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Technical Paper

Development of a 5-Component Diesel Surrogate Chemical Kinetic Mechanism Coupled with a Semi-Detailed Soot Model with Application to Engine Combustion and Emissions Modeling

2023-08-28
2023-24-0030
In the present work, five surrogate components (n-Hexadecane, n-Tetradecane, Heptamethylnonane, Decalin, 1-Methylnaphthalene) are proposed to represent liquid phase of diesel fuel, and another different five surrogate components (n-Decane, n-Heptane, iso-Octane, MCH (methylcyclohexane), Toluene) are proposed to represent vapor phase of diesel fuel. For the vapor phase, a 5-component surrogate chemical kinetic mechanism has been developed and validated. In the mechanism, a recently updated H2/O2/CO/C1 detailed sub-mechanism is adopted for accurately predicting the laminar flame speeds over a wide range of operating conditions, also a recently updated C2-C3 detailed sub-mechanism is used due to its potential benefit on accurate flame propagation simulation. For each of the five diesel vapor surrogate components, a skeletal sub-mechanism, which determines the simulation of ignition delay times, is constructed for species C4-Cn.
Technical Paper

Generation of Reactive Chemical Species/Radicals through Pilot Fuel Injection in Negative Valve Overlap and Its Effects on Engine Performances

2022-08-30
2022-01-1002
This study investigated the potential of generating reactive chemical species (including radicals) through pilot fuel injection in negative valve overlap for improving the combustion and emissions performances of spark ignition gasoline engines under low load and low speed operating conditions. Several Ford sub-models were used for simulating the physics and chemistry processes of injecting a small amount of fuel in NVO (negative valve overlap). Effects of different NVO degrees and different pilot injection timings, factors for fuel conversion were simulated and investigated. CO and H2 conversions during NVO, CO and H2 amounts before spark timing were used for comparing different schemes.
Journal Article

Quantitative Analysis of Gasoline Direct Injection Engine Emissions for the First 5 Firing Cycles of Cold Start

2021-04-06
2021-01-0536
A series of cold start experiments using a 2.0 liter gasoline turbocharged direct injection (GTDI) engine with custom controls and calibration were carried out using gasoline and iso-pentane fuels, to obtain the cold start emissions profiles for the first 5 firing cycles at an ambient temperature of 22°C. The exhaust gases, both emitted during the cold start firing and emitted during the cranking process right after the firing, were captured, and unburned hydrocarbon emissions (HC), CO, and CO2 on a cycle-by-cycle basis during an engine cold start were analyzed and quantified. The HCs emitted during gasoline-fueled cold starts was found to reduce significantly as the engine cycle increased, while CO and CO2 emissions were found to stay consistent for each cycle. Crankcase ventilation into the intake manifold through the positive-crankcase ventilation (PCV) valve system was found to have little effect on the emissions results.
Journal Article

A Novel Technique for Measuring Cycle-Resolved Cold Start Emissions Applied to a Gasoline Turbocharged Direct Injection Engine

2020-04-14
2020-01-0312
There is keen interest in understanding the origins of engine-out unburned hydrocarbons emitted during SI engine cold start. This is especially true for the first few firing cycles, which can contribute disproportionately to the total emissions measured over standard drive cycles such as the US Federal Test Procedure (FTP). This study reports on the development of a novel methodology for capturing and quantifying unburned hydrocarbon emissions (HC), CO, and CO2 on a cycle-by-cycle basis during an engine cold start. The method was demonstrated by applying it to a 4 cylinder 2 liter GTDI (Gasoline Turbocharged Direct Injection) engine for cold start conditions at an ambient temperature of 22°C. For this technique, the entirety of the engine exhaust gas was captured for a predetermined number of firing cycles.
Technical Paper

Duct Shape Optimization Using Multi-Objective and Geometrically Constrained Adjoint Solver

2019-04-02
2019-01-0823
In the recent years, adjoint optimization has gained popularity in the automotive industry with its growing applications. Since its inclusion in the mainstream commercial CFD solvers and its continuously added capabilities over the years, its productive usage became readily available to many engineers who were previously limited to interfacing the customized adjoint source code with CFD solvers. The purpose of this work is to demonstrate using an adjoint solver a method to optimize duct shape that meets multiple design objectives simultaneously. To overcome one of the biggest challenges in the duct design, i.e. the severe packaging constraints, the method here uses geometrically constrained adjoint to ensure that the optimum shape always fits into the user-defined packaging space. In this work, adjoint solver and surface sensitivity calculations are used to develop the optimization method.
Journal Article

