, effects of thin graphene layers grown by plasma-enhanced chemical vapor deposition (PECVD) on Au and Ag terminals and thin-film devices were investigated. Various mechanical, thermal/humidity, and electrical tests were performed.
Technical Paper

Corrosion Performance of a Magnesium Tower Brace

2021-04-06
2021-01-0276
This study reports the corrosion performance of three different coating strategies tested on an AE44 high performance magnesium strut tower brace used on the 2020 Ford Mustang Shelby GT500. The alloy was selected due to its improved structural performance at higher temperatures over conventional AM60B magnesium die castings. The first coating strategy used no pretreatment, conversion coating, or topcoat to gage the baseline corrosion performance of the uncoated alloy. The second coating strategy used a conventional pretreatment commonly used on AM60B alloy. The third used a ceramic-based conversion coating. A textured (stipple) powder coat was then applied to the two non-baseline parts over the pretreatment. All three coating strategies were then evaluated by comparing the corrosion performance after cyclic corrosion testing for 12 weeks using the Ford L-467 test.
Technical Paper

How Well Can mPEMS Measure Particulate Matter Motor Vehicle Exhaust Emissions?

2020-04-14
2020-01-0391
Real world emissions are increasingly the standard of comparison for motor vehicle exhaust impact on the environment. The ability to collect such data has thus far relied primarily on full portable emissions measurement systems (PEMS) that are bulky, expensive, and time consuming to set up. The present work examines four compact, low cost, miniature PEMS (mPEMS) that offer the potential to expand our ability to record real world exhaust emissions over a larger number of operating conditions and combustion engine applications than currently possible within laboratory testing. It specifically addresses the particulate matter (PM) capabilities of these mPEMS, which employ three different methodologies for particle measurement: diffusion charger, optical scattering, and a multi-sensor approach that combines scattering, opacity, and ionization. Their performance is evaluated against solid particle number and PM mass with both vehicle tests and flame generated soot.
Technical Paper

Piston Bowl Geometry Effects on Combustion Development in a High-Speed Light-Duty Diesel Engine

2019-09-09
2019-24-0167
In this work we studied the effects of piston bowl design on combustion in a small-bore direct-injection diesel engine. Two bowl designs were compared: a conventional, omega-shaped bowl and a stepped-lip piston bowl. Experiments were carried out in the Sandia single-cylinder optical engine facility, with a medium-load, mild-boosted operating condition featuring a pilot+main injection strategy. CFD simulations were carried out with the FRESCO platform featuring full-geometric body-fitted mesh modeling of the engine and were validated against measured in-cylinder performance as well as soot natural luminosity images. Differences in combustion development were studied using the simulation results, and sensitivities to in-cylinder flow field (swirl ratio) and injection rate parameters were also analyzed.
Technical Paper

Duct Shape Optimization Using Multi-Objective and Geometrically Constrained Adjoint Solver

2019-04-02
2019-01-0823
In the recent years, adjoint optimization has gained popularity in the automotive industry with its growing applications. Since its inclusion in the mainstream commercial CFD solvers and its continuously added capabilities over the years, its productive usage became readily available to many engineers who were previously limited to interfacing the customized adjoint source code with CFD solvers. The purpose of this work is to demonstrate using an adjoint solver a method to optimize duct shape that meets multiple design objectives simultaneously. To overcome one of the biggest challenges in the duct design, i.e. the severe packaging constraints, the method here uses geometrically constrained adjoint to ensure that the optimum shape always fits into the user-defined packaging space. In this work, adjoint solver and surface sensitivity calculations are used to develop the optimization method.
Technical Paper

Regeneration Strategies for Gasoline Particulate Filters

2019-04-02
2019-01-0969
Gasoline particulate filters (GPFs) are extremely effective at reducing tailpipe emissions of particulate mass and particulate number. Especially in the European and Chinese markets, where a particulate number standard is legislated, we see gasoline particulate filters being deployed in production on gasoline direct injected engines. Due to the high temperature in gasoline exhaust, most applications are expected to be passively regenerating without the help of an active regeneration strategy. However, for the few cases where a customer drive cycle has consistently low speed over a long time frame, an active regeneration strategy may be required. This involves increasing the exhaust temperature at the GPF up to around 600 degC so that soot can be combusted. We compare two different ways of achieving these temperatures, namely spark retard and air fuel ratio modulation. The former generates heat in the engine, the latter generates heat in one or more catalysts in the exhaust system.
Technical Paper

Using Artificial Ash to Improve GPF Performance at Zero Mileage

2019-04-02
2019-01-0974
Gasoline particulate filters (GPF) with high filtration efficiency (>80%) at zero mileage are in growing demand to meet increasingly tight vehicle emission standards for particulate matter being implemented in US, EU, China and elsewhere. Current efforts to achieve high filter performance mainly focus on fine-tuning the filter structure, such as the pore size distribution and porosity of the bare substrate, or the washcoat loading and location of catalyzed substrates. However, high filtration efficiency may have a cost in high backpressure that negatively affects engine power. On the other hand, it has been recognized in a few reports that very low amounts of ash deposits (from non-combustible residue in the exhaust) can significantly increase filtration efficiency with only a mild backpressure increase.
Journal Article

