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A comprehensive experimental and numerical analysis of two state-of-the-art diesel AfterTreatment Systems (ATS) for automotive applications is presented in this work. Both systems, designed to fulfill Euro 6 emissions regulations standards, consist of a closed-coupled Diesel Oxidation Catalyst (DOC) followed by a Selective Catalytic Reduction (SCR) catalyst coated on a Diesel Particulate Filter (DPF), also known as SCR on Filter (SCRoF or SCRF). While the two systems feature the same Urea Water Solution (UWS) injector, major differences could be observed in the UWS mixing device, which is placed upstream of the SCRoF, whose design represents a crucial challenge due to the severe flow uniformity and compact packaging requirements.