Passive Hydrocarbon Trap to Enable SULEV-30 Tailpipe Emissions from a Flex-Fuel Vehicle on E85 Fuel

2018-04-03
2018-01-0944
Future LEV-III tailpipe (TP) emission regulations pose an enormous challenge forcing the fleet average of light-duty vehicles produced in the 2025 model year to perform at the super ultralow emission vehicle (SULEV-30) certification levels (versus less than 20% produced today). To achieve SULEV-30, regulated TP emissions of non-methane organic gas (NMOG) hydrocarbons (HCs) and oxygenates plus oxides of nitrogen (NOx) must be below a combined 30 mg/mi (18.6 mg/km) standard as measured on the federal emissions certification cycle (FTP-75). However, when flex-fuel vehicles use E85 fuel instead of gasoline, NMOG emissions at cold start are nearly doubled, before the catalytic converter is active. Passive HC traps (HCTs) are a potential solution to reduce TP NMOG emissions. The conventional HCT design was modified by changing the zeolite chemistry so as to improve HC retention coupled with more efficient combustion during the desorption phase.
Journal Article

Benefits of Pd Doped Zeolites for Cold Start HC/NOx Emission Reductions for Gasoline and E85 Fueled Vehicles

2018-04-03
2018-01-0948
In the development of HC traps (HCT) for reducing vehicle cold start hydrocarbon (HC)/nitrogen oxide (NOx) emissions, zeolite-based adsorbent materials were studied as key components for the capture and release of the main gasoline-type HC/NOx species in the vehicle exhaust gas. Typical zeolite materials capture and release certain HC and NOx species at low temperatures (<200°C), which is lower than the light-off temperature of a typical three-way catalyst (TWC) (≥250°C). Therefore, a zeolite alone is not effective in enhancing cold start HC/NOx emission control. We have found that a small amount of Pd (<0.5 wt%) dispersed in the zeolite (i.e., BEA) can significantly increase the conversion efficiency of certain HC/NOx species by increasing their release temperature. Pd was also found to modify the adsorption process from pure physisorption to chemisorption and may have played a role in the transformation of the adsorbed HCs to higher molecular weight species.
Journal Article

A New Catalyzed HC Trap Technology that Enhances the Conversion of Gasoline Fuel Cold-Start Emissions

2018-04-03
2018-01-0938
Passive in-line catalyzed hydrocarbon (HC) traps have been used by some manufacturers in the automotive industry to reduce regulated tailpipe (TP) emissions of non-methane organic gas (NMOG) during engine cold-start conditions. However, most NMOG molecules produced during gasoline combustion are only weakly adsorbed via physisorption onto the zeolites typically used in a HC trap. As a consequence, NMOG desorption occurs at low temperatures resulting in the use of very high platinum group metal (PGM) loadings in an effort to combust NMOG before it escapes from a HC trap. In the current study, a 2.0 L direct-injection (DI) Ford Focus running on gasoline fuel was evaluated with full useful life aftertreatment where the underbody converter was either a three-way catalyst (TWC) or a HC trap. A new HC trap technology developed by Ford and Umicore demonstrated reduced TP NMOG emissions of 50% over the TWC-only system without any increase in oxides of oxygen (NOx) emissions.
Technical Paper

Development of Wireless Message for Vehicle-to-Infrastructure Safety Applications

2018-04-03
2018-01-0027
This paper summarizes the development of a wireless message from infrastructure-to-vehicle (I2V) for safety applications based on Dedicated Short-Range Communications (DSRC) under a cooperative agreement between the Crash Avoidance Metrics Partners LLC (CAMP) and the Federal Highway Administration (FHWA). During the development of the Curve Speed Warning (CSW) and Reduced Speed Zone Warning with Lane Closure (RSZW/LC) safety applications [1], the Basic Information Message (BIM) was developed to wirelessly transmit infrastructure-centric information. The Traveler Information Message (TIM) structure, as described in the SAE J2735, provides a mechanism for the infrastructure to issue and display in-vehicle signage of various types of advisory and road sign information. This approach, though effective in communicating traffic advisories, is limited by the type of information that can be broadcast from infrastructures.
Technical Paper