Smart DPF Regenerations - A Case Study of a Connected Powertrain Function

2019-04-02
2019-01-0316
The availability of connectivity and autonomy enabled resources, within the automotive sector, has primarily been considered for driver assist technologies and for extending the levels of vehicle autonomy. It is not a stretch to imagine that the additional information, available from connectivity and autonomy, may also be useful in further improving powertrain functions. Critical powertrain subsystems that must operate with limited or uncertain knowledge of their environment stand to benefit from such new information sources. Unfortunately, the adoption of this new information resource has been slow within the powertrain community and has typically been limited to the obvious problem choices such as battery charge management for electric vehicles and efforts related to fuel economy benefits from adaptive/coordinated cruise control. In this paper we discuss the application of connectivity resources in the management of an aftertreatment sub-system, the Diesel Particulate Filter (DPF).
Technical Paper

Coating on striker: Robust corrosion protection with low cost

2018-09-03
2018-36-0044
Corrosion is a known phenomenon that the automotive industry needs to pay attention, once that several issues faced in the field had it as root cause. Indisputably is important spend resources in usage of proper materials and process based on chemical properties, minimum thickness, adhesion conditions, wear resistance, finish applicators, etc. to cover the parts in order to ensure robust protection against this phenomena; however, the key point is to optimize these resources once that the customer will buy/use the vehicle (not the part singly); so if develop a proper design in system level providing proper protection of the parts, despite of the part does not have the most efficient protection level, the customers will have a satisfactory experience during vehicle usage.
Technical Paper

Development of Wireless Message for Vehicle-to-Infrastructure Safety Applications

2018-04-03
2018-01-0027
This paper summarizes the development of a wireless message from infrastructure-to-vehicle (I2V) for safety applications based on Dedicated Short-Range Communications (DSRC) under a cooperative agreement between the Crash Avoidance Metrics Partners LLC (CAMP) and the Federal Highway Administration (FHWA). During the development of the Curve Speed Warning (CSW) and Reduced Speed Zone Warning with Lane Closure (RSZW/LC) safety applications [1], the Basic Information Message (BIM) was developed to wirelessly transmit infrastructure-centric information. The Traveler Information Message (TIM) structure, as described in the SAE J2735, provides a mechanism for the infrastructure to issue and display in-vehicle signage of various types of advisory and road sign information. This approach, though effective in communicating traffic advisories, is limited by the type of information that can be broadcast from infrastructures.
Technical Paper

Accelerated Corrosion Testing of Automotive Evaporators and Condensers

2018-04-03
2018-01-0062
There is an ongoing effort in the industry to develop an accelerated corrosion test for automotive heat exchangers. This has become even more important as automakers are focusing on corrosion durability of 15 years in the field versus current target of 10 years. To this end an acid immersion test was developed and reported in a previous paper for condensers (1). This paper extends those results to evaporators and establishes the efficacy of the test using these results and those reported in the literature. The paper also discusses variability in corrosion test results as observed in tests such as ASTM G85:A3 Acidified Synthetic Sea Water Test (SWAAT), and its relation to field durability.
Technical Paper

A Packaging Layout to Mitigate Crosstalk for SiC Devices

2018-04-03
2018-01-0462
SiC devices have inherent fast switching capabilities due to their superior material properties, and are considered potential candidates to replace Si devices for traction inverters in electrified vehicles in future. However, due to the comparatively low gate threshold voltage, SiC devices may encounter oscillatory false triggering especially during fast switching. This paper analyzed the causes of false triggering, and also studied the impact of a critical parasitic parameter - common source inductance. It is shown that crosstalk is the main cause for the false triggering in the case and some positive common source inductance help to mitigate the crosstalk issue. A packaging layout method is proposed to create the positive common source inductance through layout of control terminals / busbars, and/or the use of control terminal bonded wires at different height.
Technical Paper

Gasoline Particulate Filter Efficiency and Backpressure at Very Low Mileage

2018-04-03
2018-01-1259
The need for gasoline particulate filter (GPF) technology is expected to grow with increasingly tight particle emissions standards being implemented in US, EU, China and elsewhere. Derived from the successful experience with diesel particulate filters (DPF), GPFs adopted the characteristic alternately plugged honeycomb structure that provides a large area of porous cordierite wall for filtering particles with minimal additional backpressure. However, unlike DPFs, continuous soot regeneration in GPFs makes it difficult to grow and sustain the soot cake on the filter wall that gives DPFs their high filtration efficiency. Therefore, filtration performance of low mileage GPFs relies heavily on the porous structure of filter media, which depends on both the substrate and the applied washcoat. In this work, a blank, two fresh washcoated filters and two washcoated filters with 3000 km mileage accumulation were characterized to compare their filtration performance.
Technical Paper

Stress Analysis on the Single-Lap SPR- Adhesive Hybrid Joint

2018-04-03
2018-01-1445
Self-pierced rivet (SPR) and adhesive are two important joining technologies widely used in automobile industry, and they are often used together to form a hybrid joint. SPR and adhesives can often be used in close proximity in a component, leading to an interaction of the two joints. This interaction can influence the corrosion and noise, vibration and harshness (NVH) characteristics of the structure, as well as its strength and durability. In this paper, the stress distribution in an SPR-adhesive hybrid joint is evaluated by using the finite element method, and then compared with that in an adhesive joint. Results indicate that the stress concentrates at the edge of adhesive layer in hybrid joint and adhesive joint and around the rivet in an SPR joint. The effect of rivet is numerically investigated by either removing the rivet from the hybrid joint or changing the position of the rivet on the overlapping area.
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