A Packaging Layout to Mitigate Crosstalk for SiC Devices

2018-04-03
2018-01-0462
SiC devices have inherent fast switching capabilities due to their superior material properties, and are considered potential candidates to replace Si devices for traction inverters in electrified vehicles in future. However, due to the comparatively low gate threshold voltage, SiC devices may encounter oscillatory false triggering especially during fast switching. This paper analyzed the causes of false triggering, and also studied the impact of a critical parasitic parameter - common source inductance. It is shown that crosstalk is the main cause for the false triggering in the case and some positive common source inductance help to mitigate the crosstalk issue. A packaging layout method is proposed to create the positive common source inductance through layout of control terminals / busbars, and/or the use of control terminal bonded wires at different height.
Technical Paper

Copper Effect on the Ultrasonic Fatigue Life of A356 Aluminum Alloy Under Variable Humidity Levels

2018-04-03
2018-01-1411
Ultrasonic fatigue tests (testing frequency around 20kHz) have been conducted on A356 aluminum alloys with different copper contents and AS7GU aluminum alloy. Tests were performed in dry air and submerged in water conditions. The effect of copper content was investigated and it was concluded that copper content plays an important role influencing the humidity effect on A356 aluminum alloy ultrasonic fatigue lives. Also, for the same copper content, copper in solute solution or in precipitate have different humidity sensitivities.
Technical Paper

The Development of Low Temperature Three-Way Catalysts for High Efficiency Gasoline Engines of the Future: Part II

2018-04-03
2018-01-0939
It is anticipated that future gasoline engines will have improved mechanical efficiency and consequently lower exhaust temperatures at low load conditions, although the exhaust temperatures at high load conditions are expected to remain the same or even increase due to the increasing use of downsized turbocharged engines. In 2014, a collaborative project was initiated at Ford Motor Company, Oak Ridge National Lab, and the University of Michigan to develop three-way catalysts with improved performance at low temperatures while maintaining the durability of current TWCs. This project is funded by the U.S. Department of Energy and is intended to show progress toward the USDRIVE target of 90% conversion of hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx) at 150 °C after high mileage aging. The testing protocols specified by the USDRIVE ACEC team for stoichiometric S-GDI engines were utilized during the evaluation of experimental catalysts at all three facilities.
Journal Article

The Influence of Fuel Cetane Number on Catalyst Light-Off Operation in a Modern Diesel Engine

2017-08-18
2017-01-9378
The design of modern diesel-powered vehicles involves optimization and balancing of trade-offs for fuel efficiency, emissions, and noise. To meet increasingly stringent emission regulations, diesel powertrains employ aftertreatment devices to control nitrogen oxides, hydrocarbons, carbon monoxide, and particulate matter emissions and use active exhaust warm-up strategies to ensure those devices are active as quickly as possible. A typical strategy for exhaust warm-up is to operate with retarded combustion phasing, limited by combustion stability and HC emissions. The amount of exhaust enthalpy available for catalyst light-off is limited by the extent to which combustion phasing can be retarded. Diesel cetane number (CN), a measure of fuel ignition quality, has an influence on combustion stability at retarded combustion phasing. Diesel fuel in the United States tends to have a lower CN (both minimum required and average in market) than other countries.
Technical Paper

MyFord Dock Development

2017-03-28
2017-01-1694
Demand for enhanced infotainment systems with features like navigation, real-time traffic, music streaming service, mirroring and others is increasing, forcing automakers to develop solutions that fulfill customer needs. However, many of those systems are too expensive to be fitted to an entry-level vehicle leaving a gap in the market that fails customer’s expectation. This gap is usually filled by a smartphone which may have all the features the customer wants but in many cases it cannot be properly fitted in the vehicle due to lack of specific storage space. This paper describes how the engineering team developed an innovative, flexible and effective solution that holds a smartphone in an ergonomic location.
Technical Paper

High Frequency Sloshing - Energy Dissipation and Viscous Damping through CFD

2017-03-28
2017-01-1317
Liquid sloshing is an important issue in ground transportation, aerospace and automotive applications. Effects of sloshing in a moving liquid container can cause various issues related to vehicle stability, safety, component fatigue, audible noise and, liquid level measurement. The sloshing phenomenon is a highly nonlinear oscillatory movement of the free-surface of liquid inside a container under the effect of continuous or momentarily excitation forces. These excitation forces can result from sudden acceleration, braking, sharp turning or pitching motions. The sloshing waves generated by the excitation forces can impact on the tank surface and cause additional vibrations. For the loads with the frequencies between 2 to 200 Hz, the structural fatigue failure is a major concern for automotive applications.
Technical Paper

Investigation into Occurrence of Megaknock and Auto-Ignition in GTDI Engines

2017-03-28
2017-01-0690
The performance of boosted gasoline engines is limited at high loads by knock, stochastic Low Speed Pre-Ignition, and Megaknock. An investigation has been carried out on the occurrence of abnormal combustion and megaknock in a 1.6 L GTDI engine with the aim to determine the causes of such phenomena. A classification of abnormal combustion events and causes is presented in order to facilitate a consistent terminology. The experiments specifically focus on the effects of exhaust residual gas on occurrence of megaknock in multi-cylinder engines. The results showed that while a misfire will not lead to megaknock, a very late combustion in one cycle, in one cylinder may lead to megaknock in the following cycle in the same or adjacent cylinder. Additionally, a recently developed multi-zone model was used to analyze the role of residual gas on auto-ignition.
Technical Paper

Evolution of Engine Air Induction System Hydrocarbon Traps

2017-03-28
2017-01-1014
Engine air induction systems hydrocarbon trap (HC trap) designs to limit evaporative fuel emissions, have evolved over time. This paper discusses a range of HC traps that have evolved in engine air induction systems. (AIS) The early zeolite flow through HC trap utilized an exhaust catalyst technology internal stainless steel furnace brazed substrate coated with zeolite media. This HC trap was installed in the AIS clean air tube. This design was heavy, complicated, and expensive but met the urgency of the implementation of the new evaporative emissions regulation. The latest Ford Motor Company HC trap is a simple plastic tray containing activated carbon with breathable non-woven polyester cover. This design has been made common across multiple vehicle lines with planned production annual volume in the millions. The cost of the latest HC trap bypass design is approximately 5% of the original stainless steel zeolite flow through HC trap.
Journal Article

The Effects of CO, C2H4, and H2O on the NOx Storage Performance of Low Temperature NOx Adsorbers for Diesel Applications

2017-03-28
2017-01-0942
Model low temperature NOx adsorbers (LTNA) consisting of Pd on a ceria/zirconia washcoat on monoliths were evaluated for low temperature NOx storage under lean conditions to assess their potential for adsorbing the cold-start NOx emissions on a diesel engine during the period before the urea/SCR system becomes operational. A reactor-based transient test was performed with and without C2H4, CO/H2, and H2O to assess the effects of these species on the NOx storage performance. In the absence of C2H4 or CO/H2, H2O severely suppressed the NOx storage of these model LTNAs at temperatures below 100°C, presumably by blocking the storage sites. When C2H4 was included in the feedgas, H2O still suppressed the NOx storage below 100°C. However, the C2H4 significantly increased the NOx storage efficiency above 100°C, attributable to the formation of alkyl nitrites or alkyl nitrates on the catalyst.
Journal Article

The Development of Low Temperature Three-Way Catalysts for High Efficiency Gasoline Engines of the Future

2017-03-28
2017-01-0918
In anticipation that future gasoline engines will have improved fuel efficiency and therefore lower exhaust temperatures during low load operation, a project was initiated in 2014 to develop three-way catalysts (TWC) with improved activity at lower temperatures while maintaining the durability of current TWCs. This project is a collaboration between Ford Motor Company, Oak Ridge National Laboratory, and the University of Michigan and is funded by the U.S. Department of Energy. The ultimate goal is to show progress towards the USDRIVE goal of 90% conversion of hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NOx) at 150°C after high mileage aging. A reactor was set up at Ford to follow the catalyst testing protocols established by the USDRIVE ACEC tech team for evaluating catalysts for stoichiometric gasoline direct-injection (S-GDI) engines; this protocol specifies a stoichiometric blend of CO/H2, NO, C3H6, C2H4, C3H8, O2, H2O, and CO2 for the evaluations.
Journal Article

Tire Tread Performance Modification Utilizing Polymeric Additives

2017-03-28
2017-01-1502
Tire manufacturers have long grappled with the challenge of balancing the conflicting tire attributes of traction, rolling resistance, and treadwear. Improvements to one of these “magic triangle” attributes often comes at the expense of the other attributes. Recent regulations have further increased the pressure on manufacturers to produce optimized tires with minimal performance compromises. In order to meet this challenge, the tire industry is looking to new material systems beyond the traditional tire tread components. Polymeric materials beyond the base elastomers and processing oils used in tread provide opportunities to modify the physical and viscoelastic properties of tread. In this study, various polymeric materials were evaluated as additives in a model tire tread formulation. Hydrocarbon resin, high styrene resin, and thermoplastic styrene elastomers were added to the model formulation at various loading levels and through various addition strategies.
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